太陽能電池發電是現今非常熱門的研究課題，其中又以有機薄膜太陽能電池最具有發展潛力。苝是具有良好電子遷移率的化合物，已經有許多將其應用在有機薄膜太陽能電池的研究。

本論文討論從苝-3,4,9,10-四羧酸酐出發，將之溴化，再進行酯化反應，製備三種不同碳數的1,7-二溴苝-3,4,9,10-四羧酸酯。再經由Suzuki-Coupling合成一系列帶有多共軛系統的衍生物；所合成之產物的光學能階差在2.32~2.49電子伏特之間。最後透過UV-Vis、PL和CV來探討其結構與光電性質之關係。

The development of solar cell has been a popular topic, recently the researches focus on the organic-thin-film-type . Various perylene derivatives with good electron mobility are promising materials for organic solar cells .
New compounds with aromatic group were synthesized via esterification with simple phase transfer catalysis (PTC) method and Suzuki-coupling.
Several perylene-3,4,9,10-tetracarboxylic dianhydride’s have been synthesized. The optical energy gap (Eg) of these new compounds are between 2.32eV to 2.49eV. The relationship between the structure and photoelectric property of these new compounds were studied .

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