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研究生: 温捷翔
Wun, Jie-Siang
論文名稱: 以原子層沉積二氧化鉿研製增強型 金氧半高電子遷移率電晶體
Enhancement-mode Metal-Oxide-Semiconductor High Electron Mobility Transistors with Hafnium Oxide by Atomic Layer Deposition
指導教授: 王永和
Wang, Yeong-Her
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 微電子工程研究所
Institute of Microelectronics
論文出版年: 2022
畢業學年度: 110
語文別: 英文
論文頁數: 86
中文關鍵詞: 氮化鋁鎵/氮化鎵高電子遷移率電晶體掘入式閘極原子層沉積二氧化鉿沉積後退火表面處理
外文關鍵詞: AlGaN/GaN, high electron mobility transistors (HEMTs), gate recess, atomic layer deposition, HfO2, post deposition annealing, surface treatment
相關次數: 點閱:165下載:26
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  • 隨著5G世代的到來,氮化鎵由於其高崩潰電壓、高電子飽和速度等特性已成為科技上不可或缺的一部分。一般而言,氮化鋁鎵/氮化鎵高電子遷移率電晶體為常開模式,這將會使元件有額外耗能的缺點。因此,本論文中使用了閘極蝕刻技術去蝕刻閘極下方氮化鋁鎵的厚度,藉由氮化鋁鎵的厚度下降,二維電子雲濃度降低且操作模式轉變成增強型常關操作。此外,為了降低閘極蝕刻後造成的損傷,我們以稀釋的鹽酸溶液進行表面處理降低介面缺陷,再以原子層沉積二氧化鉿薄膜作為閘極界電層並利用沉積後退火技術提高沉積品質。
    此篇論文,我們以閘極蝕刻技術達成增強型高電子遷移率電晶體。並利用原子層沉積二氧化鉿薄膜、沉積後退火技術、表面處理成功將臨界電壓提升至 1.72V,在閘極電壓為 5V 時,最大汲極電流密度達到 509 mA/mm,最大跨導值達到 220 mS/mm,次臨界擺幅與電流開關比為 127 mV/dec 與7.5 × 107,閘極漏電流有效降低至1.76 × 10-6 mA/mm,三端崩潰電壓提升至 190 V。

    With the advent of the 5G generation, gallium nitride has become an indispensable part of technology because of its high breakdown voltage and high electron saturation speed characteristics. In general, AlGaN/GaN high electron mobility transistor (HEMT) is in normally-on mode, which will cause the device to have the disadvantage of additional power consumption. Therefore, in this paper, the gate recess technique is used to etch the thickness of AlGaN under the gate. The 2DEG concentration is reduced and the operation mode is changed by decreasing the thickness of AlGaN to enhancement-mode and normally-off operation. In addition, to reduce the damage caused by gate recess, we use diluted HCl solution for surface treatment to reduce interface defects, and then use atomic layer deposition of hafnium oxide film as the gate dielectric, and use post-deposition annealing technology to improve the deposition quality.
    In this paper, we achieve E-mode HEMT by gate recess technology. Moreover, the use of atomic layer deposition of hafnium oxide film, post-deposition annealing technology, and surface treatment successfully shifts the threshold voltage to 1.72V. When the gate voltage was 5V, the maximum drain current density reached 509 mA/mm, and the maximum transconductance value reached 220 mS/mm, the subthreshold swing and Ion/off ratio is 127 mV/dec and 7.5 × 107, respectively. The gate leakage current is effectively reduced to 1.76 × 10-6 mA/mm, and the three-terminal breakdown voltage is increased to 190V.

    中文摘要I Abstract III 誌謝V CONTENTS VIII List of Tables XII List of Figures XIII Chapter 1 Introduction 1 1-1 Background 1 1-2 Motivation 6 Chapter 2 Principle of AlGaN/GaN HEMTs 11 2-1 Lattice Constant 11 2-2 Spontaneous Polarization 13 2-3 Piezoelectric Polarization16 2-4 Two-Dimensional Electron Gas (2DEG) 20 Chapter 3 Experiments Details 23 3-1 Gate recess process 23 3-1-1 Dry etching 23 3-1-2 Gate recess depth 26 3-2 Atomic Layer Deposition (ALD) HfO2 28 3-3 Experimental Equipment 30 3-3-1 Oven 30 3-3-2 Spin Coater 31 3-3-3 Mask Aligner 32 3-3-4 Electron Beam Evaporator 33 3-3-5 Rapid Thermal Annealing System 34 3-3-6 ICP Etching System 35 3-3-7 ALD System 36 3-3-8 Semiconductor Analyzer 37 3-3-9 Transmission Electron Microscopy 38 3-1-10 Atomic Force Microscope 39 3-4 Device fabrication 40 3-4-1 Sample Cleaning 41 3-4-2 Mesa Isolation 42 3-4-3 Source and Drain Ohmic Contacts 43 3-4-4 Gate Recess Process 45 3-4-5 Atomic Layer Deposition HfO2 as gate insulator 46 3-4-6 Schottky Gate Deposition 47 3-5 Schematic Procedures 48 Chapter 4 Results and Discussion 52 4-1 Properties of ALD HfO2 layer 52 4-1-1 Transmission Electron Microscopy 52 4-1-2 Energy-Dispersive X-ray Spectroscopy 53 4-2 Surface Roughness of Gate Recess Etching 55 4-2-1 Atomic Force Microscope Images of HCl surface treatment 55 4-3 D-mode MOS-HEMT Performance 56 4-3-1 Saturation Drain Current 56 4-3-2 Transfer Characteristics 57 4-3-3 Subthreshold Swing and On-Off Ratio 59 4-3-4 Gate Leakage Current 61 4-3-5 Off-State Breakdown Voltage 62 4-4 E-mode MOS-HEMT Performance 63 4-4-1 Saturation Drain Current 63 4-4-2 Transfer Characteristics 65 4-4-3 Subthreshold Swing and On-Off Ratio 69 4-4-4 Gate Leakage Current 71 4-4-5 Off-State Breakdown Voltage 72 Chapter 5 Conclusion 74 Chapter 6 Future Work 77 References 80

    [1] U.K. Mishra, P. Parikh, Yi-Feng Wu, “AlGaN/GaN HEMTs-an overview of device operation and applications,” Proceedings of the IEEE, Volume: 90, Issue: 6, June 2002.
    [2] E.A. Jones, F.F. Wang, D. Costinett, “Review of Commercial GaN Power Devices and GaN-Based Converter Design Challenges,” IEEE Journal of Emerging and Selected Topics in Power Electronics, Volume: 4, Issue: 3, Sept. 2016.
    [3] K. Nakatani, Y. Yamaguchi, Y. Komatsuzaki, “A Ka-Band High Efficiency Doherty Power Amplifier MMIC using GaN-HEMT for 5G Application,” 2018 IEEE MTT-S International Microwave Workshop Series on 5G Hardware and System Technologies (IMWS-5G).
    [4] O. Ambacher, “Growth and applications of group III-nitrides,” Journal of Physics D Applied Physics, vol. 31, no. 20, pp. 2653-2710, Oct. 1998.
    [5] R.M. Chu, Yu Cao, Mary Chen, Ray Li, Daniel Zehnder, “An Experimental Demonstration of GaN CMOS Technology,” IEEE Electron Device Letters, Volume: 37, Issue: 3, March 2016.
    [6] Z. Zheng, L. Zhang, W. Song, S. Feng, H. Xu, J. Sun, S. Yang, T. Chen, J. Wei, and K.J. Chen, “Gallium nitride-based complementary logic integrated circuits,” Nature Electronics, vol. 4, no. 8.
    [7] M. Suzuki, T. Uenoyama and A. Yanase, “First-principles calculations of effective-mass parameters of AlN and GaN,” Phys. Rev. B, vol. 52, no. 11, pp. 8132–8139, Sep. 1995.
    [8] A. Nakajima, P. Liu, M. Ogura, T. Makino, “Generation and transportation mechanisms for two-dimensional hole gases in GaN/AlGaN/GaN double heterostructures,” Received 29 January 2014.
    [9] S.J. Bader, H. Lee, R. Chaudhuri, S. Huang, A. Hickman, A. Molnar, H.G. Xing, “Prospects for Wide Bandgap and Ultrawide Bandgap CMOS Devices,” IEEE Transactions on Electron Devices, Volume: 67, Issue: 10, Oct. 2020.
    [10] J. Robertson, “High dielectric constant oxides,” Eur. Phys. J. Appl. Phys. 28, 265–291 (2004).
    [11] S, Mohsenifar, M. H. Shahrokhabadi, “Gate Stack High-κ Materials for Si-Based MOSFETs Past, Present, and Futures”, Vol. 4 No. 1, 2015, pp. 12-24. doi: 10.5923/j.msse.20150401.03.
    [12] C. Liu, S. Yang, S. Liu, Z. Tang, H. Wang, Q. Jiang, K.J. Chen, “Thermally Stable Enhancement-Mode GaN Metal-Isolator-Semiconductor High-Electron-Mobility Transistor With Partially Recessed Fluorine-Implanted Barrier,” IEEE Electron Device Letters, Volume: 36, Issue: 4, April 2015.
    [13] T.L. Wu, D. Marcon, S. You, N. Posthuma, B. Bakeroot, S. Stoffels, M.V. Hove, G. Groeseneken, S. Decoutere, “Forward Bias Gate Breakdown Mechanism in Enhancement-Mode p-GaN Gate AlGaN/GaN High-Electron Mobility Transistors,” IEEE Electron Device Letters, Volume: 36, Issue: 10, Oct. 2015.
    [14] W. Saito, Y. Takada, M. Kuraguchi, K. Tsuda, and I. Omura, “Recessed-gate structure approach toward normally off high-voltage AlGaN/GaN HEMT for power electronics applications,” IEEE Transactions on Electron Devices, vol. 53, no. 2,pp. 356-362, Feb. 2006.
    [15] X. Huang, Q. Li, Z. Liu and F.C. Lee, "Analytical loss model of high voltage GaN HEMT in cascode configuration," IEEE Energy Conversion Congress and Exposition, vol. 29, no. 5, pp. 3587-3594, Sep. 2013.
    [16] Tian-Li Wu, "Comprehensive investigation of on-state stress on D-mode AlGaN/GaN MIS-HEMTs," Reliability Physics Symposium (IRPS), 2013 IEEE International.
    [17] D. Marcon, N.E. Posthuma, "Direct comparison of GaN-based e-mode architectures (recessed MISHEMT and p-GaN HEMTs) processed on 200mm GaN-on-Si with Au-free technology," Proceedings of SPIE - The International Society for Optical Engineering 9363, March 2015.
    [18] K.J. Chen, "Fluorine-Implanted Enhancement-Mode Transistors," Part of the Power Electronics and Power Systems book series (PEPS), 09 September 2016.
    [19] J.W. Chung, J.C. Roberts, "Effect of Gate Leakage in the Subthreshold Characteristics of AlGaN/GaN HEMTs," IEEE Electron Device Letters, Volume: 29, Issue: 11, Nov. 2008.
    [20] A. Vasishth, N. Aggarwal, “Investigation of room temperature ferromagnetic behavior in dilute magnetic oxides,” January 2018.
    [21] O. Ambacher, J. Smart, J.R. Shealy, et al, “Two-dimensional electron gasses induced by spontaneous and piezoelectric polarization charges in N- and Ga-face AlGaN/GaN heterostructures,” Cite as: Journal of Applied Physics 85, 3222 (1999).
    [22] H. Yu, T. Duan, “Gallium Nitride Power Devices” Copyright © 2017 by Pan Stanford Publishing Pte. Ltd.
    [23] M. DiDomenico Jr, and I. Camlibel. “Relationship between linear and quadratic electro‐optic coefficients in LiNbO3, LiTaO3, and other oxygen‐octahedra ferroelectrics based on direct measurement of spontaneous polarization,” Applied Physics Letters, vol. 12, no. 6, pp.
    [24] F. Fornetti “Characterization and performance optimization of GaN HEMTs and amplifiers for radar applications” Dissertation for Ph.D., University of Bristol, Dec. 2010.
    [25] L. Bouzaïene, M.H. Gazzah, H. Mejri, and H. Maaref, “Back doping design in delta-doped AlGaN/GaN heterostructure field-effect transistors,” Solid state communications, vol. 140, no. 6, pp. 308-312, Nov. 2006.
    [26] E.L. Piner, D.M. Keogh, J.S. Flynn, J.M Redwing, “AlGaN/GaN High Electron Mobility Transistor Structure Design and Effects on Electrical Properties,” MRS Internet Journal of Nitride Semiconductor Research volume 5,349–354 (2000).
    [27] H.X. Guang, Z.D. Gang, J.D. Sheng, “Formation of two-dimensional electron gas at AlGaN/GaN heterostructure and the derivation of its sheet density expression,” Chinese Physics B, 2015, 24(6): 067301.
    [28] D. Ueda, "Properties and Advantages of Gallium Nitride," in Power GaN Devices: Materials, Applications and Reliability, M. Meneghini, G. Meneghesso, and E. Zanoni, Eds. Cham: Springer International Publishing, 2017, pp. 1-26.
    [29] P. Pal, K. Sato, “Surfactant Adsorption on Single-Crystal Silicon Surfaces in TMAH Solution: Orientation-Dependent Adsorption Detected by In Situ Infrared Spectroscopy,” October 2009, Journal of Microelectromechanical Systems 18(6):1345 – 1356.
    [30] X. Tan, Z. Tao, M. Yu, “Anti-reflectance investigation of a micro-nano hybrid structure fabricated by dry/wet etching methods,” Scientific Reports volume 8, Article number: 7863 (2018).
    [31] A. Matsutani, F. Koyama, “Mass Effect of Etching Gasses in Vertical and Smooth Dry Etching of InP,” February 2001, Japanese Journal of Applied Physics 40(3A):1528, DOI:10.1143/JJAP.40.1528.
    [32] R. Swain, K. Jena and T.R. Lenka, “Modeling of capacitance and threshold voltage for ultrathin normally-off AlGaN/GaN MOSHEMT,” MS received 21 January 2015; revised 16 February 2016; accepted 6 May 2016; published online 2 December 2016.
    [33] D. Hausmann, “Tech Brief: A Look at Atomic Layer Deposition (ALD),” Industry, Technology, MAY 15, 2017.
    [34] R.W. Johnson, A. Hultqvist, S. F. Bent. “A brief review of atomic layer deposition,” from fundamentals to applications Materials Today 17, 5, 2014.
    [35] H. Jiang, “Enhancement-Mode GaN MOS-HEMTs With Recess-Free Barrier Engineering and High-k ZrO2 Gate Dielectric,” IEEE ELECTRON DEVICE LETTERS, VOL. 39, NO. 3, MARCH 2018
    [36] S.D. Gupta, “Positive Threshold Voltage Shift in AlGaN/GaN HEMTs and E-Mode Operation By AlxTi1-xO Based Gate Stack Engineering,” 2019 IEEE TRANSACTIONS ON ELECTRON DEVICES
    [37] F.C. Yang, C.Y. Huang, S.K. Yang, J.G. Wu, “Normally-off AlGaN/GaN Metal–Oxide Semiconductor High Electron Mobility Transistors with RF-Sputtered Hafnium Oxide,” Department of Electrical Engineering, National Cheng Kung University, Tainan, Taiwan, 2018.
    [38] K. Rim, J. Welser, J.L. Hoyt, J.F. Gibbons, “Enhanced hole mobilities in surface-channel strained-Si p-MOSFETs,” Proceedings of International Electron Devices Meeting.
    [39] A. Nakajima, S. Kubota, K. Tsutsui, “GaN-based complementary metal–oxide–semiconductor inverter with normally off Pch and Nch MOSFETs fabricated using polarisation-induced holes and electron channels,” Selected Papers from the 13th International Seminar on Power Semiconductors (ISPS 2016).
    [40] A. Kumar, M.M. De-Souza, “Impact of channel thickness on the performance of an E-mode p-channel MOSHFET in GaN,” Received 3 January 2018, accepted 30 March 2018, published online 11 April 2018
    [41] H.W. Jang, S.Y. Kim and Jong-Lam Lee, “Mechanism for Ohmic contact formation of oxidized Ni/Au on p-type GaN,” Journal of Applied Physics 94, 1748 (2003).

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