本研究分為兩部分，第一部分為利用聚(N-乙烯甲醯胺)作為鋰離子電池中矽負極的水性黏著劑，由於PNVF可以溶在水中，其溶液也呈現中性，所以在製程上可以達到環保以及永續發展的製程。PNVF作為非結晶高分子不會阻擋鋰離子的傳導，並且其可以與矽表面之氧化層產生氫鍵以增加矽顆粒的穩定性及附著力，本論文將利用電化學方法來探討PNVF於矽負極黏著劑中的應用，以及探討添加劑以及黏著劑於矽負極中的影響和重要性，並且以臨場的電化學測試探討矽負極所發生之反應，還有研究其破裂機制。
　　由於現代商用以及研究方面大多以鋰金屬作為負極材料，但是鋰金屬會有鋰晶枝等等所衍生的安全問題，所以需要尋找替代物，而矽作為地殼中含量第二豐富之元素，其理論電容也與鋰金屬差不多，所以是非常好的替代品。而本論文中第二部分將以第一部分以PNVF作為黏著劑所製作之矽負極極片，與磷酸鋰鐵正極，共同組成全電池，並且探討全電池中預鋰化的重要性以及全電池的電化學性能。

In this study, we introduce poly(N-vinylformamide) as a efficient binder for the silicon anode. And this study is divided into two parts. The first part is the use of poly(N-vinylformamide) as the water-soluble binder of the silicon anode in lithium-ion batteries. Since PNVF can be dissolved in water, the solution is also neutral, so in the process can achieve environmental protection and sustainable development process of battery industry. As a non-crystalline polymer, PNVF doesn’t block the conduction of lithium ions, and it can generate hydrogen bonds with the oxide layer on the surface of silicon to increase the stability and adhesion of silicon particle. This study will use electrochemical methods to discuss PNVF in silicon anodes, as well as the influence and importance of additives and adhesives in silicon anodes, and the use of in-situ electrochemical testing to explore the reactions that occur in silicon anodes and study of their rupture mechanism.
Since most of the recent research still use lithium metal as the negative electrode material, but lithium metal has some safety problems like dendrite, and it will cause some safety issue, so it is necessary to find alternatives, and silicon is the second most abundant element in the crust, and its theoretical capacitance is also similar to lithium metal, so it can be a very good candidate. In the second part of this study, the silicon anode made with PNVF as the binder in the first part will be combined with the lithium iron phosphate cathode to form a Full battery, and we will discuss the importance of pre-lithiation in the Full battery and the it’s Electrochemical performance.

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