本論文係有關以有機金屬法製備兼具磁性與光學特性之金屬複合奈米粒子的研究，探討合成條件對粒徑、結構、光學、及磁性的影響，共包括鐵金合金、鐵金核殼、及鎳金合金奈米粒子等三個系統。
關於鐵金合金奈米粒子的合成，係以油酸及油胺為保護劑，於高溫下熱裂解五羰鐵及還原醋酸金而達成。結果發現，當體心立方結構的鐵併入金的成份後會轉變為面心立方的結構，隨反應時間及溫度的增加，其粒徑會減小且特性吸收峰變為較寬，粒徑大小亦隨組成而改變。吸收峰位置因金的組成增加而呈現紅位移的現象，或因增長反應時間而呈現藍位移。此外，隨著金的組成增加，交換偏移場消失溫度(TB)及矯頑磁力隨之增加，而飽和磁化量則會降低，利用外加磁場可將粒子磁自組為平行線。在高濃度保護劑及Au/Fe = 0.25之前驅物比例的條件下，可製得鐵金異質二聚體奈米粒子，反應過程中金奈米粒子會先形成，接著鐵奈米粒子異相成長在金粒子上。由HR-TEM及XRD的分析，鐵奈米粒子幾乎無氧化的現象。此外，由於金粒子與鐵粒子結合的關係，其特性吸收峰的強度較金奈米粒子低。
關於鐵金核殼型奈米粒子的合成，係先將五羰鐵裂解為鐵作為晶種，再以醋酸金在鐵粒子表面生成金殼而達成。依被覆次數可製得不同厚度之粒子，且因電漿表面共振的關係，UV-vis吸收光譜在520 nm位置呈現特性吸收峰。此外，粒子可自組裝為二維及三維之超晶格結構，愈靠近自組裝結構的中心，粒子排列愈緻密，而形成不同超晶格結構的變化，由外圍二維單層hcp結構轉變為三維雙層hcp結構，再轉變成三維六方緊密堆積。此外，可利用乙硫醇酸進行相轉移，使疏水性之粒子轉變成親水性。
關於鎳金合金奈米粒子的合成，係以油酸及油胺為保護劑，於高溫下共還原二酮化鎳及醋酸金而達成。結果顯示，二酮化鎳在反應溫度低於200C時無法還原生成鎳奈米粒子，但藉由金核可加速其還原速率，而形成鎳金合金奈米粒子，其結構為面心立方。表面電漿共振吸收值隨金的組成及反應時間的增加而增強，而粒徑因醋酸金濃度增加而持續成長，但過度的時間反應會使粒子的原子重組而導致粒徑變小。當反應溫度高於200C時，二酮化鎳可自行還原而不需金核的輔助，由於反應過程中，有更多的鎳原子參與形成鎳金合金奈米粒子，其粒徑及表面電漿共振吸收值因而減小。

This dissertation concerns the preparation of metallic composite nanoparticles with magnetic and optical properties via organometallic routes. The effects of preparation conditions on the particle size, structure, and optical and magnetic properties were investigated. Three systems were studied, including FeAu alloy, Fe-Au core-shell, and NiAu alloy nanoparticles.
FeAu alloy nanoparticles were synthesized via thermal decomposition of iron pentacarbonyl and reduction of gold acetate in the presence of stabilizers oleic acid and oleylamine. It was found that the incorporation of Au into Fe nanoparticles led to a structural change from body-centered cubic (bcc) to face-centered-cubic (fcc). The size of particles decreased with increasing the reaction time and temperature, and varied with the Au/Fe molar ratio. Their characteristic absorption bands became broader with decreasing the Au/Fe molar ratio or increasing reaction time and temperature. Also, they were red-shifted with decreasing the Au content and blue-shifted with increasing reaction time. In addition, with the increase in the Au/Fe molar ratio, their block temperature and coercivity increased while the saturation magnetization decreased. They could be self-assembled into parallel stripes in the direction of an applied magnetic field. FeAu heterodimer nanoparticles could be synthesized at a high stabilizer concentration with Au/Fe = 0.25 through the reaction the nucleation of gold seeds and the subsequent heterogeneous growth of iron. By the analyses of HRTEM and the XRD, the iron nanoparticles were almost not to be oxidized. As compared with gold nanoparticles, it shows weak characteristic absorption band due to its contact with iron.
The synthesis of Fe-Au core-shell nanoparticles were achieved by the thermal decomposition of iron pentacarbonyl and the followed reduction of gold acetate. The resultant nanoparticles were nearly monodisperse with a complete core-shell structure and the shell thickness could be tuned via the seed-mediated growth. Also, they exhibited an absorption band at 520 nm owing to the surface plasmon resonance of Au shells. Noteworthily, the Fe-Au core-shell nanoparticles could self-assemble into 2D and 3D superlattices. The packing density increased while approaching to the center of assembly, leading to the variation of superstructures from a 2D nearly hcp monolayer to a 3D hcp superlattice and a 3D hexagonal superlattice. Moreover, hydrophilic Fe-Au core-shell nanoparticles could be obtained by surface modification with mercaptoacetic acid via a phase transfer route.
NiAu nanoparticles were synthesized via the co-reduction of nickel 2,4-pentanedionate and gold acetate. It was found that, at temperatures below 200C, pure Ni nanoparticles could not be synthesized alone but Au nuclei might promote the reduction of nickel 2,4-pentanedionate to form NiAu nanoparticles. The resultant NiAu nanoparticles were face-centered cubic (fcc) structure. The surface plasmon absorption increased with increasing Au content and reaction time. Their mean diameters decreased with increasing the Au content in the feed solution, while became larger first owing to the particle growth and then decreased due to the atom rearrangement with increasing the reaction time. When reaction temperature was above 200C, the reduction of nickel 2,4-pentanedionate might occur without the assistance of Au nuclei. The particle size and surface plasmon absorption decreased due to the formation of nuclei at the beginning of reaction and the participation of more Ni atoms.

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