| 研究生: |
莊志平 Chuang, Alvin |
|---|---|
| 論文名稱: |
多層膜成長銅鋁氧化物及摻雜三氧化二鐵之影響 Multi-layer growth CuAlO2 and effects of doping Fe2O3 |
| 指導教授: |
黃榮俊
Huang, JCA |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 奈米科技暨微系統工程研究所 Institute of Nanotechnology and Microsystems Engineering |
| 論文出版年: | 2008 |
| 畢業學年度: | 96 |
| 語文別: | 中文 |
| 論文頁數: | 83 |
| 中文關鍵詞: | 銅鋁氧化物 、稀磁性半導體 、透明導電膜 |
| 外文關鍵詞: | p-type, CuAlO, DMS |
| 相關次數: | 點閱:48 下載:1 |
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本論文工作是使用離子束濺鍍系統成長CuAlO2薄膜。實驗分成二部份,第一部份藉由離子束濺鍍系統成長[CuO(10 Å)/Al2O3(10 Å )]多層膜,在1100℃高溫退火成長具有CuAlO2晶相之薄膜。第二部份則成長[CuO(10 Å)/Fe2O3(1 Å、3 Å)/Al2O3(10 Å)]多層膜,藉由1100℃高溫退火後研究摻雜Fe之CuAlO2薄膜結構、電性、磁性上之特性。
由SQUID量測摻雜Fe之多層膜,顯示樣品呈現鐵磁性;但電阻大於200M歐姆。我們藉由400℃通氧、通氬後退火處理,發現通氧退火後樣品導電性有改善並觀察到磁性上有變大之趨勢。而通氬退火後樣品導電性則無改善並觀察到磁性有變小之趨勢。磁性來源我們推測應與樣品內缺陷較有關係,確切的機制我們將於日後做進一步的研究。
In this study,we deposited CuAlO2 thin films on Al2O3(0001) substrate by ion beam sputter. The first work we deposited [CuO(10Å)/Al2O3(10Å)] multi-layers ,and 1100℃ annealed samples under argon ambience in order to get CuAlO2 thin films. The second work we deposited [CuO(10 Å)/Fe2O3(1Å、3 Å)/Al2O3(10 Å)] multi-layers ,and 1100℃ annealed samples under argon ambience .The structural ,electrical ,and magnetic properties of annealed samples have been investigated.
The ferromagnetism of [CuO(10 Å)/Fe2O3(1 Å、3 Å)/Al2O3(10 Å)] increased after 400℃ annealing under oxygen ambience but decreased under argon ambience. The results suggest that ferromagnetism in [CuO(10 Å)/Fe2O3(1 Å、3 Å)/Al2O3(10Å)] comes from an intrinsic factor highly correlated to defects. We will go on studying to find the origin of ferromagnetism exactly.
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