本研究主要探討戴奧辛/呋喃(PCDD/Fs)在台灣南部某兩座都市型都市型廢棄物焚化爐及一座燃煤火力發電廠之質量分布情形。在都市型廢棄物焚化爐中，針對各操作單元之煙道廢氣及灰渣進行採樣，其中灰渣樣品主要包括燃燒室底渣、過熱器飛灰、節熱器飛灰、半乾式洗滌塔飛灰、袋式集塵器飛灰及飛灰貯存桶灰渣；在燃煤火力發電廠中，則針對燃燒室底渣、靜電集塵器飛灰及煙道廢氣進行採樣。所有17種PCDD/Fs同源物皆以高解析度層析質譜儀(HRGC/HRMS)進行分析。由實驗可知PCDD/Fs 毒性當量濃度在兩焚化廠(MSWI-A 及MSWI-B)中之質量分布分別為煙道廢氣(0.561%, 0.0712%)、燃燒室底渣(3.88%, 0.616%)、過熱器飛灰 (0.171%, 0.237%)、節熱器飛灰 (4.19%, 0.0505%)、半乾式洗滌塔飛灰 (1.29%, 7.06%)、袋式集塵器飛灰 (89.9%, 92.0%)；而燃煤火力發電廠則為煙道廢氣 (93.9%)、燃燒室底渣(2.47%)及靜電集塵器飛灰 (3.58%)。由以上結果可知將近99.5%之PCDD/Fs飛灰可經由焚化廠之空污防治設備所捕捉下來；但在燃煤火力發電廠中則有93.9%之PCDD/Fs排放至大氣中。本研究中所提供之各種戴奧辛/呋喃(PCDD/Fs) 之排放濃度及排放係數可作為環保單位決策之參考，亦可做為進一步學術研究之寶貴資訊。

The mass distribution of polychlorinated debenzo-p-dioxins/dibenzofurans (PCDD/Fs) was investigated in two municipal solid waste incinerators (MSWIs) and one coal-fired power plant (PP) in southern Taiwan. Samples were collected from stack flue gases (SFG), bottom residues (BR), super heater (SH), economizer (EC), semi-dry absorber (SDA), bag filter (BF), and fly ash pit (FAP) in MSWIs. Stack flue gases (SFG), bottom residues (BR) and electrostatic dust collectors (ESD) in PP were also collected. In order to compare the difference between the results of MSWIs and PP, samples from SFG, BS, and FAP in a PP were also determined. Seventeen congeners of PCDD/Fs were analyzed by utilizing a high-resolution gas chromato-graph/high-resolution mass spectrometer (HRGC/HRMS). Distributions of total PCDD/F-I-TEQ in each unit of MSWI-A and MSWI-B were SFG (0.561%, 0.0712%), BR (3.88%, 0.616%), SH (0.171%, 0.237%), EC (4.19%, 0.0505%), SDA (1.29%, 7.06%), and BF (89.9%, 92.0%), respectively. However, those in SFG, BR, and FAP of PP were 93.9%, 2.47%, and 3.58%, respectively. The above results indicated 99.5% PCDD/Fs were trapped in the fly ash of MWSI. On the other hand, 93.9% PCDD/Fs was emitted to the atmosphere from PP. The results of this study provide useful in-formation for controlling PCDD/Fs in MSWIs and PP.

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