成功大學博碩士論文系統

簡易檢索 / 詳目顯示

回結果列表

研究生：	蘇柏源 Su, Bo-Yuan
論文名稱：	Cullet添加對硼矽酸玻璃熱性質影響之研究 The Effect of Cullet Content on Thermal Properties of Borosilicate Glass
指導教授：	黃啟祥 Hwang, Chii-Shyang
學位類別：	碩士 Master
系所名稱：	工學院 - 材料科學及工程學系 Department of Materials Science and Engineering
論文出版年：	2005
畢業學年度：	93
語文別：	中文
論文頁數：	64
中文關鍵詞：	熱膨脹係數、硼矽酸玻璃、碎玻璃
外文關鍵詞：	cullet, borosilicate, thermal expansion coefficient
相關次數：	點閱：85 下載：2
分享至:	分享至facebook 分享至twitter

查詢本校圖書館目錄查詢臺灣博碩士論文知識加值系統勘誤回報

　　廿一世紀為「環保」之世紀，全球各國政府無不致力於朝「垃圾減量」與「資源回收再利用」之目標全力以赴。玻璃為質重且不易分解之物質，若能解決Cullet（碎玻璃）的問題並給予再生利用，對垃圾減量問題會有相當大的幫助，也能永續環保。為此，本研究選擇被廣泛應用之硼矽酸玻璃及其Cullet為研究對象，檢討Cullet及Na2O之添加量對硼矽酸玻璃熱性質之影響。

　　研究結果顯示：含30～70 wt％ Cullet之生料粉末，與含50 wt％ Cullet及1～5 wt％ Na2O之生料粉末，於大氣中1500℃熔融10h後急冷可成為不含氣泡及不含結晶相之硼矽酸玻璃。含70 wt% Cullet所形成之玻璃具有本研究中最低的熱膨脹係數3.07×10-6/k。1～5 wt％ Na2O之添加能降低硼矽酸玻璃之熱膨脹係數，含3 wt％Na2O者，有最低的熱膨脹係數3.13×10-6/k。硼矽酸玻璃之密度是隨著Cullet添加量的增加而增加。硼矽酸玻璃之體密度及微硬度是隨著Na2O含量的增加而增大。含70 wt% Cullet之玻璃具有最大的抗熱震溫度160℃；含3 wt％ Na2O時其抗熱震溫度為140℃。

　The environmental protection is the important subject in twenty-one century. The governments in the whole world are devoted to reach the aim of reducing garbage and resources reuse. Waste glass is massy material and is hard to be decomposed. If the problem and recycle of the cullet can be solved, it would be great helpful to keep environmental protection. The study focused on the borosilicate glass and which’s cullet. Effects of the contents of cullet and Na2O on the thermal properties of borosilicate glass have been investigated.
　Results show that using the raw materials with 30~70 wt％ cullet or with 50 wt％ cullet＋1~5 wt％ Na2O , amorphous and no bubble borosilicate glasses were formed at 1500℃ for 10h in air. The borosilicate glass with 70 wt％ cullet showed the lowest thermal expansion coefficient of 3.07×10-6/k. Na2O lowered the coefficient of thermal expansion of borosilicate glass. The borosilicate glass with 3 wt% Na2O showed the lower thermal expansion coefficient of 3.13×10-6/k. The bulk density increased with the increase of cullet content. The bulk density and hardness increase with the increase of Na2O content. The thermal shock resistance of borosilicate glass was affected by the cullet and Na2O content. The glass with 70 wt％ cullet showed the highest thermal shock resistance temperature of 160℃；the glass with 50 wt％cullet＋3 wt% Na2O showed the thermal shock resistance temperature of 140℃.

目 錄
中文摘要......................................................................I
英文摘要.....................................................................Ⅱ
誌謝.........................................................................Ⅲ
目錄.........................................................................IV
表目錄............................................VII圖目錄...................................... VIII
第一章  緒論....................................1
1-1  前言............................................................................1
1-2  研究動機與目的...........................................................1
第二章  理論基礎與前人研究....................................................3
2-1  玻璃結構.................................................................3
2-1-1  玻璃之形成.............................................................3
2-1-2  玻璃的結構.............................................................3
2-2  前人研究.................................................................5
2-2-1  B2O3一元系玻璃之結構特徵...............................................6
2-2-2  SiO2－B2O3二元系玻璃系統之特性.........................................7
2-2-3  SiO2－B2O3－R2O三元系玻璃系統之特性....................................7
2-2-4  硼矽酸系玻璃...........................................................8
2-2-5  碎玻璃再利用...........................................................8
第三章  實驗方法與步驟.......................................................21
3-1  實驗用起始原料..........................................................21
3-2  實驗流程................................................................22
3-2-1  Cullet添加對硼矽酸玻璃的影響..........................................22
3-2-2  Na2O添加對硼矽酸玻璃的影響............................................23
3-3  玻璃的熔製..............................................................24
3-3-1  玻璃粉末之製備........................................................24
3-3-2  玻璃成型體之熔製......................................................24
3-4  玻璃性質之測試..........................................................24
3-4-1  感應耦電漿原子放射光譜分析（Inductively Coupled Plasma Atomic Emission  Spectrometer，簡稱ICP）......................................................24
3-4-2  硬度測度..............................................................25
3-4-3  密度測試..............................................................25
3-4-4  X光繞射分析 (X-ray diffractometer analysis)...........................25
3-4-5  傅立葉轉換紅外線吸收光譜儀（Fourier Transform Infrared Spectroscope，簡稱FT-IR）....................................................................26
3-4-6  熱差分析..............................................................26
3-4-7  熱膨脹分析............................................................26
3-4-8  熱震之測定............................................................27
3-5  熔融玻璃之命名..........................................................27
第四章  結果與討論...........................................................30
4-1  玻璃組成之分析..........................................................30
4-2  退火溫度之決定..........................................................30
4-3  玻璃之性質..............................................................31
4-3-1  密度.................................................................31 
4-3-2  硬度..................................................................31
4-3-3  X光繞射分析...........................................................32
4-3-4  FT-IR光譜分析.........................................................32
4-3-5  熱膨脹分析............................................................34
4-3-6  熱差分析..............................................................35
4-3-7  熱震分析..............................................................35
4-3-8  抗彎曲強度分析........................................................36
第五章  結論.................................................................59
第六章  參考文獻.............................................................60
表 目 錄
Table 2-1 Calculated single bond strengths of some oxides....................12
Table 2-2 Classification of cations according to their field strength........15
Table 3-1 Chemical composition of the borosilicate glass.................... 28
Table 3-2 Composition of starting materials..................................29
Table 4-1 ICP analysis of borosilicate glass with various cullet contents
melted at 1500℃ for 10h.....................................................38
Table 4-2 ICP analysis of borosilicate glass with various Na2O contents
melted at 1500℃ for 10h.....................................................39
圖目錄
Fig. 2-1 Contrast of specific volume-versus-temperature behavior of crystalline and non-crystalline materials....................................10
Fig. 2-2 Schematic two-dimensional representation of the structure of 
(a)a hypothetical crystalline compound A2O3 and (b) the glassy form of the same compound................................................................11
Fig. 2-3 Schematic two-dimensional representation of the structure of a sodium silicate glass...............................................................13
Fig. 2-4 Arrangement of Al atom in a sodium silicate glass...................14
Fig. 2-5 Thermal expansion coefficients of alkali borate glasses as a function of composition...............................................................16
Fig. 2-6 Boron-oxygen structural groupings...................................17
Fig. 2-7 Two possible effects of adding Na2O on the borate glass : 
(a) the connection between [BO3] triangles is destroyed to create unshared oxygen, (b) [BO4] tetrahedron formation strengths the network structure......18
Fig. 2-8 The structure of (a) [BO4] ‧4[BO3] (b) [BO4] ‧4[SiO2] exist in borosilicate glass...........................................................19
Fig. 2-9 The application of borosilicate glass...............................20
Fig. 3-1 Flow chart for experiment of borosilicate glass with various cullet contents melted at 1500℃ for 10h............................................22
Fig. 3-2 Flow chart for experiment of borosilicate glass with various Na2O contents melted at 1500℃ for 10h...........................................23 
Fig. 4-1 Thermal-shrinkage expansion curve of borosilicate glass with 100% cullet melted at 1500℃ for 10h and annealed at 530℃ for 3h. ..............40 
Fig. 4-2 Bulk density of borosilicate glass with various cullet contents melted at 1500℃ for 10h. ...................................................41
Fig. 4-3 Bulk density of borosilicate glass with various Na2O contents melted at 1500℃ for 10h. ..........................................................42
Fig. 4-4 Hardness of borosilicate glass with various cullet contents 
melted at 1500℃ for 10h.....................................................43
Fig. 4-5 Hardness of borosilicate glass with various Na2O contents melted at 1500℃ for 10h...............................................................44
Fig. 4-6 XRD patterns of borosilicate glass with various cullet contents
melted at 1500℃ for 10h.....................................................45
Fig. 4-7 XRD patterns of borosilicate glass with various Na2O contents melted at 1500℃ for 10h............................................................46
Fig. 4-8 FT-IR spectra of borosilicate glass with various cullet contents
melted at 1500℃ for 10h.....................................................47
Fig. 4-9 FT-IR spectra of borosilicate glass with various Na2O contents melted at 1500℃ for 10h............................................................48
Fig. 4-10 Thermal-shrinkage expansion curve of borosilicate glass with various cullet contents melted at 1500℃ for 10h.....................................49
Fig. 4-11 Thermal-shrinkage expansion curve of borosilicate glass with various Na2O contents melted at 1500℃ for 10h.......................................50
Fig. 4-12 Thermal expansion coefficients of borosilicate glass with various cullet contents melted at 1500℃ for 10h.....................................51
Fig. 4-13 Thermal expansion coefficients of borosilicate glass with various Na2O contents melted at 1500℃ for 10h.......................................52
Fig. 4-14 DTA curves of borosilicate glass with various Na2O contents........53
Fig. 4-15 OM photograph of C50 melted at 1500℃ for 10h......................54
Fig. 4-16 OM photograph of C50 melted at 1500℃ for 10h......................54
Fig. 4-17 OM photograph of C50 melted at 1500℃ for 10h after thermal shock resistance...................................................................55
Fig. 4-18 OM photograph of C50 melted at 1500℃ for 10h after thermal shock resistance...................................................................55
Fig. 4-19 OM photograph of C50 melted at 1500℃ for 10h after bending test...56
Fig. 4-20 OM photograph of C50 melted at 1500℃ for 10h after bending test...56
Fig.4-21 Thermal shock behavior of borosilicate glass with various cullet contents melted at 1500℃ for 10h............................................57
Fig.4-22 Thermal shock behavior of borosilicate glass with various Na2O
contents melted at 1500℃ for 10h............................................58


                                    

1. O. Peitl, E.D. Zanotto, ”Thermal shock properties of chemical toughened borosilicate glass”, Journal of the Non-Crystalline Solids, 247, 1999, 39-49.
2. R.R. Thmmala, ”Ceramic and Glass-Ceramic Packaging in the 1990s”, Journal of the American Ceramic Society, 74, 1991, 895.
3. 程道腴,鄭武輝,玻璃學, 徐氏基金會, 1973.
4. J. E. Robert, J. C. Swearengen, ”Effect of composition on the mechanical properties of aluminosilicate and borosilicate glasses”, Journal of the American Ceramic Society, 61, 1978, 27-30.
5. 森谷太郎等, 玻璃製造學, 標麟譯, 復文書局, 1987.
6. 作花濟夫等, 新版玻璃手冊, 玻璃與陶瓷編輯部, 1985.
7. M.M. Lima, R. Monterio, ”Characterisation and thermal behavior of a borosilicate glass”, Thermochimica Acta, 373, 2001, 69-74.
8. 紀國鐘,鄭晃忠共著, 液晶顯示器技術手冊, 經濟部技術處, 台灣電子材料與元件協會, 2002, 178.
9. 汪建民等, 陶瓷技術手冊,經濟部技術處, 中華民國粉末冶金協會、中華民國產業發展協進會出版, 1994, 926.
10.黃明鈺, ”廢玻璃容器與地磚坯土混合燒成燒結特性之探討”, 碩士論文, 國立台北科技大學材料及資源工程系, 1999.
11.吳子碩, ”玻璃資源砂應用於水泥原料之研究”, 碩士論文, 國立台北科技大學土木與防災技術系, 2003.
12.侯博震, ”廢玻璃應用於再生瀝青混凝土之研究”, 碩士論文, 雲林科技大學營建工程系, 2003.
13.張添晉、鄭啟樸、連奕偉, ”廢玻璃資源回收管理與再利用技術”, 永續產業發展雙月刊, 第十期, 2003, 67-74.
14.楊家馨, ”台灣地區玻璃工業生態調查”, 碩士論文, 國立台北大學資源管理研究所, 2003.
15. http://www.corning.com/
16. http://www.glassonweb.com/news/index/530/
17. http://www.schott.com/german/
18. Y. Tang, Z. Jiang, ”Phase diagram model for the physical properties of silicate and borosilicate glass systems : density and refractive index
analysis”, Journal of the Non-Crystalline Solids, 189, 1995, 251-257.
19. Sebastien DERIANO, Albert TRUYOL, Jean-Christophe SANGLEBOEUF , Tanguy ROUXEL, ”Physical and mechanical properties of a new borosilicate glass”, Ann. Chim. Sci, Mat 28, 2003, 55-62.
20. 江量佑, ”Ba-FeO-B2O3-Bi2O3磁性玻璃之研究”, 碩士論文, 國立成功大學材料及工程研究所, 1995.
21. Standard definitions of terms relating to glass products, ASTM C162-71, 17, 1978, 112.
22. W.H. Zachariasen, ”Characteristics of glass formation”, Journal of the American Ceramic Society, 54, 1932, 3841.
23. P.W. Mcmillan, ”Glass-ceramics”, 2nd edition, Academic press, London and New York, 1979.
24. K.H. Sun, ”The stages of glasses”, Journal of the American Ceramic Society, 30, 1947, 277.
25. H. Rason and J.E. Stanworth, ”Physical properties of glasses”,
Clarendon press, Oxford, 1950, 215.
26. J. A. Duffy, ”Charges on metal ions in glass”, Solid State Ionic, 105,
1998, 87-90.
27. F. A. Hummel, B. S. Sastry, ”Studies in lithium oxide systems：Li2O-B2O3-SiO2”, Journal of the American Ceramic Society, 43, 1960, 22-33.
28. Roger Araujo, ”Influence of boron-oxygen bonding on glass properties”, Journal of Non-Crystalline Solids, 222, 1997, 25-32.
29. R.A. Smith, ”Boron in glass and glass making,” Journal of the Non-Crystalline Solids, 84, 1986, 421-432.
30. 王承遇等, 儀器玻璃 , 台灣復文興業股份有限公司, 1995.
31. 張淵琮, ”3SiO2•B2O3–Li2O假二元系玻璃分相與結晶行為之研究”, 碩士論文, 國立成功大學地球科學系, 1999.
32. A. Abd El-Moneim, ”Quantitative analysis of elastic moduli and structure of B2O3-SiO2 and Na2O-B2O3-SiO2”, Physica B, 2003, 319-332.
33. M. Massot, S. Souto, M. Balkanski, ”Short and medium range order in ternary borate glasses”, Journal of the Non-Crystalline Solids, 182, 1995, 49-58.
34. K. El-Egili, ”Infrared studies of Na2O–B2O3–SiO2 and Al2O3–Na2O–B2O3–SiO2 glasses”, Physica B, 325, 2003, 340-348.
35. A.H. Verhoef, H.W.den Hartog,”Structure and dynamics of alkali borate glasses A molecular dynamics study”, Journal of the Non-Crystalline Solids, 182, 1995, 235-247.
36. Yasser B.Saddeek, ”Structural analysis of alkali borate glass,” Physica B, 344, 2004, 163-175.
37. E.I. Kamitsos, G.D. Chryssikos, ”Alkali sites in glass”, Solid State Ionics, 105, 1998, 75-85.
38. Kong.L. Loh, Rachel. Boekenhauer, ” The glass transition temperature of lithium borosilicate glasses related to atomic arrangements”, Journal of the Non-Crystalline Solids, 175, 1995, 137-144.
39. S. Polizzi, P. Riello, ”The microstructure of borosilicate glasses containing elongated and oriented phase-separated crystalline particles”, Journal of the Non-Crystalline Solids, 147, 1998, 232-234.
40. E. V. Shavnskii, N. I. Leonyuk, G. Bocelli, L,Righi, ”Crystallization and structural characteristics of new borosilicates”, Journal of Solid States Chemistry, 189, 1995, 251-257.
41. M. Romero and J. Ma. Rincon, ”Prepartion and properties of high iron oxide content glasses obtained from industrial wastes”, Journal of the European Ceramic Society, 18, 1998, 153-160.
42. Luisa Barbieri, Anna Corradi Bonamartini, Isabella Lancellotti, ”Alkaline and alkaline-earth silicate glasses and glass-ceramics from municipal and industrial wastes”, Journal of the European Ceramic Society, 20, 2000, 2477-2483.
43. V.I. Kiyan, ”Variations in glass melt basicity with Maximum introduction of cullet”, Glass and Ceramics, 59, 2002, 5-6.
44. A. Karamberi, A. Moutsatsou, ”Participation of coloured glass cullet in cementitious materials”, Cement & Concrete Composites, 27, 2005, 319-327.
45. N. F. Youssef, M. F. Abadir, M. A. O. Shater, ” Utilization of Soda Glass (Cullet) in the Manufacture of Wall and Floor Tiles”, Journal of the European Ceramic Society, 18, 1998, 1721-1727.
46. G. Scarinci, G. Brusatni, L. Barbieri, A. Corradi, I. Lancellotti, P. Colombo, S. Hreglish, ”Vitrification of industrial and natural wastes with production of glass fibers”, Journal of the European Ceramic Society, 20, 2000, 2485-2490.
47. H.F.Mark,et. Al., ”Enclopedia of chemical technology”,3rd. edition ,John Wiely and Sons Inc, New York, 11, 1980, 883-884
48. W.D. Kingery, H.K. Bowen and D.R. Uhlmann, Introduction to ceramics, 2nd, John Wiely and Sons Inc, New York, 1976.
49. A.J. Stryjak and P.W. McMillan, ”Nucleation and crystallization in glasses”, Mater .Sci, 13, 1947, 30.
50. W. Vogel, ”Chemistry of glass”, Journal of the American Ceramic Society, Inc.Columbus, Ohio, 1985, 154-156.
51. L.D. Pye and V.D. Fr’echette and N.J. Kreidl, ”Borate glasses”, 1977.
52. E. I. Kamitsos, A. P. Patsis, M. A. Karakassides, G. D. Chryssikos, ”Infrared reflectance spectra of lithium borate glass”, Physica B, 325, 2005, 340-348.
53. Wojciech A. Pisarski, Joanna Pisarska, Witold Ryba-Romanowski, ”Structural role of rare earth ions in leas borate glasses evidenced by infrared spectroscopy：BO3↔BO4 conversion”, Journal of Molecular Structure, 744-747, 2005, 515-520.

校內：2006-07-29公開
校外：2006-07-29公開

簡易檢索 / 詳目顯示

相關論文