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研究生: 徐孟群
Hsu, Meng-Chun
論文名稱: 以觸媒分解氧化亞氮氣體引燃混合火箭之研究
Ignition Characteristics of a Hybrid Rocket Using Catalytically Decomposed Nitrous Oxide as the Igniter
指導教授: 趙怡欽
Chao, Yei-Chin
學位類別: 碩士
Master
系所名稱: 工學院 - 航空太空工程學系
Department of Aeronautics & Astronautics
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 79
中文關鍵詞: 氧化亞氮混合火箭觸媒分解點火延遲時間
外文關鍵詞: Nitrous Oxide, hybrid rocket, catalyst decomposition, ignition delay time
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  • 近年來混合式推進系統在太空發展上深受重視,而國內成功大學航太系成功的完成以N2O為氧化劑之混合火箭發動機及飛試元件研製。為因應太空系統的多元發展,本研究提出以N2O經由觸媒分解所產生的高溫燃氣做為混合火箭推進器點火系統的新穎構想,可有效簡化混合火箭點火系統,同時可以達到混合火箭重複點火的目的,進而發展一套多功能火箭系統。
    研究中以過去發展30公斤推力級之N2O混合火箭為基礎,發展一套以同軸觸媒點火反應器與30公斤推力藥柱之整合式混合火箭發動機系統。本研究中將自N2O分解觸媒之研製、改良、分解測試開始,分析找出自主研製之觸媒的分解特性,並進而探討不同噴注器設計對於以觸媒分解氣體引燃混合火箭藥柱的點火延滯時間與點火操作特性的影響。
    本研究利用自主發展的銥氧化物觸媒成功的使N2O有良好的分解反應,並透過分解反應測試找出預熱系統為60、70W下觸媒之負載能力,確認觸媒於推進系統上的適用性。另外,以此觸媒測試結果,在N2O流量為0.32g/s下利用其分解熱氣探討軸向噴注器在不同雷諾數與背向階梯擴張比例對於點火延遲時間之影響;並進一步設計渦旋噴注器以增進藥柱引燃,並進行測試,發現在雷諾數較小時搭配背向階梯效應所產生之迴流區,能使藥柱快速引燃。透過實驗測試找出最適當的重複點火機制。

    The objective of this research is to develop a hybrid rocket igniter via using catalytically decomposed N2O to thermally ignite the fuel grain. The hybrid rocket program has been developed in National Cheng-Kung University for years. The hybrid rocket motor using liquid N2O as the oxidizer has been designed and demonstrated successfully. Accordingly, the novel ignition technology is necessitated to accomplish the feasibility of multi-function propulsion for spacecraft missions. In this research, manufacture, modification and demonstration of catalyst for N2O decomposition are addressed, and analyzing characteristics of N2O decomposition via laboratory-made catalysts is also conducted. Catalytically decomposed gas attempts to thermally ignite the hybrid rocket fuel grain, so that the configuration and layout of injection system are essential and pivot in ignition system. Consequently, corresponding effects of injector configuration on ignition delay and operational characteristics are further investigated in the study.
    As to the laboratory-made catalyst, iridium oxide is impregnated onto metal meshes. The catalytic decomposition characteristics of nitrous oxide are performed via using 60-70W pre-heating system. Results confirm the feasibility of the laboratory-made catalyst applied in propulsion system. Therefore, according to the result of catalytic decomposition test, the N2O flow rate is fixed in 0.32g/s for ignition testing. The axial and swirl injectors are applied separately to discuss the effect of various Reynolds number and expansion ratio on the ignition delay time. The experimental results show the recirculation region induced by backward- facing step would apparently accelerate the ignition of fuel grain in low Reynolds number condition. Eventually, the proper multi-ignition mechanism of hybrid rocket is successfully verified and demonstrated by the series of experiments.

    摘要 I Abstract III 誌謝 V 目錄 VII 表目錄 IX 圖目錄 X 符號 XII 第一章 緒論 1 1-1混合火箭簡介 1 1-1.1混合火箭基本特性介紹 1 1-1.2 混合火箭演進 5 1-1.3 近代國內外混合火箭系統研究 7 1-2研究動機與目的 9 第二章 文獻回顧與理論分析 11 2-1 N2O觸媒分解概念與應用 11 2-1.1 觸媒反應基本原理 11 2-1.2 N2O分解特性 12 2-1.3 N2O活性物質及載體選擇 14 2-2混合火箭藥柱基本特性 16 2-2.1 燃料退縮率問題 16 2-2.2 HTPB(Hydroxyl Terminated Polybutadiene) 17 2-2.3 石蠟燃料(Paraffin) 18 2-3 混合火箭點火特性分析 18 2-4 點火模式評估 20 2-5 渦旋噴注器設計概念 20 第三章 實驗設備與方法 25 3-1觸媒製作 25 3-1.1 觸媒製作設備 25 3-1.2 N2O分解用觸媒之製備 26 3-2 藥柱製作 27 3-3實驗測試設備 28 3-3.1觸媒及小藥柱點火測試系統 28 3-3.2 30公斤級大藥柱測試系統 30 3-3.3 實驗數據擷取系統 31 3-4實驗步驟及方法 31 第四章 觸媒反應性能測試 33 4-1 觸媒反應性能初步測試 33 4-2 電熱系統與觸媒負載能力關係 34 4-3 觸媒披覆量與反應性能關係 35 第五章 混合火箭藥柱點火測試 37 5-1 30kg推力級整合型混合火箭觀察與評估 37 5-2 引火型藥柱初步測試 38 5-3軸向噴注器與點火延滯時間探討 39 5-4 渦旋噴注器與點火關係探討 41 5-4.1 新式渦旋噴注器設計 41 5-4.2 新式渦旋噴注器測試結果 42 5-5 多次引燃小藥柱機制 44 第六章 結論及未來工作 45 6-1 結論 45 6-2 未來工作 47 參考文獻 48 自述 79

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