| 研究生: |
詹博旭 CHAN, PO-HSU |
|---|---|
| 論文名稱: |
氧化鋅摻雜氧化釩多層膜之結構與磁性研究 Structure and magnetic properties of V2O5 doped ZnO thin film |
| 指導教授: |
黃榮俊
Huang, Jung-Chun |
| 學位類別: |
碩士 Master |
| 系所名稱: |
理學院 - 光電科學與工程研究所 Institute of Electro-Optical Science and Engineering |
| 論文出版年: | 2007 |
| 畢業學年度: | 95 |
| 語文別: | 中文 |
| 論文頁數: | 91 |
| 中文關鍵詞: | 氧化鋅 、氧化釩 |
| 外文關鍵詞: | ZnO, V2O5 |
| 相關次數: | 點閱:44 下載:1 |
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本論文工作是使用離子束濺鍍系統成長[ZnO/V2O5]多層膜。實驗分成兩部份。第一部份為改變V2O5摻雜厚度,第二部份是將多層膜作高真空退火處理,研究多層膜電性及結構特性。
由SQUID量測多層膜特性,顯示樣品呈現鐵磁性,並隨退火溫度產生不同的變化,[ZnO(20Å)/V2O5(1Å)]25多層膜磁性隨退火溫度上升而變強,[ZnO(20Å)/V2O5(3Å)]25多層膜磁性隨退火溫度上升而變弱,[ZnO(20Å)/V2O5(2Å)]25多層膜變化則介於兩者之間,磁性來源我們以磁性極化子模型來解釋,發現氧空缺和薄膜磁性變化有著重要的關係。
In this study,we deposited [ZnO(20Å)/V2O5(xÅ)](x =1,3) films on Al2O3(0001) substrate by an ion beam sputter. The structural, electrical and magnetic properties of [ZnO/V2O5] films annealed at 200,400 and 600℃ have been investigated.The results of x-ray diffraction reveal no detectable V clusters or formation of secondary phases. The ferromagnetism of [ZnO(20Å)/ V2O5 (1Å)] films increased as the annealing temperature was decreased. However, the ferromagnetism of [ZnO(20Å)/V2O5(3Å)] films decreased as the annealing temperature was increased.The results suggest that ferromagnetism in [ZnO/ V2O5] comes from an intrinsic factor highly correlated to the oxygen vacancy defects.The dopant V2O5 played an important role effect defects in [ZnO/V2O5] films.
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