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研究生: 張靜宜
chang, ching-i
論文名稱: 側向磊晶技術成長氮化鎵之研究
The Investigation on GaN Growth by Epitaxial Lateral Overgrowth
指導教授: 劉全璞
Liu, Chuan-Pu
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 169
中文關鍵詞: 氮化鎵側向磊晶
外文關鍵詞: ELO, ELOG, GaN
相關次數: 點閱:31下載:1
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  •   本研究是使用磊晶側向成長法(Epitaxial Lateral Overgrowth, ELOG)的技術,利用有機化學氣相沈積法(metal organic chemical vapor deposition, MOCVD )來成長氮化鎵的膜,研究不同的mask fill factor對氮化鎵特性的影響及穿遂差排的影響,從SEM照片發現在同樣的成長條件下,當mask fill factor等於1的時候氮化鎵幾乎已經成為膜,但是當mask fill factor等於5時卻還是獨立的錐狀體,在X-ray的rocking curve中發現不同的mask fill factor在c軸方向的偏斜程度也不一樣,在光學分析的結果是比較一致的,主要發光波長都為3.4eV在Yellow Luminescence的中心位於2.3eV。在穿透式電子顯微鏡(TEM)的分析中,有明顯的看見差排彎曲的現象,這也達到這個製程的目的。

     The optical performance of a GaN blue-light emitting diode is greatly influenced by the density and distribution of threading dislocations, which in turn strongly depend on the ratio of mask to window width during Epitaxial Lateral Overgrowth (ELOG). Thus we study the dependence of microstructure and optical property evolution on the spatial distribution of the defects in the ELOG GaN films by varying mask to window width ratio. The window width is maintained at 5μm and the ratio is varied from one to five. We employ a two-step ELOG method to fabrication GaN by Metalorganic chemical vapor deposition (MOCVD), where SiO2 as the mask was grown on low-temperature GaN as the buffer and seed layer. The patterns were square dot array and developed by conventional photolithography method, where the ELOG GaN stripes on SiO2 were arranged along the directions of the underlying GaN. X-ray rocking curves show that all the resulting films are of excellent epitaxial quality with non-uniform strain distribution, which was a function of the mask ratio and determines the spatial distribution of threading dislocations. The detailed GaN island evolution was also revealed by scanning electron microscopy. Photoluminescence and cathodoluminescence examine the origins of UV and yellow emissions, which can be explained by defect generation as examined by transmission electron microscopy. The mechanism for impeding threading dislocations is discussed.

    第一章 緒論.......................................1  1-1前言.........................................1  1-2研究動機及目的...............................2 第二章 理論基礎及研究回顧.........................4  2-1氮化鎵材料文獻回顧...........................4    2-1.1III族氮化物結構簡介....................4    2-1.2氮化鎵相關元件製作法展史...............5    2-1.3氮化鎵材料在白光照明上的應用...........7  2-2磊晶成長基板的選擇...........................9    2-2.1藍寶石(sapphire)......................12    2-2.2碳化矽(Silicon Carbide)...............21    2-2.3矽(Silicon)...........................27  2-3緩衝層(buffer layer)的介紹..................29    2-3.1氮化鋁緩衝層(AlN).....................30    2-3.2氮化鎵緩衝層(GaN).....................34    2-3.3多層氮化鎵及氮化鋁緩衝層..............39  2-4 Epitaxial Lateral Overgrowth (ELOG)製程的演進.................................................40    2-4.1簡介Epitaxial Lateral Overgrowth製程..41    2-4.2Facet-initiated ELO (FIELO)製程簡介...45    2-4.3PENDEO epitaxy (PE)製程簡介...........45    2-4.4Utilization of other mask的利用.......47    2-4.5Air-bridged ELO(ABLEG)製程簡介......47    2-4.6介紹Production of grooved stripe structure........................................50    2-4.7 Facet-Controlled Epitaxial Lateral Overgrowth(FACELO)製程簡介.................................52 第三章 實驗方法及步驟............................56  3-1 Epitaxial Lateral Overgrowth製程成長氮化鎵.56    3-1.1實驗流程..............................56    3-1.2實驗藥品及材料........................58    3-1.3實驗設備..............................58    3-1.4參數設定..............................59  3-2分析方法....................................62    3-2.1掃瞄式電子顯微鏡......................62    3-2.2多功能X光薄膜繞射儀...................63    3-2.3光致螢光光譜..........................65    3-2.4穿透式電子顯微鏡......................66 第四章 結果......................................67  4-1ELOG氮化鎵表面型態..........................67  4-2ELOG氮化鎵rocking curve分析.................80  4-3ELOG氮化鎵的光學性質........................92    4-3.1ELOG氮化鎵光致螢光性質量測............92    4-3.2ELOG氮化鎵陰極光特性.................105  4-4ELOG氮化鎵穿透式電子顯微鏡(TEM)分析........111 第五章 討論.....................................131  5-1成長條件與表面形態的關係...................131 第六章 結論.....................................145 第七章 參考文獻.................................147

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