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研究生：	李奕慧 Lee, Yi-Hui
論文名稱：	含瀝青基材之碳/碳複合材料製程及性質研究
指導教授：	朱建平 Ju, Chien-Ping 陳瑾惠 Chern Lin, Jiin-Huey
學位類別：	碩士 Master
系所名稱：	工學院 - 材料科學及工程學系 Department of Materials Science and Engineering
論文出版年：	2005
畢業學年度：	93
語文別：	中文
論文頁數：	126
中文關鍵詞：	磨耗、碳/碳複合材料
外文關鍵詞：	Wear, Carbon/Carbon Composites
相關次數：	點閱：66 下載：3
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　　碳/碳複合材料具有高比強度，質輕的特性，縱使在高溫環境下，只須在適當的保護氣氛或另添加元素改善，可保有其良好的機械性質，另外其製成的物件重量遠比鋼鐵材料來得輕，因此碳/碳複合材料是製作飛機煞車材料的最佳選擇。

　　本實驗主要研究PAN系碳纖維補強酚醛樹脂基材之碳/碳複合材料，藉由改變含浸材料及基材添加物的方式，在生胚成型後經穩定化、快速碳化、石墨化、緻密化及最終石墨化處理，製備碳/碳複合材料，其中緻密化處理以液態含浸法(Liquid Impregnation Method)來提升材料性質。量測材料的基本性質與機械性質，另外包括摩擦係數、磨耗量及磨耗面觀察等磨潤性質，討論各參數對於碳/碳複合材料機械及磨耗性質之影響。

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中文摘要............................................................I
誌謝...............................................................II
目錄..............................................................III
表目錄.............................................................VI
圖目錄............................................................VII
第一章 前言.........................................................1
第二章 文獻回顧.....................................................3
1 碳/碳複合材料之發展與性質.......................................3
1.1 碳/碳複合材料之研究發展.......................................3
1.2 碳/碳複合材料應用領域.........................................3
1.3 碳/碳複合材料之性質...........................................5
2 碳纖維之介紹....................................................6
2.1 碳纖維之編織方式..............................................6
2.2 補強材碳纖維之種類............................................6
3 基材、添加材及含浸材之介紹......................................9
3.1 酚醛樹脂......................................................9
3.2 煤焦瀝青.....................................................10
3.3 中間相瀝青...................................................10
3.4 碳黑.........................................................11
3.5 石墨.........................................................11
4 碳/碳複合材料製程..............................................13
4.1 重覆含浸對材料之影響.........................................13
4.2 穩定化.......................................................13
4.3 碳化.........................................................14
4.4 石墨化.......................................................15
5 材料磨潤性質研究...............................................16
5.1 磨潤簡介.....................................................16
5.2 碳/碳複合材料之磨潤研究......................................17
第三章 實驗........................................................32
1 實驗材料.......................................................32
1.1 基材.........................................................32
1.2 補強材.......................................................32
1.3 添加材.......................................................32
1.4 含浸材.......................................................32
2 實驗製程.......................................................33
2.1 材料準備.....................................................33
2.2 熱壓.........................................................33
2.3 穩定化.......................................................33
2.4 碳化.........................................................34
2.5 石墨化.......................................................34
2.6 真空重覆含浸.................................................34
3 性質量測及分析.................................................36
3.1 厚度變化測量.................................................36
3.2 重量測量.....................................................36
3.3 密度及孔隙度測量.............................................36
3.4 三點彎曲測試.................................................37
3.5 抗壓測試.....................................................38
3.6 磨耗性質測試.................................................38
3.7 光學相機觀察.................................................39
3.8 掃描式電子顯微鏡觀察.........................................39
第四章 結果與討論..................................................45
1 不同含浸材對碳/碳複合材料性質的影響............................45
1.1 密度、孔隙度、重量與厚度的變化...............................45
1.2 緻密化過程中密度、孔隙度、重量與厚度的改變...................47
1.3 磨耗性質.....................................................48
1.4 磨耗面SEM觀察................................................51
1.5 撓曲強度及模數性質...........................................54
1.6 抗壓強度性質.................................................54
2 不同添加物選用含浸材II對碳/碳複合材料性質的影響................80
2.1 密度、孔隙度、重量與厚度的變化...............................80
2.2 緻密化過程中密度、孔隙度、重量與厚度的改變...................82
2.3 磨耗性質.....................................................83
2.4 撓曲強度及模數性質...........................................84
3 不同添加物選用含浸材PM對碳/碳複合材料性質的影響...............101
3.1 密度、孔隙度、重量與厚度的變化..............................101
3.2 緻密化過程中密度、孔隙度、重量與厚度的改變..................102
3.3 磨耗性質....................................................103
3.4 撓曲強度及模數性質..........................................105
第五章 結論.......................................................121
第六章 參考文獻...................................................123
                                    

Awasthi S. and Wood J.L., “C/C Composite Materials for Aircraft Brakes”, Ceram. Eng. Sci. Proc., vol.9, pp.553-560, 1988.
Bowden F.P. and Tabor D., “The friction and lubrication of solids”, Part2, Oxford University, Oxford, 1950.
Bragg W.L., “Introduction to Crystal Analysis”, Bell&Sons, London, pp.64, 1928.
Clark K.T. and Lancaster J.K., “Breakdown and Sliding”, Wear, vol.6, pp.467-482, 1963.
Dowson D., Godet M. and Taylor C.M., “The Wear of Non-Metallic Materials., Session XIII：The Wear of Graphite”, in Proceeding of the 3rd Leeds-Lyon Symposium on Tribology, pp.187-211, 1976.
Fitzer E. and Manocha L.M., “Carbon reinforements and carbon/carbon composites”, Springer, Germany, 1998.
Jenkins G.M. and Kawamura K., “Polymeric carbons-carbon fibre, glass and char”, Cambridge University Press, Great Britain, pp.14, 1976.
John D.B. and Dan D.E., “Carbon-carbon materials and composites”, Noyes Publications, U.S.A., pp.116, 1993.
Kenneth G. and Budinski, “Surface Engineering for Wear Resistance”, Prentice Hall. Englewood Cliffs, New Jersey, 1988.
Ko T. H. and Ma T. S., “Effect of post-curing on the mechanical properties of carbonized phenolic resins”, Polymer composites, vol.19, no.4, 1998.
Lancaster J.K., “Transitions in the Friction and Wear of Carbons and Graphites Sliding Against Themselves”, ASLE Transactions, vol.183, pp.187-201, 1975.
Laušević Z. and Marinković S., “Mechanical properties and chemistry of carbonization of phenol formaldehyde resin”, Carbon, vol.24, no.5, pp.575-580, 1986.
Lee K.J., Chern Lin J.H. and Ju C.P., “Surface effect on braking of PAN-pitch carbon-carbon composite”, Wear, vol.199, pp.228-239, 1996.
Matzinos P.D., Patrick J.W. and Walker A., “Coal-tar pitch as a matrix precursor for 2-D C/C composites”, Carbon, vol.34, no 5, pp.693-644, 1996.
Matzinos P.D., Patrick J.W. and Walker A., “The void structure of 2D C/C performs and composites：effect of the nature of the matrix precursor coal-tar pitch”, Carbon, vol.35, no.4, pp.507-513, 1996.
Mckee D.W., “Oxidation behavior and protection of carbon/carbon composites”, Carbon, vol.25, no.4, pp.551-557, 1987.
Mckee D.W., “Oxidation behavior of matrix-inhibited carbon/carbon composites”, Carbon, vol.26, no.5, pp.659-665, 1988.
Michael and Niu C.Y., “Composites Airframe Structure”, pp.62-65, 1992.
Moore D.F., “Principles and Application of Tribology”, Pergamon, Great Britain, pp.177-202, 1975.
Murdie N., Don J., Kocher C., Liew R. and Ju C.P., “Microstructural Analysis of C-C Composites Used in Aircraft Braking Applications”, Proc. 13th Ann. Conference on Metal Matrix, Carbon, and Ceramic Matrix Composites, J.D.Buckley ed., pp.349-365, Jan.18-21, Cocoa Beach, FL, 1989.
Murdie N., Ju C.P., Don J. and Fortunato F.A., “Microstructure of Worn Pitch/Resin/CVI C-C Composites”, Carbon, vol.29, pp.335-342, 1991.
Pérez M., Granda M., Santamaría R., Menéndez R., “Preventing mesophase growth in petroleum pitch by the addition of coal-tar pitch”, Carbon, vol.41, pp.1854-1857, 2003.
Romovacek G.R., “The determination of the quinoline-insoluble (QI) content of tar and pitch”, 1984.
Ruppe J.P., “Today and the Future in Aircraft Wheel and Brake Development”, Canadian Aeronautics and Space Journal, vol.26, pp.209-216, 1980.
Savage G., “Carbon-carbon composites”, Chapman&Hall, Great Britain, pp.121, 1993.
Schmidt D.L., Sampe J, 8, 9, 1972.
Stanton G.E., “New Designs for Commercial Aircraft Wheel and Brakes”, Journal of Aircraft, vol.5, pp.73-77, 1968.
Tatarzycki E.M. and Webb R.T., “Friction and Wear of Aircraft Brakes” in “Friction, Lubrication, and Wear Technology”, ASM Handbook, vol.18, ASM International, pp.582-587, 1992.
Thomas C.R., “Essentials of carbon-carbon composites”, Royal Society of Chemistry, Great Britain, pp.20, 1993.
Trick K.A. and Saliba T.E., “Mechanisms of the pyrolysis of phenolic resin in a carbon/phenolic composite”, Carbon, vol.33, no.11, pp.1509-1515, 1995.
Tzeng S.S., Pan J.H., “Densification of two-dimensional carbon/carbon composites by pitch impregnation”, Materials Science and Engineering, A316, pp.127-134, 2001.
Weaver J.V., “Advanced Materials for Aircraft Brakes”, Aeronotical Journal, pp.695-698, 1972.
Yamashita Y. and Ouchi K., “A study on carbonization of phenol-　 formaldehyde resin labelled with deuterium and 13C”, Carbon, vol.19, pp.89-94, 1981.

方名達、顏瑞賓、董健光，中鋼碳素化學公司發展現況介紹，第三屆兩岸碳材料研討會，pp.26，2004年.
柯澤豪，碳/碳複合材料的現況及未來，工業材料，第95期，1994年.
許明發，郭文雄編著，複合材料，高立圖書有限公司，1998年.
許明發，碳、碳纖維、碳/碳複合材料之加工技術及應用，滄海書局，1997年.
郭華軒，碳化速率對碳/碳複合材料機械及磨潤性質影響之研究，國立成功大學材料科學及工程研究所博士論文，2004年.
陳金多，碳-碳複合材料等速磨潤性質研究，國立成功大學材料科學及工程研究所博士論文，1995年.
陳聖孟，不同添加物及基材對碳/碳複合材料磨潤性質之影響，國立成功大學材料科學及工程研究所碩士論文，2004年.
游錫揚，纖維複合材料，國彰出版社，pp.252，1997年.
稻桓道夫，大谷杉郎，大谷朝男共著，賴耿陽編著，碳材料碳纖維工學，復漢出版社，1986年.
賴耿陽，碳材料化學與工學，復漢出版社，pp82-152，1991年.
藍緯洲，碳/碳複合材料之耐高溫氧化研究，國立成功大學材料科學及工程研究所碩士論文，1993年.

校內：2010-07-13公開
校外：2010-07-13公開

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