本論文以助熔長晶法，合成出兩種不同結構系統之八個金屬硫族化合物。分別為第一個系統六個化和第二系統兩個化合物。
第一個系統六個化合物皆為等結構，其晶系屬於非中心對稱空間群，且因置換元素不同致晶格大小有所差異。由化合物的能隙、紅外-可見光區的穿透度及拉曼光譜圖顯示出此化合物在紅外光區具有非線性應用潛力。
第二系統兩個化合物亦為等結構。由能隙和兆赫波時域光譜儀發現在兆赫波段有良好穿透度，搭配其窄能隙對應於長程光通訊波段，期望能應用於此波段中兆赫波源發射器上的光電導元件。

Eight new compounds have been synthesized through solid state reactions using a KBr flux to promote crystal growth.
Six compounds of first system all are isostructures crystallizing in the non-centrosymmetric space group. The characterizations of band gap, transmission in the uv-vis-ir range, and raman spectroscopy support that these compounds have the potential application as the non-linear optical crystals applied in the infrared ranges.
Both 5 and 6 adopt same three-dimensional structure. The band gap of 5 and 6 characterized by UV-Vis-NIR spectrum. At last, we prove compound 5 have good transmission in 0.1~0.5 THz region by Terahertz Time-Domain Spectroscopy and expect it can be used to in optical communications.

1.Petrov, V.; Badikov, V.; Panyutin, V., Nato Science for Peace and Security Series B: Physics and Biophysics 2008, 1, 105-147.
2.Schunemann, P. G., Proc. of SPIE 2007, 6455, 64550R-64550R-7.
3.Kang, S. B., ETRI Journal 2009, 31, 667-674.
4.Gallot, G.; Zhang, J.; McGowan, R. W.; Jeon, T.-I.; Grischkowsky, D., Applied Physics Letters 1999, 74, 3450.
5.Rama Venkatasubramanian, E. S., Thomas Colpitts & Brooks O'Quinn, NATURE 2001, 413, 597-602.
6.Bilc, D.; Mahanti, S.; Quarez, E.; Hsu, K.-F.; Pcionek, R.; Kanatzidis, M., Physical Review Letters 2004, 93.
7.Chung, I.; Jang, J. I.; Malliakas, C. D.; Ketterson, J. B.; Kanatzidis, M. G., Journal of the American Chemical Society 2010, 132, 384-389.
8.D. H. Auston, e. a., Appl.Opt 1986, 26, 211.
9.Bordui, P. F.; Fejer, M. M., Annu. Rev. Mater. Sci. 1993, 23, 321-379.
10.Zumsteg, F. C., Journal of Applied Physics 1976, 47, 4980-4985.
11.Bryan, D. A.; Gerson, R.; Tomaschke, H. E., Applied Physics Letters 1984, 44, 847-849.
12.Valencia, S.; Crassous, A.; Bocher, L.; Garcia, V.; Moya, X.; Cherifi, R. O.; Deranlot, C., NATUREMATERIALS 2011, 10, 753-758.
13.Chen, C.; Wu, Y.; Jiang, A.; Wu, B., J. Opt. Soc. Am. B 1989, 6, 616-621.
14.Abrahams, S. C., The Journal of Chemical Physics 1973, 59, 1625-1629.
15.Badikov, V.; Mitin, K.; Noack, F.; Panyutin, V.; Petrov, V.; Seryogin, A.; Shevyrdyaeva, G., Optical Materials 2009, 31, 590-597.
16.Feichtner, J. D.; Roland, G. W., APPLIED OPTICS 1972, 11, 993-998.
17.Vodopyanov, K. L.; Ganikhanov, F.; Maffetone, J. P.; Zwieback, I.; Ruderman, W., OPTICS LETTERS 2000, 25, 841-843.
18.Abrahams, S. C., The Journal of Chemical Physics 1974, 61, 1140-1146.
19.L.Panyutin, V.; I.Zagumennyi, A.; Zerrouk, A. F.; Noack, F.; Petrov, V., Conference on Lasers and Electro-Optics CLEO'09, Baltimore (MD), USA, 2009.
20.Yao, J.; Mei, D.; Bai, L.; Lin, Z.; Yin, W.; Fu, P.; Wu, Y., Inorganic chemistry 2010, 49, 9212-6.
21.Geng, L.; Cheng, W. D.; Lin, C. S.; Zhang, W. L.; Zhang, H.; He, Z. Z., Inorganic chemistry 2011, 50, 5679-86.
22.Kim, Y.; Seo, I.-s.; Martin, S. W., Chem. Mater. 2008, 20, 6048-6052.
23.Lekse, J. W.; Moreau, M. A.; McNerny, K. L.; Yeon, J.; Halasyamani, P. S.; Aitken, J. A., Inorganic chemistry 2009, 48, 7516-8.
24.(a) Sheldrick, G. M., SHELXL-97, Program for the solution of Crystal Structure, University of Göttingen, Germany, 1997. (b) Sheldrick, G. M., SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
25.Chung, D.-Y.; Choi, K.-S.; Iordanidis, L.; Schindler, J. L.; Brazis, P. W.; Kannewurf, C. R.; Chen, B.; Hu, S.; Uher, C.; Kanatzidis, M. G., Chem. Mater. 1997, 9, 3060-3071.
26.V.Petrov; V.Badikov, Optics Communication 2004, 235, 219-226.
27.Panyutin, V.; Badikov, V.; Shevyrdyaeva, G.; Mitin, K.; Seryogin, A.; Petrov, V.; Noack, F., 2008, 6875, 68750A-68750A-12.
28.Aaron Wold,Chimie Minerale A, U.E.R. de Chimie,Faculte des Science de Nantes 33,Boulevard Michelet, B.P.1044, Naantes, France(1976).
29.Ollitrault-Fichet, R.; Rivet, J.; Flahaut, J.; Daher, H.; Khanafer, M., Journal of the Less-Common Metals 1988, 138, 241-261.
30.Iyer, R. G.; Aitken, J. A.; Kanatzidis, M. G., Solid State Sciences 2004, 6, 451-459.
31.李青翰.林凡異(2009)，「兆赫波漫談」，物理雙月刊，卅一卷二期，31，頁97-108。
32.Siegel, P. H., IEEE TRANSACTIONS ON MICROWAVE THEORY AND TECHNIQUES 2002, 50, 910-928.
33.Dragoman, D.; Dragoman, M., Progress in Quantum Electronics 2004, 28, 1-66.
34.Davies, A.; Linfield, E.; Johnston, M. B., Phys. Med. Biol. 2002, 47, 3679-3689.
35.黃正雄(2009)，「兆赫輻射在半導體光電特性研究與成像檢測的應用」，物理雙月刊，卅一卷二期，31,頁127-134。
36.朱贊嘉(2007)，「利用覆晶技術結合近彈道傳輸光檢測器與共平面波導耦合線濾波器在K頻段非線性光電混波應用」，國立中央大學電機工程研究所碩士論文。
37.Bolkhovityanov, Y. B.; Pchelyakov, O. P., Physics-Uspekhi 2008, 51, 437-456.
38.Tani, M.; Lee, K.-S.; Zhang, X. C., Applied Physics Letters 2000, 77, 1396-1398.
39.Ito, H.; Kodama, S.; Muramoto, Y.; Furuta, T.; Nagatsuma, T.; Ishibashi, T., IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS 2004, 10, 709-727.
40.JDSU. Ultra-reliable AlGaInAs Diode Laser Technology Impacts the Industrial Laser Marketplace. 2003.
41.陳豪志(2010)，「兆赫波反共振中空波導原理及應用」，國立成功大學光電科學與工程研究所碩士論文。
42.Deiseroth, H. J.; Reiner, C., Z. anorg. allg. Chem. 1998, 624, 1839-1845.
43.Deiseroth, H.-J.; Reiner, C.; Xhaxhiu, K.; Schlosser, M.; Kienle, L., Zeitschrift for anorganische und allgemeine Chemie 2004, 630, 2319-2328.
44.Dronskowski, R., Inorg. Chem. 1994, 33, 6201-6212.
45.Reiner, C.; Deiseroth, H.-J.; Schlosser, M., Z. anorg. allg. Chem. 2002, 628, 249-257.
46.Likforman, P. A.; Guittard M.; Jaulmes, S. Acta Cryst. 1984, C40, 917.