本研究係以ethylene carbonate與propylene carbonate以及diethylcarbonate 三種有機溶劑以實驗設計法配置不同比例的電解液組裝鈕釦型電池進行測試，將測試結果利用迴歸方程式並繪製成等高線圖，由迴歸結果顯示第一次充放電的最大不可逆電容量損失落在X2（EC：PC：DEC＝1：2：2），而低溫下充放電的效率以及0.2C充放電的效率均落在X1（EC：DEC＝3：2），此結果可以從電解液之特性上獲得合理之解釋。
更進一步，我們研究12-Crown-4和Butane Sultone兩種添加劑加入PC為主體的電解液中對於電池性能的影響，結果顯示兩種添加劑的加入均可減少第一次充放電的不可逆電容量，另外由CV圖結果顯示12-Crown-4的添加確實可以抑止電解液的分解，以及提高鋰離子在碳極上的嵌入以及反嵌入的可逆性。

In this research, ternary organic electrolyte consisting of ethylene carbonate (EC), propylene carbonate (PC) and diethylcarbonate (DEC) were prepared using the methodology of mixture design. The performance of the mixed electrolytes were tested via sealing the electrolyte into a coin cell. The results were fitted by empirical regression equation and then plotted as the contour diagrams. The data show that the maximum coulombic efficiency and the rate capability were appeared at point X1（EC：DEC＝3：2） . The results can be reasonably explained from the physical properties of these organic electrolyte.

Furthermore, we aslo studied the effect of the addition of 12-Crown-4 and Butane Sultone, respectively, for the performance of the lithium ion batteries. Results revealed that the addition of these two additives will reduce the irreversible capacitance of the first charge and discharge cycle. Cyclic voltammorgam shows 12-Crown-4 additive can prevent the decomposition of the electrolyte with the graphite and increase the reversible for intercalation and deintercalation of lithium ion.

1. 費定國、李桐進, “鋰電池專題報導”, 能源、資源與環境, 3卷, 1期, P10～19, 1990.
2. 梁桂肇, “小型二次電池的充電特性比較”, 小型二次電池市場與技術專輯, P9～18, 1996.
3. 張維志, “小型二次電池市場分析”, 小型二次電池市場與技術專輯, P19～22, 1996.
4. 李桐進, “鎳氫化物電池之特性、應用及市場”, 小型二次電池市場與技術專輯, P108～111, 1996.
5. 費定國、王國賢, “呼之欲出—鎳氫化物電池產業”, 小型二次電池市場與技術專輯, P104～107, 1996.
6. 李敏昌, “日本SONY鋰離子二次電池研發歷史”, 小型二次電池市場與技術專輯, P40～48, 1996.
7. M. Stainer, L. C. Hardy, D. H. Whitmore, and D. F. Shriver, J. Electrochem. Soc., 131, 784(1984).
8. M. Yakoyama, H. Ishihara, I. H. Iwamoto, and H. Tasokoro, Macromolecules, 2, 184(1969).
9. Y. Matsuda, H. Hayashida and M. Morita, Denki Kagaku, 53, 628 (1985)
10. M. Morita, H. Hayashida, Y. Matsuda, J. Electrochem. Soc, 134, 2107 (1987)
11. G, Nagasubramanian, A. I. Attia and G. Halpert, J. Electrochem. Soc, 139, 3043 (1992)
12. M. Andrei, J. M. G. Cowie and P. Prosperi, Electrochim. Acta, 37, 1545 (1992)
13. Z. X. Shu, R. S. McMillan and J. J. Murray, J. Electrochem. Soc, 140, L101 (1993)
14. Y. Ein-Eli, S. R. Thomas and V. R. Koch, J. Electrochem. Soc, 143, L195 (1996)
15. Y. Ein-Eli, S. R. Thomas and V. R. Koch, J. Electrochem. Soc, 144, 1159 (1997)
16. Yang, C. H.; Li, Y. J. Wen, T. C.; Ind. Eng. Chem. Res., 36, 1614(1997)
17. Lin, S. M.; Wen, T. C.; J. Appl. Electrochem., 23, 487(1993)
18. Yang, C. H.; Yang, H. J.; Wen, T. C.; Wu, M. S.; Chang, J. S.; Polymer, 40, 871(1999).
19. Dey, A. N.; Sullivan, B. P.; J. Electrochem. Soc, 117, 222 (1970)
20. Basenhard, J. O.; Fritz, H. P.; J. Electroanal. Chem, 53, 329(1974)
21. Eichinger, G. J.; J. Electroanal. Chem, 74, 183(1976)
22. Arakawa, M.; Yamaki, J.; J. Electroanal. Chem, 219, 273(1978)
23. Fong, R.; von Sacken, U.; Dahn, J. R. J. Electrochem. Soc. 137, 2009 (1990)
24. Peled, E. J. Electrochem. Soc. 126, 2047 (1997)
25. Peled, E. Handbook of Battery Materials; Besendhard, J. O., Ed.; Wiley-VCH: Weinheim, 1999; p419
26. Dudley, J. T.; Wllkinson, D. P.; Thomas, G, .; LeVae, R.; Woo, S.; Blom, H.; Horvath, C.; Juzkow, M. W.; Denis, B.; Juric, P.; Aghakian, P.; Dahn, J. R. J. Power Source 35, 59(1991)
27. Nakamura, H.; Komatsu, H.; Yoshio, M. J. Power Source 62, 219(1996)
28. Wrodnigg, G. H.; Besenhard, J. O.; Winter, M. J. Electrochem. Soc. 146, 470(1999)
29. Fujimoto, H.; Fujimoto, M.; Ikeda, H.; Ohshita, R.; Fujitani, S.; Yonezu, I. J. Power Source 93, 224(2001)
30. S. M. Lin and T. C. Wen, "A Mixture Design Approach to the Service Life and the Oxygen Evolving Catalytic Activity of Ru-Sn-Ti Ternary Oxide Coated Electrodes", J. Appl. Electrochem., 23, 487(1993)
31. S. M. Lin and T. C. Wen, "Oxygen Evolution on Ir-Ru-Sn Ternary Oxide-Coated Electrodes in H2SO4 Solution - An Approach Employing Statistical Experimental Strategy", J. Electrochem. Soc., 140, 2265(1993)
32. S. M. Lin and T. C. Wen, "Applying Simplex Design to Voltammetric Charge of Ternary Ir-Ru-Sn Oxide-Coated Titanium Electrodes”, Bull. Electrochem., 10(2-3), 101(1994)
33. C. H. Yang, S. M. Lin and T. C. Wen, Polym. Eng. and Sci., 35, 722(1995).
34. J. A. Cornell, “Experiments with Mixtures: Design, Models, and the Analysis of Mixture Data”, 2nd ed., John Wiley & Sons, Inc., New York (1990).
35. A. I. Khuri and J. A. Cornell, “Response Surface Designs and Analysis”, Chap. 9, pp. 333-374, Marcel Dekker, Inc., N. Y. (1987).
36. 林世民,“釕基氧化物電極對氧氣及有機合成反應之電觸媒特性”,國立成功大學化學工程研究所博士論文,1994.
37. H. Scheffe, “Experiment with Mixtures”, J. Royal Statist. Soc., B20 ,344 (1958).
38. R. A. McLean and V. L. Anderson, “Extreme Vertices Design of Mixture Experiments”, Technometrics, 8, 447 (1966).
39. J G Webster, “Eelctrical Impedance Tomography”, Adam Hilger, Bristol(1990).
40. J. Ross MacDonald, “Impedance Spectroscopy - Emphasizing Solid Materials and Systems”, John Wiley & Sons, New Year(1987).
41. “CMS300 Electrochemical System Operator’s Manual”, Gamry Instruments, Inc., USA.(1993).
42. “Basics on AC Impedance Measurements”, Application Note AC-1. Available upon request from EG&G Princeton Applied Research, Electrochemical Instruments Division.
43. “Basics od AC Impedance Measurements”, Application Note AC-2. Available upon request from EG&G Princeton Applied Research, Electrochemical Instruments Division.
44. “Electrochemical Corrosion Measurements”, Application Note CORR-4. Available upon request from EG&G Princeton Applied Research, Electrochemical Instruments Division.
45. Mars G. Fontana, “Corrosion Engineering” McGraw-Hill, New York(1986).
46. Delahay, Paul, “The Electrical Double Layer and Electrode Kinetics”, Interscience, New York(1965).
47. Naji, A.; Ghanbaja, J.; Humbert, B.; Willmann, P. and Billaud, D., J. Power Source 63, 33(1996)
48. Naji, A.; Ghanbaja, J.; Humbert, B.; Willmann, P. and Billaud, D., Carbon, 35, 845(1997)
49. Billaud, D., Henry , F. X. and Willmann, P., Mater Res. Bull., 28,477(1993)
50. Zheng, T. and Dahn, J. R., Synth. Metals, 73,1(1995)
51. D. Aurbach, A. Zaban, Y. Gofer, Y. Ein-Eli, I. Weissman, O. Chusid, O. Abramson, B. Markovsky, J. Power Source 54,76(1995)
52. D. Aurbach, A. Zaban, Y. Ein-Eli, I. Weissman, O. Chusid, O. Markovsky, M. D. Levi, , A. Schecter, E. Granot, J. Power Source 86,91(1997)
53. D. Aurbach, O. Markovsky, M. D. Levi, A. El Levi, M. Schecter, Y. Moshkovich, J. Power Source in press(1999)
54. D. Aurbach, Y. Ein-Eli, Langmuir 8,1845(1992)
55. D. Aurbach, Y. Ein-Eli, B. Markovsky, and A. Zaban, J. Electrochem. Soc. 142, 2882(1995)
56. D. Aurbach, Y. Ein-Eli, this Journal, 142, 1746(1995)
57. T.Abe, Y, Mizutani, N. Kawabata, M. Inaba, Z. Ogumi, Synth. Met, 125, 249(2002)