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研究生: 劉威辰
Liu, Wei-Chen
論文名稱: 具微共振腔結構之高分子電致發光二極體的磁場效應
Magnetic field effect of microcavity-structured polymer light emitting diodes
指導教授: 郭宗枋
Guo, Tzung-Fang
學位類別: 碩士
Master
系所名稱: 理學院 - 光電科學與工程學系
Department of Photonics
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 88
中文關鍵詞: 微共振腔 、高分子電致發光二極體 、磁電致發光效應 、自旋交換交互作用
外文關鍵詞: Microcavity, PLED, Magnetoelectroluminescence, Spin exchange interaction
相關次數: 點閱:159  下載:0 
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  • 透過微共振腔內部的光學現象,可以使材料發光光譜從較廣的範圍縮減至較窄的範圍,代表材料內部激發態的能量受到共振腔而改變,且在先前的論文中提到在微共振腔結構下的磁場效應有被增強的趨勢,因此想探討微共振腔元件磁場效應中的主導機制。
    本篇論文將常見的高分子材料PPV的衍生物Super-yellow(SY-PPV)做為微共振腔元件的主動層材料,透過改變銀陰極的厚度調變元件的發光光譜半高寬,可以從原本約100 nm的半高寬縮減至約20 nm,接著將微共振腔元件置於外加磁場的環境中量測磁場下的電致發光變化,並發現磁電致發光效應會隨著共振腔模態場變化,便是由於共振腔增加了分子間交互作用(Intermolecular interaction)所造成的現象。
    於是,便透過增加通過元件的電流密度以減少載子間的距離增加彼此間的交互作用,以驗證增加分子間交互作用是否會改變磁場效應,並且從共振腔模態場寬與窄的元件磁效應中發現,共振腔模態場較窄的元件在較小的電流密度變化就可以有較大的磁場效應變化,如此便可以得知增加分子間交互作用進而改變磁場效應的首要影響為共振腔模態場,次要影響則是電流密度的變化。
    最後我們使用聚芴的衍生物(polyfluorene derivative, PF)驗證我們的理論機制不只在一個高分子材料出現,也可以在不同的主動層材料中有相同的機制存在,且根據論文的回顧發現PF具有較為明顯的三重態湮滅(Triplet-triplet annihilation, TTA)的現象,驗證共振腔提升分子間交互作用的理論。

    In this work, we observe the device with microcavity structure will have different magnetoelectroluminescence (MEL) line-shape comparing to device without microcavity. Trough microcavity effect we can get narrower emission spectral and higher optical confinement. We use light-emitting polymer super-yellow (SY-PPV) as active material in microcavity device. It has been well known the spin reaction process of SY-PPV happens in polaron pair system by using magnetic field effect. The spin in polaron pairs can easily be flipped by the magnetic field energy. Therefore, we can observe the ratio between singlet and triplet polaron pairs (PPS and PPt). In microcavity device, we can observe different line-shape of MEL and the full wavelength at half maximum (FWHM) of line-shape be narrowed while the thickness of semitransparent cathode increased. The change of the emission spectral and MEL is due to the redistribution of spatial energy in SY-PPV. It will affect the spin exchange interaction in polaron pairs. Higher carrier concentration will also affect spin exchange interaction. Therefore, we can increase the current density or higher optical confinement to verify the MEL line-shape changing phenomena. Furthermore, we use another light-emitting polymer to verify the phenomena can be repeated in different kind of material.

    摘要 I Extended Abstract II 致謝 VIII 目錄 IX 圖目錄 XII 表目錄 XVI 第一章 研究領域與實驗動機 1 1-0 前言-有機半導體發展簡介 1 1-1 微共振腔電致發光二極體的發展簡介 2 1-2 有機半導體磁場效應 5 1-2-a有機自旋閥的發展 5 1-2-b有機磁場效應的發展 7 1-2-c有機磁場效應的研究領域 13 1-2-d微共振腔元件的磁場效應 14 1-2-e結論 16 1-3 實驗研究動機 16 1-4 論文章節大綱 17 第二章 有機材料科學與磁場效應機制討論 18 2-0前言 18 2-1有機材料物理簡介 18 2-1-a 有機材料的半導體特性 18 2-1-b 有機材料的激發態 18 2-2 氫原子模型的自旋量子效應 21 2-2-a 超精細結構交互作用 (Hyperfine interaction) 22 2-2-b 自旋軌道耦合作用 (Spin-orbital coupling) 23 2-2-c 黎曼效應 (Zeeman effect) 24 2-2-d 自旋交換耦合作用力 (Spin exchange interaction) 26 2-3有機材料的激發態磁場效應理論模型 27 2-3-a 極化子對模型 (Polaron pair model) 27 2-3-b 雙極化子模型 (Bipolaron model) 29 2-3-c 激子模型 (Exciton model) 30 2-4章節總結 31 第三章 實驗操作流程與量測分析方法 32 3-0前言 32 3-1有機半導體元件製程 32 3-1-a銀陽極製程 33 3-1-b微共振腔元件製程 35 3-2磁場效應量測方式與訊號處理 38 3-2-a磁場效應的量測方式與訊號處理 39 3-2-b 電致發光 (Electroluminescence)/磁場效應量測系統之架設 40 3-2-c 光致發光 (Photoluminescence)頻譜/磁效應量測系統之架設 42 3-3 電性與發光現象量測系統 43 3-3 紫外光-可見光譜儀 (UV-visible spectrometer) 44 3-4章節總結 44 第四章 高分子微共振腔元件之磁電致發光研究 45 4-0前言 45 4-1銀薄膜反射鏡微共振腔 (Microcavity)的光學特性與優勢 45 4-1-a 微共振腔效應 (Microcavity effect) 48 4-1-b 光致激發光譜的光學特性 49 4-1-c 電致激發光譜的光學特性 51 4-1-d 結論 52 4-2無共振腔與微共振腔元件的磁電致發光效應 53 4-2-a 無共振腔元件 (Device without cavity) 53 4-2-b微共振腔元件 (Device with microcavity) 54 4-2-c 無共振腔與微共振腔元件數據擬合與比較 57 4-2-d 磁效應擬合係數A1、A2、B1、B2 61 4-2-e 磁效應與光譜半高寬的關係 62 4-2-f 結論 63 4-3 磁效應曲線半高寬變化之現象理論分析 64 4-3-a 電流密度對分子間激發態交互作用的貢獻 64 4-3-b 共振腔對分子間激發態交互作用的貢獻 67 4-3-c 改變載子濃度的磁效應貢獻 69 4-3-d 結論 71 4-4 高分子材料Polyfluorene於共振腔結構下的磁電致發光效應 73 4-5章節總結 76 第五章 總結與未來工作 78 5-1總結 78 5-2未來工作 79 參考資料 80

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