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研究生：	蔡岱凌 Tsai, Dai-Ling
論文名稱：	缺氮氮化碳應用於結合光催化5-羥甲基糠醛氧化與分解水產氫之研究 Nitrogen-deficient Carbon Nitride for Combined Photocatalytic 5- (Hydroxymethyl) furfural Oxidation and Hydrogen Evolution
指導教授：	吳季珍 Wu, Jih-Jen
學位類別：	碩士 Master
系所名稱：	工學院 - 化學工程學系 Department of Chemical Engineering
論文出版年：	2022
畢業學年度：	110
語文別：	中文
論文頁數：	114
中文關鍵詞：	缺氮氮化碳、水分解產氫、5-羥甲基糠醛氧化
外文關鍵詞：	nitrogen-deficient carbon nitride, hydrogen evolution, 5- (hydroxymethyl) furfural oxidation
相關次數：	點閱：59 下載：0
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摘要	I
誌謝	IV
目錄	V
圖目錄	X
表目錄	XIX
第一章 緒論	1
1-1前言	1
1-2研究動機	1
第二章 文獻回顧	3
2-1半導體材料的光催化	3
2-1-1光催化的歷史回顧	3
2-1-2光催化的基本原理	3
2-1-3光催化的主要領域	4
2-1-3-1光催化產氫	5
2-1-3-2 CO2光催化還原	6
2-1-3-3光催化降解	6
2-1-3-4金屬離子光催化還原	7
2-1-3-5光催化有機物氧化使產物增值	7
2-2生物質	8
2-3聚合氮化碳	11
2-3-1由超分子複合物合成氮化碳	13
2-3-2硫氰酸鉀後處理氮化碳	20
2-3-3氮化碳光催化產氫結合生物質氧化之應用	22
2-4先前已研究之硫氰酸鉀後處理氮化碳結構分析[33]	27
第三章 實驗	40
3-1實驗材料	40
3-1-1藥品	40
3-1-1-1製備超分子複合物	40
3-1-1-2製備硫氰酸鉀後處理氮化碳	40
3-1-1-3光催化HMF氧化同時產氫實驗	40
3-1-1-4氮化碳製備工作電極和Mott-Schottky量測實驗	41
3-1-2設備	42
3-2實驗流程設計	42
3-3實驗步驟	43
3-3-1以三聚氰胺和三聚氰酸合成的超分子複合物鍛燒成氮化碳	43
3-3-2添加少量2,4,6-三氨基嘧啶取代三聚氰胺合成三聚氰胺、三聚氰酸和2,4,6-三氨基嘧啶的超分子複合物鍛燒成缺氮氮化碳	44
3-3-3硫氰酸鉀後處理氮化碳[33]	45
3-3-4氮化碳應用於水分解產氫之研究	46
3-3-5光沉積鉑金共觸媒後的光觸媒光催化HMF氧化同時產氫實驗	47
3-3-5-1光沉積鉑金共觸媒	47
3-3-5-2光催化HMF氧化同時產氫	48
3-4 氮化碳製備工作電極和Mott-Schottky量測實驗	50
3-4-1氮化碳製備工作電極	50
3-4-2 Mott-Schottky量測實驗	51
3-5分析與鑑定	52
3-5-1掃描式電子顯微鏡 (Scanning Electron Microscope)	52
3-5-2穿透式電子顯微鏡 (Transmission Electron Microscope)	53
3-5-3 X射線繞射儀 (X-ray Diffractometer)	53
3-5-4表面積及奈米孔徑分析儀 (Surface Area and Porosimetric Analyzer)	54
3-5-5元素分析儀 (Elemental Analyzer)	54
3-5-6 X光光電子能譜儀 (X-ray Photoelectron Spectrometer)	55
3-5-7傅立葉轉換式紅外線光譜儀 (Fourier Transform Infrared Spectroscopy)	55
3-5-8紫外光-可見光吸收光譜儀 (UV-visible Absorption Spectrometer)	56
3-5-9光激發螢光光譜儀 (Photoluminescence Spectroscopy)	56
3-5-10時間解析光激發螢光光譜儀 (Time-Resolved Photoluminescence Spectroscopy)	57
3-5-11核磁共振儀 (Nuclear Magnetic Resonance)	57
3-5-12氣相層析儀 (Gas Chromatography)	58
3-5-13高效能液相層析儀 (High Performance Liquid Chromatography)	58
3-5-14 密度泛函理論計算 (Density Functional Theory)	59
第四章 結果與討論	60
4-1氮化碳之分析與鑑定	60
4-1-1氮化碳之形貌與結構分析	61
4-1-2氮化碳之化學微結構分析	68
4-1-3氮化碳之光學特性分析	75
4-2 密度泛函理論DFT模擬計算缺氮氮化碳 (TCN) 之電子結構	79
4-3氮化碳應用於水分解產氫之研究	83
4-4氮化碳應用於結合光催化5-羥甲基糠醛氧化與分解水產氫之研究	84
4-4-1氮化碳應用於結合光催化5-羥甲基糠醛氧化與分解水產氫之產物分析與效能	84
4-4-2優化缺氮氮化碳 (TCN) 於結合光催化5-羥甲基糠醛氧化與分解水產氫實驗前光沉積鉑金共觸媒重量比	99
4-4-3缺氮氮化碳應用於結合光催化5-羥甲基糠醛氧化與分解水產氫之機制探討	101
4-4-4減少取樣以改善氮化碳應用於結合光催化5-羥甲基糠醛氧化與分解水產氫實驗的漏氧情況	105
第五章 結論	109
第六章 參考文獻	111
                                    

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校內：2027-09-27公開
校外：2027-09-27公開電子論文尚未授權公開，紙本請查館藏目錄

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