| 研究生: |
邱揚眞 Chiu, Yang-Chen |
|---|---|
| 論文名稱: |
具潮濕乾燥變色功能之鹼激發玻璃膠結材 Alkali-Activated Glass Binders with the Characteristic of Color-Changing under Wet and Dry Environments |
| 指導教授: |
黃忠信
Huang, Jong-Shin |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 土木工程學系 Department of Civil Engineering |
| 論文出版年: | 2023 |
| 畢業學年度: | 111 |
| 語文別: | 中文 |
| 論文頁數: | 95 |
| 中文關鍵詞: | 廢玻璃 、鹼激發 、膠結材 、氯化亞鈷 、酚酞 、潮濕乾燥變色 |
| 外文關鍵詞: | Waste glass, alkali-activation, binder, cobalt chloride, phenolphthalein, color-changing mechanism |
| 相關次數: | 點閱:46 下載:0 |
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為取代高耗能及高二氧化碳排放量傳統卜特蘭水泥製程,本研究選用廢容器玻璃粉末,配合低耗能且低汙染之鹼激發製程,藉由添加具變色功能之化學變色物質,包括氯化亞鈷及酚酞,製成一具有潮濕乾燥變色功能之鹼激發玻璃膠結材。驗證添加此兩種化學變色物質所製成鹼激發膠結材,於潮濕乾燥不同含水環境下,均能重複呈現不同顏色變化。然後,進一步探討不同化學變色物質種類與添加量、鹼活化劑種類與濃度及拌合養護環境等,對所製成鹼激發玻璃膠結材試體感溼性、耐久性及顏色變化等之影響。試驗結果顯示,添加氯化亞鈷所製成鹼激發玻璃膠結材,至少需添加20%重量百分比之氯化亞鈷,方可使鹼激發玻璃膠結材完全變色,且可潮濕乾燥反覆變色達30餘次,試體抗壓強度最高可達1.5MPa,添加酚酞所製成鹼激發玻璃膠結材,添加酚酞0.01%重量百分比即可產生明顯外觀顏色變化,可潮濕乾燥反覆變色達20次,試體抗壓強度則可高達29.54MPa 。
Waste container glass was used as the raw material in the production of alkali-activated binder under a low-energy and low-pollution process to replace traditional Portland cement binder made from a manufacturing process of high energy consumption and carbon dioxide emission. The alkali-activated glass binders with the characteristic of color-changing were developed by introducing some color-changing chemicals including cobalt chloride and phenolphthalein. The alkali-activated glass binders containing these two color-changing chemicals demonstrated repeatedly their color-changing mechanisms under many cycles of dry and wet conditions. The effects of type and concentration of color-changing chemicals, alkaline activator and curing condition on the color-changing mechanism, microstructure and compressive strength of the alkali-activated glass binders were investigated. Experimental results showed that the color-changing mechanism can be verified repeatedly for more than 30 cycles of dry and wet conditions if at least 20% weight fraction of cobalt chloride was added. Moreover, the compressive strength of the alkali-activated glass binders containing cobalt chloride reached a maximum value of 1.5MPa. At the same time, the color-changing mechanism can be verified repeatedly for more than 20 cycles of dry and wet conditions when only 0.01% weight percentage of phenolphthalein was introduced necessarily. As a result of that, the compressive strength of the alkali-activated glass binders containing phenolphthalein could reach up to 29.54MPa.
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