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研究生: 邱揚眞
Chiu, Yang-Chen
論文名稱: 具潮濕乾燥變色功能之鹼激發玻璃膠結材
Alkali-Activated Glass Binders with the Characteristic of Color-Changing under Wet and Dry Environments
指導教授: 黃忠信
Huang, Jong-Shin
學位類別: 碩士
Master
系所名稱: 工學院 - 土木工程學系
Department of Civil Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 95
中文關鍵詞: 廢玻璃鹼激發膠結材氯化亞鈷酚酞潮濕乾燥變色
外文關鍵詞: Waste glass, alkali-activation, binder, cobalt chloride, phenolphthalein, color-changing mechanism
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  • 為取代高耗能及高二氧化碳排放量傳統卜特蘭水泥製程,本研究選用廢容器玻璃粉末,配合低耗能且低汙染之鹼激發製程,藉由添加具變色功能之化學變色物質,包括氯化亞鈷及酚酞,製成一具有潮濕乾燥變色功能之鹼激發玻璃膠結材。驗證添加此兩種化學變色物質所製成鹼激發膠結材,於潮濕乾燥不同含水環境下,均能重複呈現不同顏色變化。然後,進一步探討不同化學變色物質種類與添加量、鹼活化劑種類與濃度及拌合養護環境等,對所製成鹼激發玻璃膠結材試體感溼性、耐久性及顏色變化等之影響。試驗結果顯示,添加氯化亞鈷所製成鹼激發玻璃膠結材,至少需添加20%重量百分比之氯化亞鈷,方可使鹼激發玻璃膠結材完全變色,且可潮濕乾燥反覆變色達30餘次,試體抗壓強度最高可達1.5MPa,添加酚酞所製成鹼激發玻璃膠結材,添加酚酞0.01%重量百分比即可產生明顯外觀顏色變化,可潮濕乾燥反覆變色達20次,試體抗壓強度則可高達29.54MPa 。

    Waste container glass was used as the raw material in the production of alkali-activated binder under a low-energy and low-pollution process to replace traditional Portland cement binder made from a manufacturing process of high energy consumption and carbon dioxide emission. The alkali-activated glass binders with the characteristic of color-changing were developed by introducing some color-changing chemicals including cobalt chloride and phenolphthalein. The alkali-activated glass binders containing these two color-changing chemicals demonstrated repeatedly their color-changing mechanisms under many cycles of dry and wet conditions. The effects of type and concentration of color-changing chemicals, alkaline activator and curing condition on the color-changing mechanism, microstructure and compressive strength of the alkali-activated glass binders were investigated. Experimental results showed that the color-changing mechanism can be verified repeatedly for more than 30 cycles of dry and wet conditions if at least 20% weight fraction of cobalt chloride was added. Moreover, the compressive strength of the alkali-activated glass binders containing cobalt chloride reached a maximum value of 1.5MPa. At the same time, the color-changing mechanism can be verified repeatedly for more than 20 cycles of dry and wet conditions when only 0.01% weight percentage of phenolphthalein was introduced necessarily. As a result of that, the compressive strength of the alkali-activated glass binders containing phenolphthalein could reach up to 29.54MPa.

    摘要 i Extended Abstract ii 致謝 xv 目錄 xvi 圖目錄 xix 表目錄 xxv 第1章 緒論 1 1.1 研究動機 1 1.2 研究目的 2 1.3 論文組織與內容 4 第2章 文獻回顧 6 2.1 玻璃材料 6 2.1.1 玻璃成分與結構 6 2.1.2 廢容器玻璃現況 6 2.2 氯化亞鈷 7 2.2.1 氯化亞鈷之材料特性 7 2.2.2 氯化亞鈷遇水之特性 8 2.2.3 氯化亞鈷遇鹼之特性 8 2.3 酚酞 9 2.3.1 酚酞之材料特性 9 2.3.2 酚酞於土木工程之應用 10 2.4 鹼激發膠結材 10 2.4.1 鹼激發膠結材之發展歷程與原理 10 2.4.2 無機聚合物 11 2.4.3 鹼激發膠結材強度影響因素 13 2.5 鹼激發玻璃膠結材 16 2.5.1 玻璃之侵蝕 16 2.5.2 鹼激發玻璃膠結材之現況 19 第3章 試驗材料與研究方法 27 3.1 試驗規劃 27 3.2 試驗材料與儀器設備 28 3.2.1 試驗材料 28 3.2.2 試驗儀器設備 29 3.3 配比參數及設計 31 3.3.1 配比參數 31 3.3.2 配比計算範例 33 3.4 試體製作 34 3.4.1 添加氯化亞鈷之鹼激發膠結材 34 3.4.2 添加酚酞之鹼激發膠結材 35 3.4.3 塗層 36 3.5 試驗方法 37 3.5.1 廢容器玻璃粉末試驗 37 3.5.2 抗壓強度試驗 38 3.5.3 硬固膠結材pH值試驗 38 3.5.4 反覆變色試驗 39 3.5.5 簡易吸附水量試驗 39 第4章 試驗結果與討論 51 4.1 添加氯化亞鈷之鹼激發玻璃膠結材 51 4.1.1 鹼模數對於顏色呈現之影響 51 4.1.2 鹼當量對於顏色呈現之影響 52 4.1.3 反覆變色試驗 54 4.1.4 鹼當量對吸附水量之影響 55 4.1.5 抗壓試驗 55 4.2 添加酚酞之鹼激發玻璃膠結材 57 4.2.1 鹼當量與水膠比對於顏色呈現之影響 58 4.2.2 硬固膠結材pH值試驗 58 4.2.3 反覆變色試驗 59 4.2.4 抗壓試驗 60 4.3 綜合比較 62 第5章 結論與建議 87 5.1 結論 87 5.2 建議 89 參考文獻 91

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