| 研究生: |
陳鈺麟 Chen, Yu-Lin |
|---|---|
| 論文名稱: |
以自旋極化光電子於感測手性分子與產氫效率之研究 Spin Polarization for Sensing Chiral Molecules and Hydrogen Generation |
| 指導教授: |
蘇彥勳
Yen, Hsun Su |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2021 |
| 畢業學年度: | 109 |
| 語文別: | 中文 |
| 論文頁數: | 104 |
| 中文關鍵詞: | 化學水浴沉積法 、氧化鋅 、金奈米粒子 、精胺酸 、表面電漿共振 |
| 外文關鍵詞: | chemical bath deposition method, zinc oxide, gold nanoparticle, arginine, surface plasmon resonance |
| 相關次數: | 點閱:130 下載:0 |
| 分享至: |
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透過化學水浴沉積法所合成製備出氧化鋅柱狀結構材料,氧化鋅材料是個寬能隙的半導體材料,也因此在吸收太陽光能做落在紫外光區域,在貴金屬奈米材料粒子中如金奈米粒子會表現出表面電漿共振效應(SPR),以利增益共振能量傳遞以及增強在太陽光能頻譜中的可見光區域的吸收,使用簡單化學的方法修飾不同形貌的貴金屬奈米材料粒子於氧化鋅材料的表面,此外在貴金屬奈米材料粒子外圍裝飾精胺酸手性分子。並於本研究中使用XRD、SEM、TEM、UV-vis、Spin polarization等分析儀器量測材料特性與光學性質,在研究中使用自旋極化電子系統所創造出角動量不同的極化光源如自旋向上與自旋向下,利用不同自旋方向極化光來量測含有精胺酸分子的試片電極,其在不同旋光度的精胺酸分子受測下,其在量測結果表現著不同強度的光電流值表現,且在表面有貴金屬奈米粒子的表面電漿共振效應增強其共振能量傳遞的幫助下,在選擇性的差異幅度增強,更能分辨精胺酸分子於自旋極化系統中,此藉由自旋極化系統在分辨旋光性不同的精胺酸分子領域中是有著潛在的開發商用價值。
In this research, a zinc oxide nanorods material was synthesized by the chemical bath deposition method and the zinc oxide material was a wide band gap semiconductor so the absorbance of zinc oxide is in the UV light region. The effect of surface plasmon resonance (SPR) form gold nanoparticles, it can enhance the absorbance of the visible light. The arginine molecular is one of the chiral molecule and focus on the optical property. The characteristics of the material can be measured by a different of analysis like the XRD、SEM、TEM、UV-vis、Spin polarization etc. From the result, it could find that the Au nanoparticles successfully synthesized by the simple method. The gold nanoparticles enhance the absorbance light to visible and the SPR effect the visible peak in different shape of gold nanoparticles such as gold nanoparticles and the urchin gold nanoparticles. In the spin polarization system, we created the different angular moment light such as spin up and spin down. The arginine molecular under the spin polarization system measurement, the result that the different spin light source could enhance by the different type of arginine molecular. The gold nanoparticles also helped the arginine molecular to increase the result of the select.
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