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研究生: 希以勒
Hakim, Cyril El
論文名稱: 高壓條件下微尺度通道甲烷燃燒數值模擬研究
Numerical Simulation of Methane Combustion in a Micro-Scale Channel under High Pressure Conditions
指導教授: 趙怡欽
Chao, Yei-Chin
學位類別: 碩士
Master
系所名稱: 工學院 - 航空太空工程學系
Department of Aeronautics & Astronautics
論文出版年: 2018
畢業學年度: 106
語文別: 英文
論文頁數: 108
外文關鍵詞: micro-combustion, micro-reactor, millimeter scale, catalyst surface, radicals, exothermicity, combustion mechanism, micro-power devices, gas phase combustion, catalytic micro-channel, numerical simulation, high pressure, heterogeneous reaction, homogeneous reaction, methane-air mixture.
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  • Over the past few years, micro-scale combustion has generally received a good consideration with the development of electronic-mechanical devices and micro-electro-mechanical systems (MEMS) in the following domains namely chemical analysis, civil and military aeronautics, astronautics, communication, biomedical but also environmental.
    Indeed, aware of the promising type of easily transported energy device, various research studies have been done on the combustion characteristics and performance of micro-scale reactors. Thus, many advantages of micro-scale-combustor are known to be a good supplier of power by simplicity, for its long shelf life and for using an easy fuel replacement. For example, micro-scale reactors are capable to provide power adapted on various kind of hydrocarbons combustion for equipment such as drones, mobile-phones, mini-robots or small airplanes [1-3]. Due to the millimeter scale, we are faced to the tiny dimensions of the micro-scale reactor which make it difficult to maintain a stable flame on the contrary of the “traditional” reactor. Therefore, the arrangement solution suggested is to apply the reaction mechanism of methane-air mixture catalytic oxidation on platinum-coated on the surface wall in the micro-reactor. The heterogeneous reaction, preceding catalyst surface, produces chemical radicals and then, catalytically induced exothermicity. As a result, this way permits to trigger the homogeneous reaction inside the micro-channel. Understanding the process of micro-scale combustion mechanism is very important to the development of micro-power devices.
    Being part of this movement, the objective of this thesis was to investigate the gas phase combustion characteristics inside a catalytic micro-channel depending on the effect of the high pressure conditions thanks to numerical simulations with heterogeneous and homogeneous chemistries of methane-air mixture reactions. The first results obtained with theses simulations will be presented in this document.

    ABSTRACT I ACKNOWLEDGEMENTS III CONTENTS IV LIST OF TABLES VIII LIST OF FIG.S IX NOMENCLATURE XII CHAPTER 1: INTRODUCTION 1 1.1 COMBUSTION 1 1.2 CATALYTIC COMBUSTION 2 1.3 HOMOGENEOUS CHEMICAL REACTIONS IN GAS PHASE REGION 3 1.4 CONCEPT OF MICRO-COMBUSTION 4 1.5 APPLICATIONS OF MICRO-COMBUSTION 4 1.6 THESIS OVERVIEW 6 CHAPTER 2: LITERATURE REVIEW 8 2.1 BACKGROUND SIMULATIONS OF MICRO COMBUSTION 8 2.2 MOTIVATION 14 2.3 OBJECTIVE OF THE THESIS 15 CHAPTER 3: NUMERICAL METHOD 17 3.1 SOFTWARE 17 3.2 GOVERNING EQUATION 17 3.3 COMPUTATIONAL DOMAIN 19 3.3.1 Geometric model 19 3.3.2 Meshing of the System 22 3.3.3 Catalyst 22 3.3.4 Mixture of Methane-Air Combustion 23 3.3.5 Boundary conditions 26 3.4 CHEMICAL MECHANISM MODEL 29 3.4.1 Gas phase Reaction 29 3.4.2 Surface Reaction 30 CHAPTER 4: RESULTS AND DISCUSSION 32 4.1 MICRO-COMBUSTION CHARACTERISTICS FOR DIFFERENT REACTION MODELS 32 4.2 EFFECT OF PRESSURE 38 4.3 EFFECT OF INLET FLOW VELOCITY 53 4.4 EFFECT OF ENTRANCE DIAMETER 58 CHAPTER 5: CONCLUSIONS 65 5.1 SUMMARY 65 5.2 FUTURE WORK 68 REFERENCES 69 APPENDIX 77 APPENDIX 1: SKELETAL GAS PHASE MECHANISM CODE 77 APPENDIX 2: SURFACE REACTION MECHANISM CODE 78 APPENDIX 3: TABLE OF FLAME POSITION OF CONCENTRATION OF OH, O, H RADICALS FOR DIFFERENT PRESSURES FOR INLET FLOW VELOCITY VIN=5M/S 81 APPENDIX 4: CONTOURS OF O, H RADICALS RESPECTIVELY FOR DIFFERENT PRESSURES FOR INLET FLOW VELOCITY VIN=5M/S 90 APPENDIX 5: TABLE OF FLAME POSITION OF CONCENTRATION OF METHANE FUEL FOR DIFFERENT PRESSURES FOR INLET FLOW VELOCITY VIN=5M/S 91 APPENDIX 6: TABLE OF FLAME POSITION OF CONCENTRATION OF OH, O, H RADICALS FOR DIFFERENT PRESSURES FOR INLET FLOW VELOCITY VIN=20M/S 94 APPENDIX 7: CONTOURS OF O, H RADICALS RESPECTIVELY FOR DIFFERENT PRESSURES FOR INLET FLOW VELOCITY VIN=20M/S 103 APPENDIX 8: TABLE OF FLAME POSITION OF CONCENTRATION OF METHANE FUEL FOR DIFFERENT PRESSURES FOR INLET FLOW VELOCITY VIN=20M/S 104 APPENDIX 9: TABLE OF FLAME POSITION FOR DIFFERENT OPERATION CONDITIONS FOR INLET ENTRANCE DIAMETER D=0.2MM 107 APPENDIX 10: TABLE OF OH MAGNITUDE FLAME FOR DIFFERENT OPERATION CONDITIONS FOR INLET ENTRANCE DIAMETER D=0.2MM 107 APPENDIX 11: TABLE OF FLAME POSITION FOR DIFFERENT OPERATION CONDITIONS FOR INLET ENTRANCE DIAMETER D=2MM 108 APPENDIX 12: TABLE OF OH MAGNITUDE FLAME FOR DIFFERENT OPERATION CONDITIONS FOR INLET ENTRANCE DIAMETER D=2MM 108

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