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研究生: 胡立群
Hu, Li-Chun
論文名稱: 呼吸式質子交換膜燃料電池排水週期與溫度控制系統之模擬分析
Purge Cycle and Simulation of Temperature Control System Analysis for Air-Breathing PEMFC
指導教授: 賴維祥
Lai, Wei-Hsiang
學位類別: 碩士
Master
系所名稱: 工學院 - 航空太空工程學系
Department of Aeronautics & Astronautics
論文出版年: 2022
畢業學年度: 110
語文別: 中文
論文頁數: 122
中文關鍵詞: 呼吸式質子交換膜燃料電池Matlab燃料電池模型Simulink電路分析模糊控制
外文關鍵詞: Air-Breathing PEMFC, Fuel Cell Model, Simulink Analysis, Fuzzy Control
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  • 本研究目標在透過實際燃料電池實驗與理論分析模擬其性能,進而開發最適合的燃料電池系統控制。為了解燃料電池的操作條件,透過改變排水週期與風扇控制,探討對燃料電池之性能影響。在模擬部分,本研究利用Matlab繪製燃料電池模型,並與實際的電池性能匹配,結果顯示當電流密度小於275 mA/cm2時,誤差可控制在5%以內,且利用Simulink繪製模擬電堆負載,研究燃料電池的溫度變化與變動負載系統響應狀況,減少實際使用與開發燃料電池成本。
    本實驗利用樹莓派4B (Raspberry Pi 4B)當作主控板,結合周邊次系統,開發出燃料電池控制系統,包含燃料供給次系統、電池堆監控次系統與散熱次系統,為了使控制系統能夠穩定順利運作,更開發模糊控制應用至燃料電池控制中,研究結果發現模糊控制具有較佳的溫度掌握,溫度的浮動範圍可控制在12.9%以內,優於傳統控制的溫度浮動範圍高達34.4%,模糊控制可減少不必要的振盪情形發生,更能降低燃料電池的使用門檻,溫度能自動維持在理想範圍內,故更有利於應用在燃料電池控制上。

    This study aims to develop the most suitable fuel cell system control by simulating fuel cell performance through practical experiments and theoretical analysis. Because the air supply and the cooling are combined in the same system in the air-breathing proton exchange membrane fuel cell (PEMFC), it has the advantage of reducing weight and volume. To understand the operating conditions of the fuel cell, the effect on the performance of the fuel cell is investigated by changing the drain cycle and fan control. In the simulation part, this study uses Matlab to build up the fuel cell model and compares with the actual cell performance. According to the result, when current density is less than 275 mA/cm2, the error can be control within 5%. This study also uses Simulink to build up the simulated circuit load, study the temperature change and response of the fuel cell system, and reduce the cost of application and development of the fuel cell system.
    In this study, the Raspberry Pi 4B is used as the main control board, combined with the balance of plant, to develop a fuel cell control system. The system includes fuel supply subsystem, stack monitoring subsystem and cooling subsystem. To make the system operate stably and smoothly, the fuzzy control is introduced and applied to the fuel cell system. The experimental results show that adding the fuzzy control can manipulate the stack temperature more smoothly and continuously, its temperature variation is within 12.9%, instead of 34.4% of traditional control, which is beneficial to the application of fuel cell control.

    中文摘要 I Abstract II 誌謝 VII 目 錄 VIII 表目錄 XIII 圖目錄 XIV 符號 XIX 第 1 章 緒論 1 1-1 前言 1 1-2 研究動機與目的 3 1-3 文獻回顧 4 1-3-1 燃料電池控制系統 4 1-3-2 燃料電池數學模型 7 1-3-3 燃料電池模糊理論之應用 9 1-4 模糊理論 12 1-4-1 模糊集合 12 1-4-2 模糊集合的運算 14 1-4-3 模糊邏輯與模糊推論 15 第 2 章 質子交換膜燃料電池簡介 17 2-1 質子交換膜燃料電池基本構造 17 2-1-1 端板(End Plate) 17 2-1-2 集電板(Current Collector) 18 2-1-3 雙極板(Bipolar Plate) 18 2-1-4 膜電極組(Membrane Electrode Assembly, MEA) 19 2-2 燃料電池發電原理 20 2-3 極化曲線 23 2-3-1 活化過電位 (Activation Over-potential) 25 2-3-2 歐姆過電位 (Ohmic Over-potential) 27 2-3-3 濃度過電位 (Concentration Over-potential) 28 第 3 章 實驗設備 31 3-1 燃料電池測試機台 32 3-2 燃料供應次系統 33 3-3 燃料電池控制系統硬體設備 34 3-3-1 樹莓派4B (Raspberry Pi 4B) 34 3-3-2 壓力感測器 35 3-3-3 電壓與電流感測器 36 3-3-4 溫度感測器與熱電偶 39 3-3-5 風扇 40 3-3-6 電磁閥 41 3-4 41級呼吸式質子交換膜燃料電池堆 42 3-4-1 膜電極組 43 3-4-2 金屬雙極板 44 3-4-3 集電板 45 3-4-4 端板 45 第 4 章 實驗方法 46 4-1 周邊次系統(BOP) 46 4-1-1 氫氣供給系統 46 4-1-2 空氣供給系統 46 4-1-3 監控系統 47 4-1-4 排水系統 47 4-1-5 散熱系統 48 4-2 建立燃料電池操作條件與模式 48 4-2-1 排水週期對燃料電池性能影響 48 4-2-2 風扇控制對燃料電池性能影響 49 4-2-3 燃料電池操作模式設定 50 4-3 Matlab燃料電池性能分析 57 4-3-1 燃料電池數學模型 57 4-3-2 Simulink燃料電池模型 61 4-3-3 建立模糊邏輯 67 4-4 燃料電池控制系統建置 70 4-4-1 樹莓派遠端控制 70 4-4-2 樹莓派周邊元件之應用 72 4-4-3 樹莓派數據紀錄 79 4-4-4 控制系統穩定測試 80 4-4-5 建立模糊控制 82 第 5 章 結果與討論 84 5-1 燃料電池平台測試 84 5-1-1 41級呼吸式金屬雙極板燃料電池極化曲線 85 5-1-2 排水週期對燃料電池性能影響 87 5-1-3 風扇控制對燃料電池性能影響 90 5-2 MATLAB燃料電池分析 95 5-2-1 燃料電池數學模型 96 5-2-2 Simulink 燃料電池模擬分析 100 5-2-3 模糊邏輯分析 106 5-3 燃料電池控制系統 110 5-3-1 傳統控制與模糊控制系統穩定測試 110 第 6 章 結論 115 第 7 章 未來工作 117 參考文獻 118

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