時代的進步與工業的發展，使得人類仰賴化石燃料來發展文明
為了減少對於化石燃料的依賴，各種替代能源的研究因運而生，本論
文利用甲醇作為燃料，使用ASPEN PLUS軟體來模擬產氫製程，由結果可
知在同樣的甲醇重組器，水煤氣反應器，進行設計下，自熱重組的產氫程序比較能提升氫氣產率，並以此為主體作了除去一氧化碳的三種設計，使產氫系統可以隨著需氫量的大小而因地制宜。
為了對系統有更進一步的了解，本文採用具優先氧化段反應器為除一氧化碳段的甲醇自熱重組系統進行一系列的動態操控，在變數減少的情況下，成功在動態下使系統可以達到所要的產率。
最後在MATLAB/Simulink與ASPEN PLUS進行系統結合動態模擬，並透過控制器將系統溫度維持一定。

This research connect hydrogen processor and the low temperature PEM fuel cell system, the purpose of the system is to build a conceptual designs of different producing hydrogen by reforming methanol. By the results of ASPEN PLUS software, we can see with the same reformer and Water Gas Shift reactor, autothermal can make more yield of hydrogen. With the design ,we conduct 3 cases of CO reducing design for adapting different usage, sizing from massive methanol steam reforming with PSA(Pressure Swing Adsorption) to small scale methanol autothermal with PROX(Preferential Oxidation) reactor. Both PROX reactor and PSA serve as CO reducing unit for purpose of preventing the PEM Fuel Cell from poisoning the platinum catalyst , causing the cell efficiency loss. Moreover the stand alone design and simple waste heat recovery are also built in the systems above. Second part is conducting a series of dynamic of hydrogen production and ATV control. With ASPEN PLUS Dynamic, the system can reach a steady hydrogen producing, and found that the inlet water feed doesn’t affect much to the system. So methanol feed is the control variable, through the controller the output hydrogen can soon reach the set point. Finally we can build ASPEN/MATLAB integration and conduct a simple temperature control

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