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研究生: 陳志發
Chen, Chih-Fa
論文名稱: 微波輔助燃燒合成YAG螢光粉之製程開發
指導教授: 鍾賢龍
Chung, Shyan-Lung
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 119
中文關鍵詞: 白光發光二極體微波加熱
外文關鍵詞: Microwave heating, YAG
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  •   近幾年來,將具低耗電、無熱輻射、環保與使用壽命長等優點的白光LED作為照明光源是未來最被看好的發展趨勢。日亞化學利用GaN藍光晶片與黃色釔鋁石榴石(yttrium aluminum garnet,YAG)螢光粉的結合可以發出白光,此乃目前市面上最常見的白光LED的製作方式。為進一步提升白光LED的發光效率,研究出螢光效率更優良的YAG:Ce黃色螢光粉是必須的。

      微波加熱技術是種高效率的加熱方法,近來廣泛的被應用。吾人利用微波加熱技術配合燃燒反應法可以順利合成YAG:Ce黃色螢光粉,實驗發現可以利用不同燃料的調配與煅燒溫度的調整控制螢光粉的粒徑範圍且粒徑分佈均勻,最小的粉體粒徑可以達到50nm,合成出來的產物為YAG晶相而無雜相。

     Recently, white light emitting diode(LED) has become the trend of illumination source because of its energy saving、no heat radiation、low pollution and long using life. The most popular white light emitting diode is fabricated by the combination of GaN blue chip and yttrium aluminum garnet phosphor in the market condition. In order to promote the lighting efficiency of white LED, It’s necessary to research better YAG:Ce phosphor.

     Microwave heating technology is an efficient way of heating and used widely in many industry recently. We can synthesize YAG:Ce phosphor by applying microwave heating technology and combustion reaction. According to our experiment, we can control the particle size of YAG:Ce phosphor by adjusting fuels and calcinations temperature. The minimum particle size is 50 nm and there is no other phase but YAG phase in the product.

    總目錄 摘要 ……………………………………………………………………….Ⅰ Abstract ………………………………………...…………………………Ⅱ 誌謝 ……………………………………………………………………….Ⅲ 總目錄 …………………………………………………………………….Ⅳ 表目錄 …………………………………………………………………….Ⅶ 圖目錄 …………………………………………………………………….Ⅷ 第一章 緒論 1-1 白光發光二極體簡介 …...……….…………...………………. 1 1-2 釔鋁石榴石營光粉簡介 ..……………………………………. .4 1.3 氧化物陶瓷粉末的合成方法 ...………………....……..……...10 1-3-1 固相反應法(solid state method) ..………………………10 1-3-2 共同沈澱法(coprecipitation method) ..………..………...10 1-3-3 溶膠-凝膠法(sol-gel method) ...………………....…….11 1-3-4 水熱法(hydrothermal method) ...………………....……..11 1-3-5 微乳液法(microemulsion method) ...………………........12 1-3-5 噴霧裂解法(spray pyrolysis method) ...………………...13 1-3-6 燃燒合成法(Combustion Synthesis Method,SHS) ……13 第二章 理論基礎與文獻回顧 2-1 微波加熱 ………………..…………………………….… ……17 2-1-1 微波簡介 ……..………………..... .…………………….17 2-1-2 微波加熱原理 ………………..…………………………19 2-1-3 微波的穿透深度 …………………..……………………25 2-1-4 微波加熱的特點 …………………..……………………26 2-1-5 微波加熱裝置 …………………..………………………28 2-1-6 微波公害 …………………..……………………………30 2-2 螢光發光 …………………..…………………………...….. …31 2-2-1 螢光材料的簡介與分類 …………………..……………31 2-2-2 發光原理 …………………..……………………………36 2-2-3 螢光材料的設計 …………………..……………………40 2-2-4 影響螢光效率的因素 …………………..………………43 2-3 YAG粉體合成之文獻回顧 …..………...………………….… 49 第三章 YAG螢光粉體合成方法之開發 3-1 實驗方法 .…………………………………………….………. 52 3-1-1 固態反應法 .…………………………………………….54 3-1-2 微波輔助-固態反應法 .………………………………...55 3-1-3 微波輔助-溶液燃燒合成法 .…………………………...56 3-2 實驗設備 ………………….…………………………….……. 59 3-3 實驗藥品 ………………………………………………………61 3-4 量測與分析儀器 ………………….……………….…………..64 第四章 實驗結果與討論 4-1 固態反應法合成(Y3-xCex)Al5O12 …..……………….…. …….69 4-1-1 Ce3+濃度對YAG:Ce螢光性的影響 …..……………..69 4-1-2 煅燒溫度對YAG:Ce螢光性的影響 …..…………….74 4-2 微波輔助固態反應法合成(Y3-xCex)Al5O12 …………………. 80 4-3 微波輔助燃燒反應法合成(Y3-xCex)Al5O12 ………………. …87 4-3-1 不同燃料對微波輔助燃燒反應法合成YAG:Ce螢光粉的影響 …..…………………………………….…………..87 4-3-2 混合燃料對微波輔助燃燒反應法合成YAG:Ce螢光粉的影響 …..…………………………………….…………..98 第五章 結論 …………………………………….……………..…..……113 參考文獻 ………………………………………….……………..…..…..115 自述 ……………………………………………………………………...119

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