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研究生: 林聖富
Lin, Sheng-Fu
論文名稱: 利用掃描探針場致氧化技術製作矽鍺奈米氧化物
Fabrication of SiGe Nano-oxides by Scanning Probe Anodic Oxidation
指導教授: 吳忠霖
Wu, Zhong-Lin
學位類別: 碩士
Master
系所名稱: 理學院 - 物理學系
Department of Physics
論文出版年: 2018
畢業學年度: 106
語文別: 中文
論文頁數: 38
中文關鍵詞: 原子力顯微鏡局域性陽極氧化矽鍺合金
外文關鍵詞: Atomic Force microscope, Local Anodic Oxidation, Silicon-Germanium Alloy
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  • 本實驗研究在矽鍺(SiGe)基板上進行侷域陽極氧化(LAO),藉由LAO後產生不同的SiGe氧化物結構。用AFM確認LAO後的區域,證實表面因LAO氧化產生氧化物結構。
    經由TEM分析SiGe氧化物內結構,在原先為單晶結構的SiGe層晶LAO後呈現非晶相的狀態,但是在非晶質結構頂層出現局部晶質現象。由晶格常數分析後,頂部局部晶質之晶格常數為接近鍺元素之晶格。
    透過TEM對氧化物內結構的解析,確認陽極氧化對SiGe合金的影響後,進一步去成長奈米點氧化物,期望在奈米點氧化物內生成Ge量子點。

    We investigated scanning probe assisted localized anodization (LAO) on a SiGe substrate, which can produce SiGe oxide structures with nano-meter scale. The LAO area, which was examined by AFM, confirmed that the area was oxidized with amorphous structure and having nano-crystalline clusters by HR-TEM. After analyzing the lattice constants of the nanoclusters, we can confirm the formation of Ge nanoclusters in the LAO structures of SiGe.

    第一章 緒論 1 1.1 前言 1 1.2 研究動機 3 第二章 實驗儀器原理 8 2.1原子力顯微鏡(Atomic Force Microscope) 8 2.2穿透式電子顯微鏡 11 2.3掃描式電子顯微鏡 (Scanning Electron Microscope) 13 第三章 實驗方法 15 3.1以局域性陽極氧化方法產生奈米氧化物 15 3.1.1 基板處理及清洗 15 3.1.2 陽極氧化法成長方形氧化物 17 3.1.3 陽極氧化法成長奈米點氧化物 18 3.1.4 導電式原子力顯微鏡 19 3.2 掃描式電子顯微鏡確認氧化物結構 20 第四章 實驗結果與分析 21 4.1 連續電壓產生之方形氧化物 21 4.2 HF蝕刻階梯狀氧化物 23 4.3 奈米點氧化物成長 26 第五章 分析與討論 28 5.1 量子點氧化物結構與施加偏壓 28 5.2 SiGe和Si的陽極氧化系統比較 30 5.3 氧化結構TEM分析 32 5.4 EDX(能量色散X-射線光譜) 34 第六章 結論 36 文獻參考 37

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