本研究係針對廢棄物之焚化飛灰進行PCDD/Fs熱處理實驗，探討經由不同溫度進行熱處理實驗以及於實驗中添加氧化鈣(CaO)對於熱處理實驗後飛灰中PCDD/Fs之濃度變化。熱處理前飛灰之總TEQ為6.20 ng I-TEQ/g，在熱處理溫度為50~250℃之間時，由於尚未達到PCDD/Fs生成所需之溫度，且亦不足以破壞既存之PCDD/Fs，故熱處理前後無明顯差異。總毒性當量介於4.33~7.99 ng I-TEQ/g。於熱處理溫度300℃之後，於熱處理後PCDD/Fs含量反而遠高於熱處理前，顯示於熱處理過程中PCDD/Fs有生成之現象發生。總毒性當量介於371~741 ng I-TEQ/g。於實驗中加入氧化鈣(CaO) ，目的在於抑制PCDD/Fs生成之現象。添加氧化鈣(CaO) 進行熱處理後飛灰之總毒性當量介於59.3~360 ng I-TEQ/g，其PCDD/Fs濃度及毒性與未添加CaO相比，皆有明顯的下降，其下降比例介於19.3~85.2%，平均為62.9%。顯示以CaO來抑制PCDD/Fs生成有一定之成效。

The objectives of the study were to know the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from waste incineration fly ash after thermal treatment, and the effect of temperature gradient and CaO of PCDD/Fs formation. The results indicated that the total PCDD/Fs content in raw fly ash was 6.20 ng I-TEQ/g which was close to treated fly ash range from 4.33 to 7.99 ng I-TEQ/g at low temperature (50-250℃). However, the PCDD/Fs contents (371 to 741 ng I-TEQ/g) in treated fly ash was dramatically increase at the temperature higher then 300℃. In addition, mixing CaO with raw fly ash, the total PCDD/Fs content was decreased between 59.3 to 360 ng I-TEQ/g, which was a obvious inhibition efficiency. Thus, the CaO really could enhance the inhibition of PCDD/Fs formation during the thermal process.

Abad, E., Caixach, J. Rivera, J. Improvements in dioxin abatement strategies at a municipal waste management plant in Barcelona, Chemosphere ,50, 1175-1182,2003.
Alcock Ruth E., Robert Gemmill, Kevin C. Jones，Improvements to the UK PCDD/F and PCB atmospheric emission inventory following an emissions measurement programme，Chemosphere, Volume 38, Issue 4, Pages 759-770, February 1999.
Altwicker, E.R. Relative rates of formation of polychlorinated dibenzodioxin and dibenzofuran precursor and De novo reactions, Chemosphere, Vol. 33, No. 10, pp. 1897-1904, 1996.
Ballschmite r. K, W. Krämer, H. Magg, W. Schäfer, W. Zoller, A. Nottrodt, K.D. Sladek，Distribution of polychlorodibenzodioxin and -furan emissions between particulates, flue gas condensate and impinger absorption in stack gas sampling，Chemosphere, Volume 14, Issues 6-7, 1985, Pages 851-854.
Cunliffe, A.M., Williams, P. T. De-novo formation of dioxins and furans and the memory effect in waste incineration flue gases. Waste Management, 29, 739-748, 2009.
Cunliffe, A.M., Williams, P. T. Desorption of PCDD/PCDF from municipal solid waste incinerator flyash under post-combustion plant conditions. Chemosphere, 68, 1723-1732, 2007.
Caserini Stefano, Monguzzi Anna Maria，PCDD/Fs emissions inventory in the Lombardy Region: results and uncertainties，Chemosphere, Volume 48, Issue 8, Pages 779-786, September 2002.
Cleverly Dankay，Nursing research — taking an active interest，Nurse Education Today, Volume 18, Issue 4, Pages 267-272, May 1998.
Cains P. W., G. H. Eduljee，Prediction of PCDD and PCDF emissions from municipal solid waste (MSW) incinerators，Chemosphere, Volume 34, Issue 1, Pages 51-69, January 1997.
Dickson, L.C., Lenoir, D., Hutzinger, O. Surface-catalyzed formation of chlorinated dibenzodioxins and dibenzofurans during incinerator. Chemosphere, 19, 277-282, 1989.
Dickson P.H., M.A. Shara, D. Bagchia and S.J. Stohs，Excretion of formaldehyde, malondialdehyde, acetaldehyde and acetone in the urine of rats in response to 2,3,7,8-tetrachlorodibenzo-p-dioxin, paraquat, endrin and carbon tetrachloride，Journal of Chromatography B: Biomedical Sciences and Applications, Volume 576, Issue 2,8, Pages 221-233,1992.
Dong, J.I., Lee, J.K., Ko, Y.H., Seo, S.S., Kim, B.H., Park, G.H. The effect of activated carbon injection rate to dioxin emission level in an incinerator SDA+B/F APC. Proceeding of 21th International Symposium on Halogenated Environmental Organic Pollutants and Persistent Organic Pollutants (2001).
Dong, J.I., Ko, Y.H., Lee, J.G., Seo, S.S. Lee, Y.J., Yoon, K.D., Kim, B.H., Park, G.H. The characteristics of gas/solid phase PCDD/Fs behavior in duplicate bag filter flue gas treatment system of MSWI. Proceeding of 21th International Symposium on Halogenated Environmental Organic Pollutants and Persistent Organic Pollutants (2001).
Everaert, K., Baeyens, J. The formation and emission of dioxin in large scale thermal processes. Chemosphere, 46, 439-448, 2002.
Gullett, B., Bruce, K.R., Beach, L.O. Effect of sulfur dioxide on the formation mechanism of polychlorinated dibenzodioxin and dibenzofuran in municipal waste combustors. Environ. Sci. Technol. 26 (1992) 1938-1943.
Hutzinger, O., Blumich, M. J. Sources and fate of PCDDs and PCDFs: an overview. Chemosphere, 14, 581-600, 1985.
Hsing-Wang Li, Wen-Jhy Lee, Perng-Jy Tsai, Jin-Luh Moud, Guo-Ping Chang-Chien, Kuen-Thyr Yang. A novel method to enhance polychlorinated dibenzo-p-dioxins and dibenzofurans removal by adding bio-solution in EAF dust treatment plant, Journal of Hazardous Materials 150 (2008) 83-91.
Karasek F.W , L.C. Dickson.，Mechanism of formation of polychlorinated dibenzo-p-dioxins produced on municipal incinerator flyash from reactions of chlorinated phenols，Journal of Chromatography A, Volume 389, Pages 127-137 , 1987.
Lustenhouwer, J.W.A., Olie, K., Hutzinger, O. Chlorinated dibenzo-p-dioxin and related compounds in incinerator effluents: a review of measurements and mechanism of formation, Chemosphere, 9, 501-522, 1980.
Liu, W., Zheng, M., Zhang, B., Qian, Y., Ma, X., Liu, W. Inhibition of PCDD/Fs formation from dioxin precursors by calcium oxide. Chemosphere, 60, 785-790, 2005.
Lisa Lundin, Stellan Marklund. Thermal degradation of PCDD/F, PCB and HCB in municipal solid waste ash, Chemosphere 67 (2007) 474-481.
Long-Full Lin, Wen-Jhy Lee, Hsing-Wang Li, Mao-Sung Wang, Guo-Ping Chang-Chien. Characterization and inventory of PCDD/F emissions from coal-fired power plants and other sources in Taiwan, Chemosphere 68 (2007) 1642-1649.
J.H. Yan, Z. Peng, S.Y. Lu, X.D. Li, M.J. Ni, K.F. Cen, H.F. Dai. Degradation of PCDD/Fs by mechanochemical treatment of fly ash from medical waste incineration, Journal of Hazardous Materials 147 (2007) 652-657.
Leona Vlkova, Vladimir Pekarek, Vera Pacakov, Jindrich Karban, Michal Bures, KarelStulik. Dechlorination ability of municipal waste incineration fly ash for polychlorinated phenols, Chemosphere 56 (2004) 935-942.
Luijk. R, Dorland C., Smit P., Jansen J., Govers H. A. J.，The role of bromine in the de novo synthesis in a model fly ash system ，Chemosphere, Volume 28, Issue, Pages 1299-13097, 1994.
Leeuwen F. X. Rolaf van, Mark Feeley, Dieter Schrenk, John Christian Larsen, William Farland, Maged Younes，Dioxins: WHO’s tolerable daily intake (TDI) revisited，Vol.40 ,pp. 1095-1101, 2000.
Mininni, G., Sbrilli, A., Maria, Braguglia, C.M., Guerriero, E., Marani, D., Rotatori, M. Dioxins, furans and polycyclic aromatic hydrocarbons emissions from a hospital and cemetery waste incinerator, Atmospheric Environmental, 41, 8527-8536, 2007.
McKay Gordon. Dioxin characterisation, formation and minimisation during
municipal solid waste (MSW) incineration: review, Chemical Engineering, 343–368,2002.
M.S. Milligan,E.R. Altwicker，Formation of dioxins: Competing rates between chemically similar precursors and de novo reactions，Vol.27, pp. 301-307 ,199.
Naikwadi, K.P., Karasek, F.W. Prevention of PCDD formation in MSW incinerators by inhibition of catalytic activity of fly ash produced. Chemosphere, 19, 299-304, 1989.
Nicolas Visez, Jean-Pierre Sawerysyn. Chlorination and thermal degradation of 2-chlorodibenzodioxin and dibenzofuran by CuCl2 or CuCl at 350℃, Chemosphere 73 (2008) S90-S93.
Okamoto Yasuharu，A new dioxin decomposition process based on a hybrid density-functional calculation，Chemical Physics Letters, Volume 310, Issues 3-4, 3, Pages 355-360 ,September 1999.
Pandelova, M.E., Lenoir, D., Kettrup, A., Schramm, K.W. Primary measures for reduction of PCDD/F in co-combustion of lignite coal and waste: effect of various inhibitors, Environ. Sci. Technol. 39 (2005) 3345-3350.
Rappe, C. Sources of PCDDs and PCDFs. Introduction. Reactions, levels, patterns, profiles and trends, Chemosphere, 25, 41-44, 1992.
Ruokojärvi, P., Aatamila, M., Tuppurainen, K., Ruuskanen, J. Effect of urea on fly ash PCDD/F concentrations in different particle sizes, Chemosphere 43 (2001) 757-762.
R. Grabic , V. Pekarek, J. Ullrich , M. Puncochar , E. Fiserova ,
J. Karban , M. SSebestova. Effect of reaction time on PCDD and PCDF formation by de novo synthetic reactions under oxygen deficient and rich atmosphere, Chemosphere 49 (2002) 691-696.
Stieglitz, L., Zwick, G., Beck, J., Roth, W., Vogg, H. On the de-novo synthesis of PCDD/F on fly ash of municipal waste incinerators, Chemosphere 18, 1219-1226, 1989.
Schwarz Gert, Hans R. Kricheldorf，Phase transitions and melting of poly(4-hydroxybenzoate)，Polymer, Volume 31, Issue 3, Pages 481-485, March 1990.
Sri Harjanto, Eiki Kasai, Toshikatsu Terui, Takashi Nakamura. Formation and transport of PCDD/Fs in the packed bed of soil containing organic chloride during a thermal remediation process, Chemosphere 49 (2002) 217-224.
Stanmore, B. R. The formation of dioxins in combustion systems. Combustion & Flame, 136, 398-427, 2004.
Tejima, H., Nakagawa, I., Shinoda, T.A., Maeda, I. PCDDs/PCDFs reduction by good combustion technology and fabric filter with/without activated carbon injection, Chemosphere 32 (1996) 169-175.
Taiwan Environmental Protection Agency; available at http://waste.epa.gov.tw/prog/IndexFrame.asp?Func=5 (accessed 2008).
U.S. Environmental Protection Agency, Exposure and Human Health Reassessment of 2,3,7,8-Tetrachlorodibenzo-p-Dioxin (TCDD) and Related Compounds National Academy Sciences (NAS) Review Draft, (2000) EPA/600/P-00/001Bb.
U.S. Environmental Protection Agency. Tetra- through Octa-Chlorinated Dioxins and Furans by Isotope Dilution HRGC/HRMS, Revision B, Method-1613B, 1994.
US EPA, The Inventory of Sources of Dioxin in the United States (External Review Draft 2005).EPA/600/p-03/002a,2005.
Wenbin Liu, Minghui Zheng , Bing Zhang, Yong Qian, Xiaodong Ma, Wenxia Liu. Inhibition of PCDD/Fs formation from dioxin precursors by calcium oxide, Chemosphere 60 (2005) 785-790.
Wei Wang, Xingbao Gao, Lei Zheng, Yuxin Lan. Reductive dechlorination of polychlorinated dibenzo-p-dioxins and dibenzofurans in MSWI fly ash by sodium hypophosphite, Separation and Purification Technology 52 (2006) 186-190.
Wen-Jhy Lee, Shun-I Shih, Chih-Yuan Chang, Yi-Chieh Lai, Lin-Chi Wang, Guo-Ping Chang-Chien. Thermal treatment of polychlorinated dibenzo-p-dioxins and dibenzofurans from contaminated soils, Journal of Hazardous Materials 160 (2008) 220-227.
Wang Lin-Chi, Wen-Jhy Lee, Wei-Shan Lee, Guo-Ping Chang-Chien, Perng-Jy Tsai. Effect of chlorine content in feeding wastes of incineration on the emission of polychlorinated dibenzo-p-dioxinsydibenzofurans, The Science of the Total Environment 302 (2003) 185-198.
Wiles Carlton C，Municipal solid waste combustion ash: State–of-the- knowledge，Journal of Hazardous Materials, Volume 47, Issues 1-3, Pages 325-344, May 1996.
Wiesenhahn C. P. Li, D. F., S. S. Penner，Production of toxic equivalents to 2, 3, 7, 8-TCDD in municipal-waste incinerators (MWIs)，Energy, Volume 13, Issue 3, Pages 217-223, March 1988.
WHO-Environmental health No. 24 Chernobyl: Health hazards from radiocaesium: Report WHO meeting June 1987, 42 pp
Y. Kakuta, T. Matsuto, Y. Tojo, H. Tomikawa . Characterization of residual carbon influencing on de novo synthesis of PCDD/Fs in MSWI fly ash, Chemosphere 68 (2007) 880-886.
Y i - Chieh Lai , Wen - J hy Lee Hsing – Wang Li, Lin- Chi Wang, Guo-Ping Chang-Chien. Inhibition of Polybrominated Dibenzo-p-dioxin and Dibenzofuran Formation from the Pyrolysis of Printed Circuit Boards, Environ. Sci. Technol. 2007, 41, 957-962.
Yi-Chieh Lai, Wen-Jhy Lee, Kuo-Lin Huang, Hong-Hsin Huang. Emissions of polycyclic aromatic hydrocarbons from thermal pre-treatment of waste hydrodesulfurization catalysts, Chemosphere 69 (2007) 200-208.
行政院環境保護署，http://www.epa.gov.tw/，2009
環保署，“固定污染源戴奧辛排放標準”， http://w3.epa.gov.tw/epalaw/index.aspx，2008
環保署，“廢棄物焚化爐戴奧辛管制及排放標準”， http://w3.epa.gov.tw/epalaw/index.aspx，2008

環保署，“固定污染源管制”，
http://stationary.estc.tw/news.asp?xItem=1888&CtNode=529，2008
行政院環境保護署垃圾焚化飛灰熔融廠興建工程規劃、設計及監造專案工作計畫 EPA-92-E2Y1-04-001, 2004。
行政院環境保護署環境檢驗所，戴奧辛及呋喃檢測方法—同位素標幟稀釋氣相層析/高解析質譜法，NIEA M801.11B，2005
張旭彰，“灰渣熔融處理法的理論與實務”，工業污染防治，第十二卷， 第四期，pp. 95-112，1993。
林鴻祺, 江東法, 廖明村, “一般廢棄物焚化灰渣處理處置及再利用技術探討”, 一般廢棄物焚化灰渣資源化技術與實務研討會, pp.69-90, 台北市, 1996。
郭益銘，“焚化灰渣玻璃化之評估研究”，博士論文，國立成功大學環境環境工程系碩士論文，2002。
黃奕叡，“廢棄物焚化灰渣熱熔之研究”，碩士論文，國立成功大學環境工程學系，2002。
張志遠，“戴奧辛/呋喃污染土壤熱脫附研究”，碩士論文，國立成功大學環境工程學系，2007。
張乃斌，固體廢棄物處理，三民書局股份有限公司出版，1998。
陳聯平，十年回顧：台灣地區垃圾焚化爐營建實錄，2002。
詹炯淵，“垃圾焚化飛灰管理對策之研究”，碩士論文，國立台灣大學環境工程學研究所，2001。
廖明村, 張豐藤, “垃圾焚化灰渣處理處置及資源化技術探討”, 中興工程, 第60期, pp.125-136, 1998。
李俊賢、詹長權、王榮德，從戴奧辛毒性談台灣醫療事業廢棄物焚化處理，中國衛誌，Vol.18，pp.237-240，1999。
陳建民、李孫榮，戴奧辛、環境與人類，工業污染防治，Vol.57，1996。