| 研究生: |
莊育修 Chuang, Yu-Hsiu |
|---|---|
| 論文名稱: |
冬瓜子之成分研究 The constituents of the seeds of Benincasa hispida |
| 指導教授: |
吳天賞
Wu, Tian-Shung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
理學院 - 化學系 Department of Chemistry |
| 論文出版年: | 2011 |
| 畢業學年度: | 99 |
| 語文別: | 中文 |
| 論文頁數: | 86 |
| 中文關鍵詞: | 冬瓜屬 、冬瓜子 、三酸甘油酯 |
| 外文關鍵詞: | Benincasa, Benincasa hispida, triglyceride |
| 相關次數: | 點閱:38 下載:11 |
| 分享至: |
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由冬瓜子(Benincasa hispida)分離得到40個化合物,其中25個經光譜分析,確認其化學結構,分別為1,3-dilinoleoyl-2-olein (18)、squalene (25)、β-sitosterol (26) & stigmasterol (27)、β-sitosteryl laurate (28)、Δ7-sitosteryl laurate (29)、α-spinasteryl laurate (30)、cussoracoside C (31)、(2E, 4E)-dihydrophaseic acid (32)、(2Z, 4E)-dihydrophaseic acid (33)、cucumegastigmane I (34)、dehydrovomifoliol (35)、cyclo(Gly- L-Leu) (36)、cyclo(Gly- L-Phe) (37)、N5-(4-methoxyphenyl) methyl-L-glutamine (38)、vanillin (39)、4-hydroxybenzyl alcohol (40)、(E)-ferulic acid (41)、trans-coniferyl aldehyde (42)、erythro-guaiacylglycerol (43)、dihydroconiferyl alcohol (44)、trans-coniferyl alcohol (45)、glabrol (46)、(2S)-liquiritigenin-4’-methyl ether (47)、hyaloserin (48)。上述化合物的結構乃是利用1維和2維核磁共振光譜,質譜,紫外光譜以及紅外線光譜決定,並與文獻所報導的物理性質和光譜數據進行比對得到確認。另有15個未知化合物結構尚待確定。
Forty compounds were isolated from the seeds of Benincasa hispida. Among them, twenty five known compounds were identified their structures as 1,3-dilinoleoyl-2-olein (18), squalene (25), β-sitosterol (26) & stigmasterol (27), β-sitosteryl laurate (28), Δ7-sitosteryl laurate (29), α-spinasteryl laurate (30), cussoracoside C (31), dehydrovomifoliol (32), cucumegastigmane I (33), (2E, 4E)-dihydrophaseic acid (34), (2Z, 4E)-dihydrophaseic acid (35), cyclo(Gly- L-Leu) (36), cyclo(Gly- L-Phe) (37), N5-(4-methoxyphenyl) methyl- L-glutamine (38), vanillin (39), 4-hydroxybenzyl alcohol (40), (E)-ferulic acid (41), trans-coniferyl aldehyde (42), erythro-guaiacylglycerol (43), dihydroconiferyl alcohol (44), trans-coniferyl alcohol (45), glabrol (46), (2S)-liquiritigenin-4'-methyl ether (47) and hyaloserin (48) by 1H-, 13C-, 2D-NMR, MS, UV and IR spectral analyses. The structures were identified by comparison of their physical and spectral data with those reported in the literature. In addition, fifteen unknown compounds have to further identify their structures by spectral and chemical methods.
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