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研究生： 林秦竹
Lin, Cin-Jhu
論文名稱： Aza-Michael加成反應合成之高電位高分子電解質於鋰電池之應用
High-Voltage Polymer Electrolyte Synthesized from Aza-Michael Addition Reaction for Lithium Batteries
指導教授： 鄧熙聖
Teng, Hsi-Sheng
學位類別： 碩士
Master
系所名稱： 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年： 2025
畢業學年度： 113
語文別： 中文
論文頁數： 130
中文關鍵詞： 鋰金屬電池 、固態電解質 、Aza-Michael加成反應 、互穿式電解質
外文關鍵詞： Lithium metal battery, Solid-state electrolytes, Aza-Michael Addition Reaction, Interpenetrating Polymer Network Electrolyte
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    • 摘要 I High-Voltage Polymer Electrolyte Synthesized from Aza-Michael Addition Reaction for Lithium Batteries II 致謝 XXV 目錄 XXVI 圖目錄 XXX 表目錄 XXXIV 第一章、緒論 1 1.1 鋰電池的發展概述 1 1.2 鋰離子電池構造 3 1.3 鋰離子電池工作原理 4 1.4 正極材料 6 1.4.1 層狀結構（layered） 6 1.4.2 尖晶石結構（spinel） 8 1.4.3 橄欖石結構（olivine） 9 1.5 負極材料 11 1.5.1 碳基負極(Carbon-based anodes) 11 1.5.2氧化物負極(Oxide-based anodes) 12 1.5.3 合金型負極(Alloy anodes) 13 1.5.4 鋰金屬負極（Lithium metal anodes） 14 1.6 電解質 16 1.6.1 液態電解質(Liquid electrolytes) 16 1.6.2 膠態電解質（Gel Polymer Electrolyte） 20 1.6.3 全固態電解質（Solid-State Electrolytes） 23 1.7 研究動機與目的 31 第二章、理論說明與文獻回顧 32 2.1 Aza-Michael Addition Reaction 32 2.2 互穿式高分子電解質，Interpenetrating polymer network electrolytes, IPN 33 2.3 雙鋰鹽電解質系統（Dual-lithium salt system） 35 2.4 聚（偏二氟乙烯-co-六氟丙烯），PVDF-HFP 36 2.5 導離子度（Ionic Conductivity） 38 2.6 鋰離子遷移常數（Lithium-ion transference number, tLi+） 39 2.7 電化學阻抗圖譜(Electrochemical Impedance Spectroscopy） 42 2.8 臨界電流密度 （Critical current density, CCD） 44 第三章、實驗方法與儀器原理介紹 47 3.1 實驗藥品與用品 47 3.2 實驗儀器設備 48 3.3 LFP正極極片製作 48 3.4 Aza-Michael Synthesized Polymer Electrolyte(AME)電解質之製作 50 3.5 鈕扣型電池之組裝 51 3.6 實驗分析儀器之原理介紹 52 3.6.1 掃描式電子顯微鏡 （Scanning Electron Microscope） 52 3.6.2 傅立葉轉換紅外光譜儀 （Fourier-transform infrared spectroscopy） 54 3.6.3 熱重分析儀 （Thermogravimetric analyzer） 55 3.6.4 動態機械分析 （Dynamic mechanical analysis） 57 3-7 電化學測試 59 3.7.1 導離子度 （Ionic conductivity, σ） 59 3.7.2 鋰離子遷移常數 （Lithium transference number, tLi+） 59 3.7.3 線性掃描伏安法 （Linear sweep voltammetry, LSV） 60 3.7.4 臨界電流密度 （Critical current density, CCD） 60 3.7.5 電池倍率及循環充放電性能測試 61 第四章、結果與討論 62 4.1 固態電解質 63 4.1.1反應機制 63 4.1.2 FTIR 64 4.1.3 Raman 67 4.2 AME基本電化學測試 68 4.2.1 導離子度 68 4.2.2 鋰離子遷移常數 71 4.2.3 電化學窗口 72 4.3 AME熱穩定性與機械強度測試 73 4.3.1 熱穩定性測試 73 4.3.2 機械強度測試 75 4.4 SPE與鋰金屬界面穩定性測試 76 4.4.1 界面相容性測試 76 4.4.2 CCD測試 79 4.5 全電池性能測試 81 4.5.1 倍率充放電性能測試 81 4.5.2 循環充放電性能測試 83 4.5.3 SEM觀察循環後的鋰金屬表面 86 第五章、結論 88 參考文獻 89

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