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研究生: 張荏凱
Chang, Jen-Kai
論文名稱: 常溫水相環境友善合成法製備可調節近紅外發光性質的水溶性Ag2Se量子點
Environmentally Friendly Water-Based Synthesis of Water-Soluble Ag2Se Quantum Dots with Tunable Near-Infrared Emission Properties at Room Temperature
指導教授: 涂維珍
Tu, Wei-Chen
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 奈米積體電路工程碩士博士學位學程
MS Degree/Ph.D. Program on Nano-Integrated-Circuit Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 92
中文關鍵詞: 硒化銀量子點近紅外光光感測器
外文關鍵詞: Silver Selenide, Quantum Dots, Near-Infrared Light, Photodetector
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  • 研究成功在常溫常壓條件下採用水相合成法合成了具有均勻尺寸分佈的水溶性硒化銀量子點(Ag2Se QDs)。合成過程中使用了硝酸銀(AgNO3)和亞硒酸鈉(Na2SeO3)作為前體材料,並添加巰基乙酸(TGA)作為封端劑分子。我們對不同的合成參數進行了調控,包括元素比例、配體用量、酸鹼度、濃度、合成時間。通過XRD、FTIR、FESEM、EDS、HRTEM、UV-Vis和PL等表徵方法,詳細研究了合成得到的量子點的結構和性質並將其材料應用於近紅外光感測器。
    研究結果顯示,合成得到的硒化銀量子點(Ag2Se QDs)尺寸約為10 nm,合成的量子點在紅光到近紅外光波段表現出可調節的發光性質,發光峰值範圍約為730-880 nm,FWHM範圍約為65-155 nm,近紅外光感測器元件的最大響應度約170 (mA/W),最大光探測率約18.6*1010 Jones,上升時間約為1秒,下降時間約為1秒,。通過對合成參數的優化,我們成功合成了具有優異光學性質的硒化銀量子點(Ag2Se QDs),為其在光學與電學領域提供了潛在的應用價值。

    The successful synthesis of water-soluble silver selenide quantum dots (Ag2Se QDs) with uniform size distribution using an aqueous-phase synthesis method under ambient conditions is investigated. The synthesis process utilized silver nitrate (AgNO3) and sodium selenite (Na2SeO3) as precursor materials, with thioglycolic acid (TGA) added as a capping agent molecule. Various synthesis parameters were controlled, the structure and properties of the synthesized quantum dots were thoroughly studied, and their material application was explored in near-infrared light photodetector.
    The research findings reveal that the synthesized silver selenide quantum dots (Ag2Se QDs) have a size of approximately 10 nm. The synthesized quantum dots exhibit tunable luminescent properties in the red to near-infrared wavelength range, with a peak emission ranging from 730 to 880 nm and a FWHM range of 65 to 155 nm. The maximum responsivity of the near-infrared light sensor element is around 170 (mA/W), and the maximum detectivity is approximately 18.6*1010 Jones. The rise time and fall time are both around 1 second. By optimizing the synthesis parameters, we successfully produced silver selenide quantum dots (Ag2Se QDs) with excellent optical properties, offering potential application value in the fields of optics and electronics.

    中文摘要 i 致謝 viii 目錄 ix 圖目錄 xiii 表目錄 xvii 第一章 緒論 1 1-1 前言 1 1-2 研究動機 1 1-3 量子點的簡介 2 1-4 量子點的應用 4 1-5 硒化銀簡介 5 1-6 近紅外光簡介與應用領域 6 1-7 近紅外量子點與自駕車的關係 7 第二章 原理 9 2-1 量子點物理和化學性質 9 2-1-1 量子侷限效應(Quantum Confinement Effect) 9 2-1-2 表面效應(Surface Effect) 10 2-1-3 量子穿隧效應(Quantum tunneling effect) 11 2-2 量子點製備方法 12 2-2-1 水相合成法(Aqueous phase synthesis method) 12 2-2-2 熱分解法(Thermal decomposition method) 13 2-2-3 微波法(Microwave-assisted method) 14 2-3 光電感測器基本原理 15 2-3-1 光伏效應(Photovoltaic effect, PVE) 16 2-3-2 光電導效應(Photoconductive effect, PCE) 17 2-3-3 光電門效應(Photogating Effect, PGE) 18 第三章 實驗材料及儀器 19 3-1 實驗化學藥品及材料 19 3-2 製程儀器 20 3-2-1 秤重天平 20 3-2-2 電磁加熱攪拌器 21 3-2-3 可調式微量吸管 22 3-2-4 pH值檢測器 23 3-2-5 超音波震盪器 24 3-2-6 微量離心機 25 3-2-7 紫外光臭氧清洗機 26 3-2-8 旋轉塗佈機 27 3-2-9 熱蒸鍍機 28 3-2-10 烘箱 29 3-3 量測儀器 30 3-3-1 微光激發光譜儀 30 3-3-2 傅立葉轉換紅外光光譜儀 31 3-3-3 紫外光/可見光/近紅外光 分光光譜儀 32 3-3-4 X光繞射儀 33 3-3-5 高解析場發射掃描穿透式電子顯微鏡 34 3-3-6 化學分析電子光譜儀 36 3-3-7 光學顯微鏡 37 3-3-8 電性量測系統 38 第四章 實驗步驟 39 4-1 Ag2Se量子點製備 39 4-2 Ag2Se量子點光電感測器元件製程 45 4-2-1 基板清洗 45 4-2-2 基板溼蝕刻 45 4-2-3 紫外線臭氧處理 46 4-2-4 旋轉塗佈 46 4-2-5 熱退火 46 4-2-6 蒸鍍電極 46 4-2-7 Ag2Se量子點光電感測器元件 48 第五章 結果與討論 49 5-1 Ag2Se量子點分析 49 5-1-1 光學圖像 49 5-1-2 XRD晶相分析 51 5-1-3 TEM分析 52 5-1-4 EDS素像分析 54 5-1-5 SAED分析 55 5-1-6 XPS元素分析 56 5-1-7 FTIR分析 58 5-1-8 UV/Vis/NIR吸收光譜圖分析 61 5-1-9 光致發光光譜分析 65 5-1-10 能隙分析 75 5-1-11 特性分析 76 5-2 Ag2Se量子點/SiO2/Si異質結構光電感測器 78 5-2-1 Ag2Se量子點薄膜OM影像分析 78 5-2-2 Ag2Se量子點/SiO2/Si異質結構光電感測器I-V電流電壓量測分析 79 5-2-3 光電流與光響應度分析 80 5-2-4 光探測率分析 82 5-2-5 I-V元件開關燈響應分析 84 第六章 結論及未來展望 87 第七章 參考文獻 88

    [1] A. Rogalski, J. Antoszewski, and L. Faraone, "Third-generation infrared photodetector arrays," Journal of Applied Physics, vol. 105, no. 9, 2009, doi: 10.1063/1.3099572.
    [2] H. Tan et al., "Single-Crystalline InGaAs Nanowires for Room-Temperature High-Performance Near-Infrared Photodetectors," Nano-Micro Letters, vol. 8, no. 1, pp. 29-35, 2016/01/01 2016, doi: 10.1007/s40820-015-0058-0.
    [3] P. Norton, "HgCdTe infrared detectors," Optoelectronics review, no. 3, pp. 159-174, 2002.
    [4] G. Konstantatos et al., "Ultrasensitive solution-cast quantum dot photodetectors," Nature, vol. 442, no. 7099, pp. 180-183, 2006.
    [5] S. Lee et al., "Sol-gel processed p-type CuO phototransistor for a near-infrared sensor," IEEE Electron Device Letters, vol. 39, no. 1, pp. 47-50, 2017.
    [6] L. Tan, A. Wan, T. Zhao, R. Huang, and H. Li, "Aqueous synthesis of multidentate-polymer-capping Ag2Se quantum dots with bright photoluminescence tunable in a second near-infrared biological window," ACS applied materials & interfaces, vol. 6, no. 9, pp. 6217-6222, 2014.
    [7] Z. Zhang et al., "Highly efficient Ag2Se quantum dots blocking layer for solid-state dye-sensitized solar cells: Size effects on device performances," Materials Today Energy, vol. 7, pp. 27-36, 2018.
    [8] S. Tang, C. He, D. Li, W. Cai, L. Fan, and Y. Li, "Precursor reactivity differentiation for single-step preparation of Ag2Se@ Ag2S core–shell nanocrystals with distinct absorption and emission properties enabling sensitive near-infrared photodetection," Journal of Materials Science, vol. 53, no. 16, pp. 11355-11366, 2018.
    [9] B. Gates et al., "Synthesis and characterization of crystalline Ag2Se nanowires through a template‐engaged reaction at room temperature," Advanced Functional Materials, vol. 12, no. 10, pp. 679-686, 2002.
    [10] Y. J. Glanville, D. G. Narehood, P. E. Sokol, A. Amma, and T. Mallouk, "Preparation and synthesis of Ag 2 Se nanowires produced by template directed synthesis," Journal of Materials Chemistry, vol. 12, no. 8, pp. 2433-2434, 2002.
    [11] L. Jacak, P. Hawrylak, and A. Wojs, Quantum dots. Springer Science & Business Media, 2013.
    [12] S. K. Kailasa, K.-H. Cheng, and H.-F. Wu, "Semiconductor Nanomaterials-Based Fluorescence Spectroscopic and Matrix-Assisted Laser Desorption/Ionization (MALDI) Mass Spectrometric Approaches to Proteome Analysis," Materials, vol. 6, no. 12, pp. 5763-5795doi: 10.3390/ma6125763.
    [13] M. Díaz‑González, A. de la Escosura‑Muñiz, M. T. Fernandez‑Argüelles, F. J. G. Alonso, and J. M. Costa‑Fernandez, "Quantum dot bioconjugates for diagnostic applications," Surface-modified nanobiomaterials for electrochemical and biomedicine applications, pp. 133-176, 2020.
    [14] D. Bera, L. Qian, T.-K. Tseng, and P. H. Holloway, "Quantum dots and their multimodal applications: a review," Materials, vol. 3, no. 4, pp. 2260-2345, 2010.
    [15] V. Reshma and P. Mohanan, "Quantum dots: Applications and safety consequences," Journal of Luminescence, vol. 205, pp. 287-298, 2019.
    [16] A. Sahu, A. Khare, D. D. Deng, and D. J. Norris, "Quantum confinement in silver selenide semiconductor nanocrystals," Chemical Communications, vol. 48, no. 44, pp. 5458-5460, 2012.
    [17] A. J. E. Rettie et al., "Ag2Se to KAg3Se2: Suppressing Order–Disorder Transitions via Reduced Dimensionality," Journal of the American Chemical Society, vol. 140, no. 29, pp. 9193-9202, 2018/07/25 2018, doi: 10.1021/jacs.8b04888.
    [18] A. Corning, "Measuring NIR Sources for Safe & Accurate 3D Sensing," 03/01 2019.
    [19] C. Rablau, "LIDAR–A new (self-driving) vehicle for introducing optics to broader engineering and non-engineering audiences," in Education and Training in Optics and Photonics, 2019: Optica Publishing Group, p. 11143_138.
    [20] L. Carrara and A. Fiergolski, "An optical interference suppression scheme for TCSPC flash LiDAR imagers," Applied Sciences, vol. 9, no. 11, p. 2206, 2019.
    [21] S. Jagtap, P. Chopade, S. Tadepalli, A. Bhalerao, and S. Gosavi, "A review on the progress of ZnSe as inorganic scintillator," Opto-Electronics Review, vol. 27, no. 1, pp. 90-103, 2019.
    [22] S. Majetich and A. Carter, "Surface effects on the optical properties of cadmium selenide quantum dots," The Journal of Physical Chemistry, vol. 97, no. 34, pp. 8727-8731, 1993.
    [23] A. Riskin, "Study of the CSD process for the ordered deposition of metallic nanocrystals," 2012.
    [24] J. T. Lue, "Physical properties of nanomaterials," Encyclopedia of nanoscience and nanotechnology, vol. 10, no. 1, pp. 1-46, 2007.
    [25] K. T. Yong et al., "Aqueous phase synthesis of CdTe quantum dots for biophotonics," Journal of Biophotonics, vol. 4, no. 1‐2, pp. 9-20, 2011.
    [26] S. Navaladian, B. Viswanathan, R. Viswanath, and T. Varadarajan, "Thermal decomposition as route for silver nanoparticles," Nanoscale research letters, vol. 2, pp. 44-48, 2007.
    [27] K. J. Sreeram, M. Nidhin, and B. U. Nair, "Microwave assisted template synthesis of silver nanoparticles," Bulletin of Materials Science, vol. 31, pp. 937-942, 2008.
    [28] Q. Qiu and Z. Huang, "Photodetectors of 2D materials from ultraviolet to terahertz waves," Advanced Materials, vol. 33, no. 15, p. 2008126, 2021.
    [29] M. Long, P. Wang, H. Fang, and W. Hu, "Progress, challenges, and opportunities for 2D material based photodetectors," Advanced Functional Materials, vol. 29, no. 19, p. 1803807, 2019.
    [30] J. Wang, J. Han, X. Chen, and X. Wang, "Design strategies for two‐dimensional material photodetectors to enhance device performance," InfoMat, vol. 1, no. 1, pp. 33-53, 2019.
    [31] H. Wang, B. Yu, S. Jiang, L. Jiang, and L. Qian, "UV/ozone-assisted tribochemistry-induced nanofabrication on Si(100) surfaces," RSC Advances, 10.1039/C7RA07198A vol. 7, no. 63, pp. 39651-39656, 2017, doi: 10.1039/C7RA07198A.
    [32] N. Singh, V. Murugadoss, J. Rajavedhanayagam, and S. Angaiah, "A wide solar spectrum light harvesting Ag2Se quantum dot-sensitized porous TiO2 nanofibers as photoanode for high-performance QDSC," Journal of Nanoparticle Research, vol. 21, no. 8, p. 176, 2019/08/10 2019, doi: 10.1007/s11051-019-4619-x.
    [33] W.-Y. Lee et al., "High-Detectivity Flexible Near-Infrared Photodetector Based on Chalcogenide Ag2Se Nanoparticles," Advanced Optical Materials, vol. 7, no. 22, p. 1900812, 2019/11/01 2019, doi:
    [34] S. Tang, C. He, D. Li, W. Cai, L. Fan, and Y. Li, "Precursor reactivity differentiation for single-step preparation of Ag2Se@Ag2S core–shell nanocrystals with distinct absorption and emission properties enabling sensitive near-infrared photodetection," Journal of Materials Science, vol. 53, no. 16, pp. 11355-11366, 2018/08/01 2018, doi: 10.1007/s10853-018-2465-3.
    [35] L. Li, Y. Cheng, Y. Ding, Y. Lu, and F. Zhang, "Application of thioglycolic acid capped nano-ZnS as a fluorescence probe for the determination of nevirapine," Analytical Methods, vol. 4, no. 12, pp. 4213-4219, 2012.
    [36] U. Chougale, S.-H. Han, M. Rath, and V. Fulari, "Synthesis, characterization and surface deformation study of nanocrystalline Ag2Se thin films," Materials Physics and Mechanics, vol. 17, pp. 47-58, 05/10 2013.
    [37] L. Mercantili, F. Davis, and S. P. J. Higson, "Ultrasonic Initiation of the Alkaline Hydrolysis of Triglycerides (Saponification) Without Phase Catalysis," Journal of Surfactants and Detergents, vol. 17, no. 1, pp. 133-141, 2014/01/01 2014, doi: 10.1007/s11743-013-1450-8.
    [38] S. Banerjee et al., "N-acetyle cysteine assisted synthesis of core⿿ shell Ag2S with enhanced light transmission and diminished reflectance: Surface modifier for c-SiNx solar cells," Journal of industrial and engineering chemistry, vol. 40, pp. 54-61, 2016.
    [39] A. Mandal and N. Tamai, "Influence of Acid on Luminescence Properties of Thioglycolic Acid-Capped CdTe Quantum Dots," The Journal of Physical Chemistry C, vol. 112, no. 22, pp. 8244-8250, 2008/06/01 2008, doi: 10.1021/jp801043e.
    [40] Y.-P. Gu, R. Cui, Z.-L. Zhang, Z.-X. Xie, and D.-W. Pang, "Ultrasmall Near-Infrared Ag2Se Quantum Dots with Tunable Fluorescence for in Vivo Imaging," Journal of the American Chemical Society, vol. 134, no. 1, pp. 79-82, 2012/01/11 2012, doi: 10.1021/ja2089553.
    [41] C.-N. Zhu, P. Jiang, Z.-L. Zhang, D.-L. Zhu, Z.-Q. Tian, and D.-W. Pang, "Ag2Se Quantum Dots with Tunable Emission in the Second Near-Infrared Window," ACS Applied Materials & Interfaces, vol. 5, no. 4, pp. 1186-1189, 2013/02/27 2013, doi: 10.1021/am303110x.
    [42] S. Yan, L. Zhang, Y. Tang, and Y. Lv, "Synthesis of water-soluble Ag 2 Se QDs as a novel resonance Rayleigh scattering sensor for highly sensitive and selective ConA detection," Analyst, vol. 139, no. 17, pp. 4210-4215, 2014.
    [43] J.-Y. Zhao et al., "How different are the surfaces of semiconductor Ag2Se quantum dots with various sizes?," Science Bulletin, vol. 67, no. 6, pp. 619-625, 2022/03/30/ 2022.
    [44] L.-J. Shi et al., "Near-infrared Ag 2 Se quantum dots with distinct absorption features and high fluorescence quantum yields," RSC advances, vol. 6, no. 44, pp. 38183-38186, 2016.
    [45] M. Yu et al., "Pb‐Doped Ag2Se Quantum Dots with Enhanced Photoluminescence in the NIR‐II Window," Small, vol. 17, no. 8, p. 2006111, 2021.
    [46] M. J. Park, K. Park, and H. Ko, "Near-infrared photodetector achieved by chemically-exfoliated multilayered MoS2 flakes," Applied Surface Science, vol. 448, pp. 64-70, 2018.
    [47] D. Chen et al., "Ag2S/ZnO core-shell nanoheterojunction for a self-powered solid-state photodetector with wide spectral response," Journal of Alloys and Compounds, vol. 735, pp. 2491-2496, 2018.
    [48] Y. Xie et al., "Ultrabroadband MoS2 photodetector with spectral response from 445 to 2717 nm," Advanced Materials, vol. 29, no. 17, p. 1605972, 2017.
    [49] M. Amiri and N. Alizadeh, "Highly photosensitive near infrared photodetector based on polypyrrole nanoparticle incorporated with CdS quantum dots," Materials Science in Semiconductor Processing, vol. 111, p. 104964, 2020.
    [50] H. Roshan, F. Ravanan, M. H. Sheikhi, and A. Mirzaei, "High-detectivity near-infrared photodetector based on Ag2S nanocrystals," Journal of Alloys and Compounds, vol. 852, p. 156948, 2021.
    [51] D. Yang and Q. Zhou, "Solution-processed P3HT: PbS-based nIR photodetector with FET configuration," IEEE Photonics Technology Letters, vol. 32, no. 2, pp. 77-80, 2019.
    [52] J. He et al., "Synergetic effect of silver nanocrystals applied in PbS colloidal quantum dots for high-performance infrared photodetectors," Acs Photonics, vol. 1, no. 10, pp. 936-943, 2014.

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