瀝青是構建和維護路面基礎設施的核心組成部分，為道路、公路及各類交通網絡提供耐用且具成本效益的表面。通過改質以提升瀝青的耐久性及力學性能是一項持續的工作，然而，目前尚無針對瀝青膠泥的標準化改質程序。本研究探討了高分子改質瀝青（PMB）的改質過程如何影響其短期及長期的成效特性。本研究分為兩個階段。在第一階段中，採用了石膠泥瀝青（SMA）混合料設計對粒料級配進行優化，並基於成效評估了兩個試驗級配。研究的第二階段則涉及實驗室老化模擬，以預測兩種黏度相同但成效等級不同的高分子改質膠泥的短期及長期成效。本研究依據AASHTO R30標準進行短期老化模擬，對鬆散瀝青混合料進行老化處理。此外，研究採用了NCHRP 09-54項目開發的先進老化模擬程序進行長期老化，該方法包含氣候老化指數（CAI），以更真實地模擬實際氣候條件。在短期及長期老化模擬後，進行了兩項成效測試（漢堡車轍試驗和IDEAL-CT試驗）。為了進一步分析差異，從混合料中提取了老化後的膠泥，並進行了流變學和化學測試，包括多重應力潛變回復（MSCR）、線性震幅掃描（LAS）、凝膠滲透層析（GPC）及傅立葉紅外光譜（FTIR）等測試。根據成效測試結果，PMA-I的成效優於PMA-II，這與基於膠泥成效等級系統的預期相反。化學和流變學測試結果進一步支持了混合料成效結果，證明了PMA-I的優越性。PMA-II的低劣成效可能歸因於其高分子改質過程中出現了過早老化。

Asphalt is a fundamental component in constructing and maintaining pavement infrastructure, providing a durable and cost-effective surface for roads, highways, and various transportation networks. Enhancing the durability and mechanical performance of asphalt through modifications is a continuous endeavor, yet there is no standardized procedure for modifying the asphalt binder. This study investigates how the modification process of Polymer-Modified Bitumen (PMB) affects its short-term and long-term performance characteristics. The study is divided into two phases. In the first phase, the gradation was optimized using the Stone Mastic Asphalt (SMA) mix design. Two trial gradations were evaluated based on their performance. The study's second phase involves laboratory aging simulations to predict both short-term and long-term performances of two polymer-modified binders with the same viscosity but different performance grades. The AASHTO R30 standard was used for short-term aging simulation, subjecting loose asphalt mixtures to aging. Additionally, an advanced aging simulation procedure developed under the NCHRP 09-54 project was employed for long-term aging. This approach includes the Climatic Aging Index (CAI) to mimic real-world climatic conditions closely. Two performance tests (Hamburg wheel tracking test and Ideal-CT) were conducted after the short-term and long-term aging simulations. To further analyze the differences, the aged binder in the mixtures was extracted and subjected to rheological and chemical tests, including Multiple Stress Creep Recovery (MSCR), Linear Amplitude Sweep (LAS), Gel Permeation Chromatography (GPC), and Fourier Transform Infrared Spectroscopy (FTIR). Based on the performance test results, PMA-I outperformed PMA-II, contrary to expectations based on the binder performance grading system. The results of the chemical and rheological tests shown to support the mixture performance results demonstrating the superiority of PMA-I. The poor performance of this PMA-II can be attributed to its polymer modification process, which might have experienced premature aging during the modification process.

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