| 研究生: |
謝易成 Sie, Yi-Cheng |
|---|---|
| 論文名稱: |
通電對鈦-6鋁-4釩合金微拉伸性質與微結構影響之研究 Effects of Electric Current Stressing on Micro-tensile Properties and Microstructure of Ti-6Al-4V Alloy |
| 指導教授: |
林光隆
Lin, Kwang-Lung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2023 |
| 畢業學年度: | 111 |
| 語文別: | 中文 |
| 論文頁數: | 246 |
| 中文關鍵詞: | Ti-6Al-4V 、電遷移 、微拉伸 、相轉變 、應變強化 |
| 外文關鍵詞: | Ti-6Al-4V, Electromigration, Micro-tensile property, Phase transformation, Strain hardening |
| 相關次數: | 點閱:143 下載:0 |
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本研究藉由微拉伸試驗和微結構分析探討冷加工Ti6Al4V合金以高電流密度直流通電對性質變化之機制探討,將狗骨頭形狀微拉伸試片結合風扇散熱進行1×104 - 1.4×104A/cm2電流密度通電1~30分鐘以及進行1.2×104、1.4×104A/cm2電流密度通電30分鐘的熱對照組,並量測微拉伸性質,後續進行微結構分析了解微拉伸性質變化機制。利用掃描式電子顯微鏡觀察破斷面,破斷機制皆屬延性破斷而未受微拉伸強度與伸長率影響。電子微探儀定量分析兩相固溶原子比例未受通電或熱對照組影響。X光繞射分析未觀察到析出物繞射峰,此外應變分析β相(200)結晶面於短時間通電造成應變,且增加電流密度導致微應變速率提升。X光繞射分析所得的差排密度變化趨勢為通電短時間內明顯下降,並於通電長時間維持穩定。電子背向散射繞射分析觀察拉伸方向的晶粒取向未有明顯變化,而通電導致α相轉變成β相,並且β相隨通電時間增加有晶粒成長,表示GOS分析隨通電時間增加生成的無應變β相晶粒應為相變化形成,並非再結晶現象。針對彈性模數、降伏強度、伸長率探討微拉伸性質的變化機制,彈性模數變化受相轉變機制影響;降伏強度變化於1.2×104A/cm2電流密度主要受應變硬化機制主導,1.4×104A/cm2電流密度則受應變硬化和相轉變機制共同主導;伸長率變化於通電前期(1.2×104A/cm2 1~5分鐘、1.4×104A/cm2 1~10分鐘)以應變硬化和相轉變機制共同主導,但目前已知機制對通電長時間的伸長率變化未能解釋,需進一步實驗探討。
This study investigated the mechanism of micro-tensile properties and microstructure variation of cold-worked Ti6Al4V alloy under electromigration at high current densities. The dog bone-shaped specimens were subjected to 1×104-1.4×104A/cm2 direct current stressing for 1-30minutes. Fan cooling incorporated for removing excess joule heat during the current stressing. The SEM analysis revealed that all specimens exhibit ductile fracture mechanism despite the variations in micro-tensile properties. XRD analysis showed that short-time current stressing induced strain in β phase (200). The strain variation rate increased at larger current densities. Dislocation density calculated by XRD initially decreased after current stressing while stabilized at a certain value in 30-minute stressing. EBSD analysis did not show changes in grain orientation along the tensile direction, but showed phase transformation and grain growth of β phase. The study investigated the effect of current stressing on elastic modulus, 0.2% yield strength, and elongation. Elastic modulus variation was likely attributed to phase transformation, while 0.2% yield strength was influenced by strain hardening and phase transformation at different current densities. The mechanism of elongation variation under long-time current stressing requires further investigation, although the behavior at short-time current stressing can be explained by strain hardening and phase transformation.
[1] E. Ezugwu and Z. Wang, "Titanium alloys and their machinability—a review," Journal of Materials Processing Technology, vol. 68, no. 3, pp. 262-274, 1997.
[2] M. J. Donachie, Titanium: a technical guide. ASM international, pp. 31, 2000.
[3] R. Pederson, "Microstructure and phase transformation of Ti-6Al-4V," Licentiate thesis, Luleå tekniska universitet, pp.4-15, 2002.
[4] J. Elmer, T. Palmer, S. Babu, and E. Specht, "In situ observations of lattice expansion and transformation rates of α and β phases in Ti–6Al–4V," Materials Science and Engineering: A, vol. 391, no. 1-2, pp. 104-113, 2005.
[5] P. S. Ho and T. Kwok, "Electromigration in metals," Reports on Progress in Physics, vol. 52, no. 3, pp. 301, 1989.
[6] C. Liu, C. Chen, and K.-N. Tu, "Electromigration in Sn–Pb solder strips as a function of alloy composition," Journal of Applied Physics, vol. 88, no. 10, pp. 5703-5709, 2000.
[7] A. Roy, "Dynamics of electromigration induced void in submicron Cu interconnects," in 2011 International Conference on Communication and Industrial Application, Kolkata, West Bengal, India, December 26-28, 2011, 2011: IEEE, pp. 1-4.
[8] J. Lienig, "Electromigration and its impact on physical design in future technologies," in Proceedings of the 2013 ACM International symposium on Physical Design, Nevada, USA, March 24-27, 2013: Association for Computing Machinery, pp. 33-40.
[9] A. Scorzoni, B. Neri, C. Caprile, and F. Fantini, "Electromigration in thin-film interconnection lines: models, methods and results," Materials Science Reports, vol. 7, no. 4-5, pp. 143-220, 1991.
[10] R. Brouwer and R. Griessen, "Electromigration of hydrogen in alloys: Evidence of unscreened proton behavior," Physical Review Letters, vol. 62, no. 15, 1760, 1989.
[11] K.-N. Tu, Y. Liu, and M. Li, "Effect of Joule heating and current crowding on electromigration in mobile technology," Applied Physics Reviews, vol. 4, no. 1, 011101, 2017.
[12] C.-L. Liang and K.-L. Lin, "The microstructure and property variations of metals induced by electric current treatment: a review," Materials Characterization, vol. 145, pp. 545-555, 2018.
[13] H. Conrad, "Effects of electric current on solid state phase transformations in metals," Materials Science and Engineering: A, vol. 287, no. 2, pp. 227-237, 2000.
[14] K. Jeong, S.-W. Jin, S.-G. Kang, J.-W. Park, H.-J. Jeong, S.-T. Hong, S.-H. Cho, M.-J. Kim and H.-N. Han "Athermally enhanced recrystallization kinetics of ultra-low carbon steel via electric current treatment," Acta Materialia, vol. 232, 117925, 2022.
[15] P. Liang and K.-L. Lin, "Non-deformation recrystallization of metal with electric current stressing," Journal of Alloys and Compounds, vol. 722, pp. 690-697, 2017.
[16] Y.-H. Liao, C.-L. Liang, K.-L. Lin, and A. T. Wu, "High dislocation density of tin induced by electric current," AIP Advances, vol. 5, no. 12, 127210, 2015.
[17] A. T. Wu, A. Gusak, K.-N. Tu, and C. Kao, "Electromigration-induced grain rotation in anisotropic conducting beta tin," Applied Physics Letters, vol. 86, no. 24, 241902, 2005.
[18] H.-C. Huang, K.-L. Lin, and A. T. Wu, "Disruption of crystalline structure of Sn3. 5Ag induced by electric current," Journal of Applied Physics, vol. 119, no. 11, 115102, 2016.
[19] Z. S. Xu and Y. X. Chen, "Effect of electric current on the recrystallization behavior of cold worked α-Ti," Scripta Metallurgica, vol. 22, no. 2, pp. 187-190, 1988.
[20] W. Wu, Y. Song, Z. Wang, S. Ning, and L. Hua, "Solid phase transformation of Ti–6.6 Al–3.4 Mo alloy induced by electroshocking treatment," Journal of Materials Science, vol. 55, pp. 2245-2255, 2020.
[21] J. Huang, Z. Xu, Y. Deng, and L. Peng, "Electropulsing-induced α to β phase transformation of Ti–6Al–4V," Journal of Manufacturing Science and Engineering, vol. 141, no. 11, 111012, 2019.
[22] Z. Zhao, G. Wang, Y. Zhang, Y. Wang, and H. Hou, "Fast recrystallization and phase transformation in ECAP deformed Ti–6Al–4V alloy induced by pulsed electric current," Journal of Alloys and Compounds, vol. 786, pp. 733-741, 2019.
[23] Z. Xu, J. Huang, L. Peng, and X. Lai, "In situ observation of deformation behavior of Ti6Al4V subjected to electrically-assisted forming process," Procedia Manufacturing, vol. 50, pp. 647-651, 2020.
[24] X. Li, B. Ji, Q. Zhou, J. Chen, and P. Gao, "Influence of grain size on electrically assisted tensile behavior of Ti-6Al-4V alloy," Journal of Materials Engineering and Performance, vol. 25, pp. 4514-4520, 2016.
[25] N. Hansen, "Hall–Petch relation and boundary strengthening," Scripta Materialia, vol. 51, no. 8, pp. 801-806, 2004.
[26] H. Conrad, S. Feuerstein, and L. Rice, "Effects of grain size on the dislocation density and flow stress of niobium," Materials Science and Engineering, vol. 2, no. 3, pp. 157-168, 1967.
[27] F. J. Humphreys and M. Hatherly, Recrystallization and Related Annealing Phenomena. Elsevier, pp. 170, 2012.
[28] W. D. Callister Jr and D. G. Rethwisch, Callister's Materials Science and Engineering. John Wiley & Sons, pp. 166-168, 218, 2020.
[29] A. Jorge Jr, W. Regone, and O. Balancin, "Effect of competing hardening and softening mechanisms on the flow stress curve modeling of ultra-low carbon steel at high temperatures," Journal of Materials Processing Technology, vol. 142, no. 2, pp. 415-421, 2003.
[30] K. Huang and R. E. Logé, "A review of dynamic recrystallization phenomena in metallic materials," Materials & Design, vol. 111, pp. 548-574, 2016.
[31] B. Zhao, P. Huang, L. Zhang, S. Li, Z. Zhang, and Q. Yu, "Temperature effect on stacking fault energy and deformation mechanisms in titanium and titanium-aluminium alloy," Scientific Reports, vol. 10, no. 1, 3086, 2020.
[32] J. Krawczyk, T. Tokarski, A. Łukaszek-Sołek, R. Dąbrowski, T. Śleboda, and O. Lypchanskyi, "Dynamic recrystallization in titanium alloys," Key Engineering Materials, vol. 687, pp. 47-54, 2016.
[33] G. Dai, J. Niu, Y. Guo, Z. Sun, Z. Dan, H. Chang and L. Zhou "Microstructure evolution and grain refinement behavior during hot deformation of Fe micro-alloyed Ti-6Al-4V," Journal of Materials Research and Technology, vol. 15, pp. 1881-1895, 2021.
[34] F. Bridier, P. Villechaise, and J. Mendez, "Analysis of the different slip systems activated by tension in a α/β titanium alloy in relation with local crystallographic orientation," Acta Materialia, vol. 53, no. 3, pp. 555-567, 2005.
[35] L. S. Toth, S. Biswas, C. Gu, and B. Beausir, "Notes on representing grain size distributions obtained by electron backscatter diffraction," Materials Characterization, vol. 84, pp. 67-71, 2013.
[36] M. E. Fitzpatrick, A. T. Fry, P. Holdway, F. Kandil, J. Shackleton, and L. Suominen, "Determination of residual stresses by X-ray diffraction," National Physical Laboratory, Teddington, Middlesex, United Kingdom, pp.6-8, 2005.
[37] J. Ayers, "The measurement of threading dislocation densities in semiconductor crystals by X-ray diffraction," Journal of Crystal Growth, vol. 135, no. 1-2, pp. 71-77, 1994.
[38] C. Cai, B. Song, P. Xue, Q. Wei, J.-M. Wu, W. Li, Y. Shi "Effect of hot isostatic pressing procedure on performance of Ti6Al4V: surface qualities, microstructure and mechanical properties," Journal of Alloys and Compounds, vol. 686, pp. 55-63, 2016.
[39] E. Trofimov, R. Y. Lutfullin, and R. Kashaev, "Elastic properties of the titanium alloy Ti-6Al-4V," Письма о материалах, vol. 5, no. 1, pp. 67-69, 2015.
[40] A. K. Gain, L. Zhang, and S. Lim, "Tribological behavior of Ti–6Al–4V alloy: Subsurface structure, damage mechanism and mechanical properties," Wear, vol. 464, pp. 203551, 2021.
[41] J. Džugan, R. Procházka, and P. Konopík, "Micro-tensile test technique development and application to mechanical property determination," in Small Specimen Test Techniques: 6th Volume: ASTM international, pp.12-30, 2015.
[42] J. L. González-Velázquez, Fractography and Failure Analysis. Springer, pp.49-69, 2018.
[43] J. Epp, "X-ray diffraction (XRD) techniques for materials characterization," in Materials Characterization using Nondestructive Evaluation (NDE) Methods: Elsevier, pp. 81-124, 2016.
[44] J.-Y. Xia , L.-J. Chai, H. Wu, Y. Zhi, Y.-N. Gou, W.-J. Huang, N. Guo "EBSD study of microstructural and textural changes of hot-rolled Ti–6Al–4V sheet after annealing at 800 C," Acta Metallurgica Sinica (English Letters), vol. 31, pp. 1215-1223, 2018.
[45] X. Wang, M. Zhan, P.-F. Gao, P.-Y. Ma, K. Yang, Y.-D. Lei, Z.-X. Li "Deformation mode dependent mechanism and kinetics of dynamic recrystallization in hot working of titanium alloy," Materials Science and Engineering: A, vol. 772, pp. 138804, 2020.
[46] G. Welsch, R. Boyer, and E. Collings, Materials properties handbook: titanium alloys. ASM International, p. 516, 1993.
[47] M.-J. Kim, S. Yoon, S. Park, H.-J. Jeong, J.-W. Park, K. Kim, J. Jo, T. Heo, S.-T. Hong, S.-H. Cho "Elucidating the origin of electroplasticity in metallic materials," Applied Materials Today, vol. 21, 100874, 2020.
[48] B. L. Adams and J. Kacher, "EBSD-based microscopy: Resolution of dislocation density," Computers, Materials, & Continua, vol. 14, no. 3, pp. 185-196, 2010.
[49] J. S. Weaver, M. W. Priddy, D. L. McDowell, and S. R. Kalidindi, "On capturing the grain-scale elastic and plastic anisotropy of alpha-Ti with spherical nanoindentation and electron back-scattered diffraction," Acta Materialia, vol. 117, pp. 23-34, 2016.
[50] T. Inamura, H. Hosoda, K. Wakashima, and S. Miyazaki, "Anisotropy and temperature dependence of Young’s modulus in textured TiNbAl biomedical shape memory alloy," Materials Transactions, vol. 46, no. 7, pp. 1597-1603, 2005.
[51] Y. Tanaka, K. Hattori, and Y. Harada, "Micro-cantilever testing of microstructural effects on plastic behavior of Ti–6Al–4V alloy," Materials Science and Engineering: A, vol. 823, p. 141747, 2021.
[52] A. A. Deev, P. A. Kuznetcov, and S. Petrov, "Anisotropy of mechanical properties and its correlation with the structure of the stainless steel 316L produced by the SLM method," Physics Procedia, vol. 83, pp. 789-796, 2016.
[53] Y. Chong, T. Bhattacharjee, M.-H. Park, A. Shibata, and N. Tsuji, "Factors determining room temperature mechanical properties of bimodal microstructures in Ti-6Al-4V alloy," Materials Science and Engineering: A, vol. 730, pp. 217-222, 2018.
[54] M. Bin, Q.-h. Rao, and Y.-h. He, "Effect of crystal orientation on tensile mechanical properties of single-crystal tungsten nanowire," Transactions of Nonferrous Metals Society of China, vol. 24, no. 9, pp. 2904-2910, 2014.
[55] Y. W. Sui, A. H. Liu, B. S. Li, J. J. Guo, and W. B. Ju, "Relationship between microstructures and mechanical properties of Ti-6Al-4V alloy in centrifugal casting," Advanced Materials Research, vol. 295, pp. 496-499, 2011.
[56] A. Xiao, Z. Yan, C. Huang, Z. Yu, S. Wang, and X. Cui, "Reduction of springback of Ti6Al4V alloy by high-density and instantaneous pulsed current," Materials Science and Engineering: A, p. 145188, 2023.