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研究生: 謝易成
Sie, Yi-Cheng
論文名稱: 通電對鈦-6鋁-4釩合金微拉伸性質與微結構影響之研究
Effects of Electric Current Stressing on Micro-tensile Properties and Microstructure of Ti-6Al-4V Alloy
指導教授: 林光隆
Lin, Kwang-Lung
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 246
中文關鍵詞: Ti-6Al-4V 、電遷移 、微拉伸 、相轉變 、應變強化
外文關鍵詞: Ti-6Al-4V, Electromigration, Micro-tensile property, Phase transformation, Strain hardening
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  • 本研究藉由微拉伸試驗和微結構分析探討冷加工Ti6Al4V合金以高電流密度直流通電對性質變化之機制探討,將狗骨頭形狀微拉伸試片結合風扇散熱進行1×104 - 1.4×104A/cm2電流密度通電1~30分鐘以及進行1.2×104、1.4×104A/cm2電流密度通電30分鐘的熱對照組,並量測微拉伸性質,後續進行微結構分析了解微拉伸性質變化機制。利用掃描式電子顯微鏡觀察破斷面,破斷機制皆屬延性破斷而未受微拉伸強度與伸長率影響。電子微探儀定量分析兩相固溶原子比例未受通電或熱對照組影響。X光繞射分析未觀察到析出物繞射峰,此外應變分析β相(200)結晶面於短時間通電造成應變,且增加電流密度導致微應變速率提升。X光繞射分析所得的差排密度變化趨勢為通電短時間內明顯下降,並於通電長時間維持穩定。電子背向散射繞射分析觀察拉伸方向的晶粒取向未有明顯變化,而通電導致α相轉變成β相,並且β相隨通電時間增加有晶粒成長,表示GOS分析隨通電時間增加生成的無應變β相晶粒應為相變化形成,並非再結晶現象。針對彈性模數、降伏強度、伸長率探討微拉伸性質的變化機制,彈性模數變化受相轉變機制影響;降伏強度變化於1.2×104A/cm2電流密度主要受應變硬化機制主導,1.4×104A/cm2電流密度則受應變硬化和相轉變機制共同主導;伸長率變化於通電前期(1.2×104A/cm2 1~5分鐘、1.4×104A/cm2 1~10分鐘)以應變硬化和相轉變機制共同主導,但目前已知機制對通電長時間的伸長率變化未能解釋,需進一步實驗探討。

    This study investigated the mechanism of micro-tensile properties and microstructure variation of cold-worked Ti6Al4V alloy under electromigration at high current densities. The dog bone-shaped specimens were subjected to 1×104-1.4×104A/cm2 direct current stressing for 1-30minutes. Fan cooling incorporated for removing excess joule heat during the current stressing. The SEM analysis revealed that all specimens exhibit ductile fracture mechanism despite the variations in micro-tensile properties. XRD analysis showed that short-time current stressing induced strain in β phase (200). The strain variation rate increased at larger current densities. Dislocation density calculated by XRD initially decreased after current stressing while stabilized at a certain value in 30-minute stressing. EBSD analysis did not show changes in grain orientation along the tensile direction, but showed phase transformation and grain growth of β phase. The study investigated the effect of current stressing on elastic modulus, 0.2% yield strength, and elongation. Elastic modulus variation was likely attributed to phase transformation, while 0.2% yield strength was influenced by strain hardening and phase transformation at different current densities. The mechanism of elongation variation under long-time current stressing requires further investigation, although the behavior at short-time current stressing can be explained by strain hardening and phase transformation.

    中文摘要 I Extended Abstract III 誌謝 LIII 目錄 LIV 表目錄 LVIII 圖目錄 LIX 第壹章 簡介 1 1.1 鈦金屬及其合金簡介 1 1.2 電遷移 5 1.2.1 電遷移理論 5 1.2.2 焦耳熱效應 11 1.3 通電對微結構之影響 12 1.3.1 通電導致再結晶現象 12 1.3.2 通電導致晶粒旋轉、晶格扭曲等現象 17 1.3.3 通電對鈦合金微結構之影響 21 1.4 通電對機械性質之影響 30 1.5 再結晶現象簡介 42 1.5.1 退火理論 42 1.5.2 動態回復與動態再結晶 47 1.6 研究目的 51 第貳章 實驗方法與步驟 52 2.1 實驗構想 52 2.2 冷加工Ti6Al4V試片 54 2.3 通電實驗 56 2.4 拉伸性質量測 63 2.5 電子背向散射繞射分析 68 2.6 X光繞射分析 69 2.7 掃描式電子顯微鏡分析 70 2.8 電子微探儀分析 70 第參章 實驗結果與討論 73 3.1 通電前試片觀察 73 3.1.1 通電前試片微拉伸性質 73 3.1.2 通電前試片破斷面分析 76 3.1.3 通電前試片相組成與相比例 79 3.1.4 通電前試片晶粒尺寸及晶粒取向 86 3.2 通電溫度量測 100 3.3 通電後試片觀察 102 3.3.1 通電對材料微拉伸性質影響 102 3.3.2 通電對材料破斷機制影響 116 3.3.3 通電對相微應變、差排密度的影響 125 3.3.4 通電對相比例與組成的影響 139 3.3.5 通電對晶粒尺寸的影響 156 3.3.6 通電對晶粒取向的影響 160 3.3.7 通電對取向差角的影響 175 3.3.8 通電後GOS分析 190 3.3.9 通電後KAM分析 199 3.4 微拉伸性質變化機制探討 207 3.4.1 彈性模數變化機制 207 3.4.2 微拉伸強度變化機制 210 3.4.2.1 通電影響微拉伸強度之機制探討 210 3.4.2.2 熱對照組影響微拉伸強度之機制探討 220 3.4.3 伸長率變化機制 227 3.4.3.1 通電影響伸長率之機制探討 227 3.4.3.2 熱對照組影響伸長率之機制探討 234 第肆章 結論 240 參考文獻 242

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