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研究生: 吳俊毅
Wu, Jun-Yi
論文名稱: 以三階段鈣系化學過氧沉澱法除去合成廢水中的硼並應用於實廠廢水
Removal of boron from synthetic wastewater by three-stage calcium-based chemical oxo-precipitation (COP) and application in real wastewater treatment
指導教授: 黃耀輝
Huang, Yao-Hui
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2022
畢業學年度: 110
語文別: 中文
論文頁數: 134
中文關鍵詞: 化學過氧沉澱過硼酸雙氧水三階段處理
外文關鍵詞: Chemical oxo-precipitation, Perborate, Hydrogen peroxide, Calcium, Three-stage
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  • 第一章 緒論 1 1-1 研究緣起 1 1-2 研究目的與內容 2 第二章 文獻回顧 3 2-1 自然界中的硼 3 2-1-1 硼的分布 5 2-1-2 硼的循環 6 2-2 硼的應用與污染來源 8 2-3 硼的必要性與危害 11 2-3-1 對動植物的必要性與危害 11 2-3-2 水質標準 15 2-4 除去水中硼的方法 17 2-4-1 吸附法 17 2-4-2 薄膜分離法 21 2-4-3 化學沉澱法及混凝 23 2-4-4 電混凝法 25 2-4-5 溶劑萃取法 28 2-5 化學過氧沉澱法 30 2-5-1 硼酸/雙氧水/過硼酸化學 30 2-5-2 化學過氧沉澱法研究成果 33 2-6 活性係數之估計方法 43 第三章 實驗設備、材料與方法 45 3-1 研究架構與流程 45 3-2 符號及公式定義 47 3-3 實驗材料、設備及方法 49 3-3-1 實驗材料及其用途 49 3-3-2 實驗設備 50 3-3-3 實驗步驟 52 3-3-3-1 三階段鈣系化學過氧沉澱技術 52 3-3-3-2 過硼酸鈣溶解/沉澱之平衡實驗 53 3-4 檢測儀器與分析方法 54 3-4-1 感應耦合電漿原子發射光譜儀(Inductively Coupled Plasma-Optical Emission Spectrometer, ICP-OES) 54 3-4-2 總溶解性過氧物種濃度測定方法 58 3-4-3 離子層析儀(Ion Chromatograph, IC) 59 3-4-4 X射線繞射儀(X-ray Diffractometer, XRD) 60 3-4-5 傅立葉轉換式紅外線光譜儀(Fourier-Transform Infrared Spectrometer, FTIR) 62 3-4-6 化學分析電子能譜儀(Electron Spectroscopy for Chemical Analysis, ESCA) 63 3-4-7 能量散佈光譜儀(Energy Dispersive Spectrometer, EDS) 64 第四章 結果與討論 66 4-1 三階段鈣系化學過氧沉澱技術加藥條件最佳化 66 4-1-1 階段反應時間(timer)之變因探討 66 4-1-2 沉澱劑加藥量莫耳比之變因探討 70 4-1-2-1 第一階段反應莫耳比對三階段鈣系COP的影響 70 4-1-2-2 第二階段反應莫耳比對三階段鈣系COP的影響 73 4-1-2-3 第三階段反應莫耳比對三階段鈣系COP的影響 76 4-1-2-4 三階段反應之原因 79 4-1-3 反應pH值(pHr)之變因探討 81 4-1-4 雙氧水添加量之變因探討 88 4-2 過硼酸鈣之組成鑑定 93 4-3 過硼酸鈣溶解度之預測 101 4-4 實廠案例測試 110 4-4-1 實廠廢水性質與成分分析 110 4-4-2 測試結果與討論 112 第五章 結論與建議 117 5-1 結論 117 5-2 建議 119 參考文獻 122 附錄A. 過硼酸分布的二元四次方程式 133

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