簡易檢索 / 詳目顯示

研究生: 林欣萩
Lin, Sin-chiou
論文名稱: 臺灣地區戴奧辛排放源對牧草中戴奧辛含量之影響及貢獻量評估
Effect and contribution assessment of PCDD/Fs in forage from PCDD/Fs emission sources in Taiwan
指導教授: 李俊璋
Lee, Ching-Chang
學位類別: 碩士
Master
系所名稱: 醫學院 - 環境醫學研究所
Department of Environmental and Occupational Health
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 95
中文關鍵詞: 複合工業污染源模式牧草戴奧辛多介質模式地理資訊系統
外文關鍵詞: forage, atmospheric dispersion model, PCDD/Fs, Multimedia model, Geographic Information System
相關次數: 點閱:167下載:8
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 過去研究顯示,食用多氯戴奧辛/呋喃(Polychlorinated dibenzo-p-dioxin/furans, PCDD/Fs)含量高之污染牧草為部分市售牛羊肉品及乳品中PCDD/Fs含量偏高的主因。因此,建立牧草安全生產機制有其必要性且刻不容緩。
    由於臺灣之牧草生產區域佔地零碎且分布極廣,若實地逐一量測各生產區域牧草中PCDD/Fs之濃度將耗費龐大的時間與經濟成本支出且緩不濟急,因此本研究擬結合大氣擴散模擬模式及多介質模式之應用,透過修正模式參數後使其可有效且快速評估牧草中PCDD/Fs之含量。臺灣地區牧草種植以狼尾草、盤固拉草及青割玉米為最大宗,因此本研究亦分區探討不同牧草種類PCDD/Fs之含量情形。
    首先選擇臺灣地區PCDD/Fs排放量較高且同時為酪農戶集中之A、B縣市為研究區,並以相對工業污染源較少之C、D縣市為對照組。以環保署「戴奧辛排放源資料庫及環境介質查詢系統」整理研究區內PCDD/Fs排放源排放資料,及2003-2005年氣象資料及相關環境參數,利用空氣擴散模式(ISC-ST3 Model)進行牧草生產區域空氣中PCDD/Fs濃度及沈降量模擬,再將模擬結果以多介質模式(Multimedia Model)推估研究區內不同牧草中PCDD/Fs之濃度,最後以此推估結果與歐盟植物性飼料中PCDD/Fs管制規範標準進行比較後,透過地理資訊系統(GIS)於空間上加以標示,進一步劃定牧草安全生產區域,提供施政者與管理者建立牧草安全生產機制之依據。
    本研究利用先前研究實測牧草中PCDD/Fs濃度值與多介質模式模擬值相比較後,結果顯示兩者相差比例在可接受的範圍,進一步肯定本研究中利用多介質模式推估各牧草中PCDD/Fs濃度值之可行性。利用ISC-ST3模擬大氣中PCDD/Fs濃度及總沈降量結果顯示,A縣市模擬值最高而D縣市模擬值最低;透過多介質模式推估各牧草中PCDD/Fs平均濃度值之結果則發現冬季各縣市牧草PCDD/Fs濃度值皆最低。此外,A縣市各牧草中PCDD/Fs模擬平均濃度值在春季、夏季與秋季皆超過歐盟植物性飼料規範標準0.75(ng WHO98-TEQPCDD/F/kg, 12% H2O),其餘縣市之牧草則符合歐盟管制規範標準。
    本研究中所推估之PCDD/Fs排放量僅包含環保署列管之固定排放源,未納入未列管的固定排放源、汽機車等移動污染源、露天燃燒、土壤揚塵等。建議完善國內未受控制之排放源資料庫之建置,以使日後在進行相關PCDD/Fs之風險暴露評估上能更為周全,及進一步蒐集健全之PCDD/Fs排放資料,建立更加趨近實測情況之模擬模式。

    Literatures showed that the higher PCDD/Fs levels in beef, mutton and milk were related to the higher PCDD/Fs levels in forages. Therefore, the establishment of clean and safe measures for forage production is too impatient to wait.
    Because of the livestock farm not only wide but scrappy, it will highly cost on manpower and economical recources by field survey in each place. This study is aimed to simulate the PCDD/Fs levels of forage from the pastures nearby the PCDD/Fs emission sources and to assess the contribution of those sources, and then establish the clean and safe zones for forage production. Three types of forage plant which are most commom used and planted on the livestock farm, Napiergrass, Pangolgrass and Silage Corn are selected to simulate PCDD/Fs levels.
    A and B County were chosen to be conducted in this study, because their high emissions of PCDD/Fs, high density of dairy farm and high production of forage. C county and D County were chosen as control area, because they also have wide pasture and less contaminated by PCDD/Fs. The basic information of pastures, dairy farm, PCDD/Fs emission sources and meteorological data were collected and the data were applied to simulate ambient levels and deposition of PCDD/Fs by atmospheric dispersion model (ISCST3). Then, the Multimedia model was applied to estimate the PCDD/Fs concentrations of environmental media and forage. The results were compared with the maximum limits for PCDD/Fs in feeding stuffs of EU. Finally, the spatial distribution of clean and safe pasture area were mapped by using the geographic information system (GIS).
    After comparing the simulated PCDD/Fs level to measured PCDD/Fs level of forage plants, the results show the range of their difference was acceptable. As above we could conclude that using multimedia model to simulate the PCDD/Fs level of forages in this study is practicable. The results of ambient PCDD/Fs level and total deposition by using ISC-ST3 atmospheric dispersion model reveal that A County was higher than others and D County was lowest. After using multimedia model to simulate the PCDD/Fs level of forages, we found that all counties have the lowest PCDD/Fs level of forage in winter. Besides, the simulated PCDD/Fs level of three kinds of forages in A County were higher than EU maximum limits (0.75 ng WHO98-TEQPCDD/F/kg, 12% H2O).
    We only included the PCDD/Fs emission data of the emission sources investigated by Taiwan EPA in this study, and the emission sources which not investigated by Taiwan EPA and some moving emission sources such as motorcycles, burning outdoors and flying dust from soil were excluded.

    第一章 緒論 1 1-1 研究緣起 1 1-2 研究目的 2 1-3 研究意義 2 第二章 文獻回顧 3 2-1 戴奧辛介紹 3 2-1-1 戴奧辛之物理化學特性 3 2-1-2 戴奧辛之發生源與環境流布 6 2-1-3 戴奧辛在大氣、土壤與植物中之傳輸作用 8 2-1-4 戴奧辛之毒理性質及其健康危害 10 2-1-5 飲食中受戴奧辛污染之重大事件 13 2-1-6 不同植物種類中PCDD/Fs濃度之相關研究 14 2-2 複合工業污染源模式 15 2-2-1 複合工業污染源模式之內涵及理論基礎 16 2-2-2 複合工業污染源模式各參數之選擇與應用 19 2-2-3 複合工業污染源模式之法規規定 21 2-3 多介質模式 23 2-4 地理資訊系統 24 第三章 研究材料與方法 27 3-1研究架構 27 3-2研究對象選取 29 3-3 戴奧辛排放量計算 30 3-4 ISC-ST3 高斯擴散模擬模式 33 3-4-1 模式參數設定與污染源資料輸入 33 3-4-2 氣象資料輸入 36 3-5 多介質模式評估 41 第四章 結果與討論 44 4-1 戴奧辛排放量計算結果 44 4-2 模式可利用性探討 50 4-2-1 ISC-ST3高斯擴散模擬模式 50 4-2-2 多介質模式 51 4-3 ISC-ST3高斯擴散模擬模式模擬結果 52 4-3-1 A縣市空氣中PCDD/Fs毒性當量濃度及沈降量模擬結果 52 4-3-2 B縣市空氣中PCDD/Fs毒性當量濃度及沈降量模擬結果 59 4-3-3 C縣市空氣中PCDD/Fs毒性當量濃度及沈降量模擬結果 65 4-3-4 D縣市空氣中PCDD/Fs毒性當量濃度及沈降量模擬結果 71 4-4 牧草中PCDD/FS含量推估結果 77 第五章 結論與建議 85 5-1 結論 85 5-2 建議 86 參考文獻 87

    Ahlborg U.G., Brouwer A., Fingerhut M.A., Jacobson J.L., Jacobson S.W., Kennedy S.W., Kettrup A.A.F., Koeman J.H., Poiger H., Rappe C., Safe S.H., Seegal R.F., Tuomisto J., Vandenber G.M.. 1992 Impact of polychlorinated dibenzo-p-dioxins, dibenzofurans, and biphenyls on human and environmental-health, with special emphasis on application of the toxic equivalency factor concept. Eur. J. Pharmacol. 228:179-199.
    Alvares A.P., Fischbein A., Anderson K.E., Kappas A. 1997 Alterastionin drug metabolism in workers exposed to polychlorinated biphenyls. Clin Pharm Ther 22: 140.
    A. Svenson, L.O. Kjeller, C. Rappe. 1980 Enzyme-mediated formation of 2,3,7,8-tetrasubstituted chlorinated dibenzodioxins and dibenzofurans. Environ. Sci. Technol 23:900-902.
    Atkinson DG, Bailey DT., Irwin JS, Touma JS. 1997. Improvements to the EPA industrial source complex dispersion model. Journal of Applied Meteorology. 36(8),1088-1095.
    Basham JP, Whitwell I. Dispersion modeling of dioxin releases from the waste incinerator at Avonmouth, Bristol, UK. Atmospheric Environment. 1999, 33(20),3405-3416.
    Barbieri S., Pirovano C., Scarlato G., Tarchini P., Zappa A., Maranzana M. 1988 Long-term effects of 2,3,7,8-tetrachlorodibenzo-p-dioxin on the peripheral nervous system. Clinical and neurophysiological controlled study on subjects with chloracne form the Seveso area. Neuroepidemiology 7: 29-37.
    Barinaga M., 1989 Agent Orange: Congress impatient for answers. Science 245: 249-250.
    Barry C., Webster T., 1994 Overview : the dioxin debate. In : Schecter A. Dioxins & Health. Plenum Press New York : 1-50.
    Bertazzi P.A., Zocchetti C., Pesatori A.C., Guercilena S., Senarico M., Rodice L., 1989 Ten-year mortality study of the population involved in the Seveso incident in 1976. Am J Epidemiol 129: 1187-1200.
    Bremmer H., Sein A., 1991 Sources of dioxins in the Netherlands. Presented at Dioxin ’91, Research Triangle Park, NC.
    Chen Lu-Yen, Jeng Fu-Tien, Chang Ming-Whei, Yen Shui-Hway. 2000 Rationalization of an odor monitoring system: a case study of Lin-Yuan Petrochemical Park. Environmental Science & Technology.,34(7), 1166-1173.
    Connett P., Webster T., 1987 An estimation of the relative human exposure to 2,3,7,8-TCDD emissions via inhalation and ingestion of cow’s milk. Chemosphere 16: 2079-2084.
    Cooper CD, Godlewski VJ Jr, Hanson R, Koletzke M, Webster N. Odor 2001 Investigation and Control at a WWTP in Orange County, Florida. Environmental Progress.. 20(3) 133-143.
    Cryer SA, van Wesenbeeck U. 2001 Predicted 1,3-Dichloropropene Air Concentration Resulting from Tree and Vine Applications in Califormia. Journal of Environmental Quality. 30(6), 1887-1895.
    Czuczwa J., Hites R., 1986 Airborne dioxins and dibenzofurans: Sources and fates. Environ. Sci Technol 20: 195-200.
    Donna B. S., and P. O. James, 1996. Sensitivity of Industrial Source Complex Model to Input Deposition Paramemeters. J. Appl. Meteor, 36:1096-1106.
    Eriksson M., Hardell L., Adam H., 1990 Exposure to dioxins as a risk factor for soft tissue sarcoma: A population-based case-control study. J Nat Cancer Inst 82: 486-490.
    EPA, User’s Guide for the Industrial Source Coplex (ISC3) Dispersion Models (EPA-454/B-95-003a),1995. Environmental Portection Agency, North Carolina 27711.
    Facchetti S., Balasso A., Fichtner C., Frare G., Leoni A., Mauri C., Vasconi M., 1986 Studies on the absorption of TCDD by some plants. Chemosphere 15:1387-1388.
    Fiedler H., Hutzinger O., Timms C., 1990 Dioxins: Sources of environmental load and human exposure. Toxicol Environ Chem 29:157-234.
    Fingerhut M.A., Halperin W.E., Honchar P.A., Smith A.B., Groth D.H., Russel W.O., 1984 An evaluation of reports of dioxin exposure and soft tissue sarcoma pathology among chemical workers in the United States. Scand J Work Environ Health 10: 299-303.
    Fishbein L., 1987 Health-risk estimates for 2,3,7,8-tetrachlorodibenzo -p-dioxin : an overview. Toxicol lnd Health 3 : 91-134.
    Fries G.H., 1995 A review of the significance of animal food products as potential pathways of human exposure to dioxins. Journal of Animal Science 73:1639-1650.
    Gochfeld M., Gallo M., Kahn P., 1988 Dioxin exposure and health. N Eng J Med 85 : 907-912.
    Hagenmaier H., Dawidowsky N., Weberruss U., et al 1990 Emission of polyhalogenated dibenzodioxins and dibenzofurans from combustion-engines, Presented at Dioxin ’90, Bayreuth, Organohalogen Compounds, 2: 329-334.
    Kakareka S., Kukharchyk T., 2002 Expert Estimates of PCDD/F and PCB Emissions for Some European Countries. MSC-E Technical Note, June 2002.
    Hardell L., Eriksson M., Lenner P., Lundgren E., 1981 Malignant Lymphoma and Phenoxy Acids: A Case Control Study. Br J Cancer 43: 169-176.
    Hardell L., Ericksson M., 1988 The Association between Soft-tissue Sarcomas and Exposure to Phenoxyacetic Acids: A new case-control study. Cancer 62: 652.
    Harrad S., Jones K., 1992 A source inventory and budget for chlorinated dioxins and furans in the United Kingdom environment. Sci Total Environ 126: 89-107.
    Hanna, S. R., J. S. Chang and D. G. Strimaitis, 1990 “Uncertainty in Source Emission Rate Estimates Using Dispersion Models”, Atmosphere Environment, Vol.24A, No.12, pp2971-2980.
    H. Fiedler 1993 Formation and sources of PCDD/PCDF. Organohalogen comp 11:221-228.
    Hippelein M., Kaupp H., Dörr G., McLachlan M., Hutzinger O., 1996 Baseline contamination for a new resource recovery facility in Germany partⅡ:Atmosphere concentrations of PCDD/F. Chemosphere 32:1605-1616.
    H.J. Bremmer, L.M. Troost, G. Kuipers, J. de Konning, A.A. Sein. 1992 Rapport 770501003, RIVM Bilthoven, The Netherlands.
    Humphrey H.E., 1988 Chemical contaminants in the Great Lakes: the human health aspect. In : Evans M eds: Toxic contaminants and ecosystem health: a Great Lake focus. New York: Wiley.
    Hülster A., Marschner H., 1993 Transfer of PCDD/PCDF from contaminated soils to food and fodder crop plants. Chemosphere 27:439-446.
    Hülster A., Müller J.F., Marschner H., 1994 Soil plant transfer of polychlorinated dibenzo-p-dioxins and dibenzofurans to vegetables of the cucumber family cucurbitaceae. Environ. Sci. Technol. 28:1110-1115.
    Kuwahara M., Uegaki R., Seike N., 2002 Possible Pathways of Dioxin Accumulation to the Above-ground Portions of Rice Plants Grown in Contaminated Soils. Organohalogen Compounds 58:57-60.
    Kew, G. A., Schaum, J. L., White, P., Evans, T. T., 1989 Review of plant uptake of 2,3,7,8-TCDD from soil and potential influences of bioavailability. Chemosphere 18:1313-1318.
    Koester C., Hites R., 1992 Photodegradation of polychlorinated dioxins and dibenzofurans adsorbed to fly ash. Environ Sci Technol 26(3):503-507.
    L.G. Oberg, R. Anderson, C. Rappe. 1992 De novo formation of hepta-and octachlorodibenzo-p-dioxins from pentachlorophenol in municipal sewage sludge. Organohalogen Comp 9: 351-354.
    Liem A.K.D. 1999 Dioxins and dioxin-like PCBs in food-stuffs. Levels and trends. Organohalogen Compd 44: 1-4.
    L.O. Kjeler, C. Rappe. 1995 Time trends in levels, patterns, and profiles for polychlorinated dibenzo-p-dioxins, dibenzofurans, and biphenyls in a sediments core from the Baltic poper. Environ. Sci. Technol 29:346-355.
    Lorber M., Pinsky P., Gehring P., Braverman C., Winters D., Sovocool W., 1998 Relationships between dioxins in soil, air, ash, and emissions form a municipal solid waste incinerator emitting large amounts of dioxins. Chemosphere 37:2173-2197.
    Ma H-W, Lai Y-L, Chan C-C. 2002 Transfer of dioxin risk between nine major municipal waste incinerators in Taiwan. Environment International.,28(1-2), 103-110.
    Malisch R., 1998 Update of PCDD/PCDF-intake from food in Germany. Chemosphere 37: 1687-98.
    Manz A., Berger J., Dwyer J.H., et al. 1991 Cancer Mortality Among Workers in Chemical Plant Contaminated with Dioxin. Lancet 338: 959-964.
    Marklund S., Andersson R., Tysklind M., et al. 1990 Emissions of PCDDs and PCDFs in gasoline and diesel fueled cars. Chemosphere 20: 553-561.
    Mastroiacovo P., Spagnolo A., Marni E., Meazza L., Bertollini R., Segni G., 1988 Birth defects in the Seveso area (Italy) after TCDD contamination. JAMA 259: 1668-1672.
    Manju N, Balakrishnan R, Mani N. 2002 Assimilative capacity and pollutant dispersion studies for the industrial zone of Manali. Atmospheric Environment., 36(21),3461-3471.
    May G., 1982 Chloracne from the accidental production of tetrachlorobenzodioxin. Br J Ind Med 39: 128-135.
    McConnell E., Huff J., Hejtmancik M., Peters A., Persing R., 1991 Toxicology and carcinogenesis studies of two grades of pentachlorophenol in B6C3F1 mice. Fundam Appl Toxicol 17: 519-532.
    McLachlan M., Hutzinger O., 1990 Accumulation of organochlorine compounds in agricultural food chains, Presented at Dioxin’90, Bayreuth, Organohalogen Compounds 1: 479-484.
    McLachlan M.S., 1997 A simple model to predict the accumulation of PCDD/Fs in an agricultural food chain. Chemosphere 34:1263-1276.
    Moses M., Prioleau P.G., 1985 Cutaneous histologic findings in chemical workers with and without chloracne with past exposure to 2,3,7,8-tetrachlorodibenzo-p-dioxin. J Am Acad Dermatol 12: 497-506.
    Mukerjee D., 1998 Health Impact of polychlorinated dibenzo-p-dioxins: a critical review. Journal of the Air Waste Management Association 48:157-165.
    Müller J.F., Hülster A., Päpke O., Ball M., Marschner H., 1993 Transfer pathways of PCDD/PCDF to fruits. Chemosphere 27:195-201.
    Patterson D.G., Fingerhut M.A., Roberts D.R., et al. 1989 Levels of Polychlorinated Dibenzo-p-dioxins (PCDD's) and Dibenzofurans (PCDF's) in Workers Exposed to 2,3,7,8-Tetrachlorodibenzo-p-Dioxin. Am J Ind Med 16: 135-146.
    Rappe C., 1992 Sources of PCDDs and PCDFs. Introduction: Reactions, levels, patterns, profiles and trends. Chemosphere 25:41-44.
    Rejinders P., Brasseur S., 1992 Xenobiotic induced hormonal and associated develop mental disorder in marine organisms and related effects in humans :An overview. In :Colborn T, Clement C, eds. Chemically-Induced Alterations in Sexual and Functional Development :The Wildlife/Human Connection, Princeton Scientific Publishing Co., Princeton NJ 159-174.
    Riss A., Scheidl K., 1990 Statutory and research action in Austria, Presented at Dioxin ’90, Bayreuth, Organohalogen Compounds 4: 51-56.
    Rordorf B.F., 1989 Prediction of vapor pressures, boiling points and enthalpies of fusion for twenty-nine halogenated dibenzo-p-dioxins and fifty-five dibenzofurans by vapor pressure correlation method. Chemosphere 18:783-788.
    Schartz P., Jacobson S., Fein G., et al. 1983 Lake Michigan fish consumption as a source of polychlorinated biphenyl in human cord serum,maternal serum and milk. Am J Public Health 73: 293-296.
    Schuhmacher M., Domingo J.L., Liobet J.M., Muller L., Jager J., 1997a Levels of PCDD/Fs in grasses and weeds collected near a municipal solid waste incinerator. Sci. Total. Environ 201: 53-62.
    Schuhmacher M., Domingo J.L., Liobet J.M., Suuderhauf W., Muller L., Jager J., 1998c Baseline levels of PCDD/Fs in the vegetation samples collected in the vicinity of a new hazardous waste incinerator in Catalonia, Spain. Chemosphere 36: 2581-2591.
    Schuhmacher M., Granero S., Rivera J., Muller L., Llobet J.M., Domingo J.L., 2000 Atmospheric deposition of PCDD/Fs near an old municipal solid waste incinerator: levels in soil and vegetation. Chemosphere 40: 593-600.
    Shatalov V., Malanicher A., Vulykh N., Berg T., ManØ S., 2001 Assessment of POP Transport and Accumulation in the Environment EMEP Report 7/2002.
    Shiu W.Y., Doucette W., Gobas F.A.P.C., 1988 physical-chemical properties of chlorinated dibenzo-p-dioxins. Environ. Sci. Technol. 22:651-658.
    Sivacoumar R, Bhanarkar AD, Goyal SK, Gadkari SK, Aggarwal AL. Air pollution modeling for an industrial complex and model performance evaluation. Environmental Pollution. 2001, 111(3), 471-477.
    Smith kilian E.C., Jones kerin C., 2000 Particles and vegetation: implications for the transfer of particle-bound organic contaminants to vegetation. Sci. Total. Environ. 246:207-236.
    Trapp S., Matthies M., 1997 Modeling volatilization of PCDD/F from soil and uptakeinto vegetation. Environ. Sci. Technol. 31:71-74.
    USEPA, 1994 Health assessment document for Tetrachlorodibenzo- p-dioxin (TCDD) and related compounds. Vol.Ⅲ,P5-5.
    USEPA. 2000 Exposure and Human Health Reassessment of 2,3,7,8- Tetrachlorodibenzo -p-Dioxin (TCDD) and Related Compounds. EPA/600/P-00/001Ab,March.
    Wagrowski D.M., Hites R.A., 1997 Polycyclic aromatic hydrocarbon accumulation in urban, suburban, and rural vegetation. Environ. Sci. Technol. 31:279-282.
    Watanabe S., Kitamura K., Nagahashi M., 1999 Effect of dioxins on human health: a review. Journal of Epidemiology. 9(1):1-13.
    Webster T., Connett P., 1990 The use of bioconcentration factors in estimating the 2,3,7,8-TCDD content of cow’s milk. Chemosphere 20: 779-786.
    Welsch-Pausch K., McLachlan M.S., Umlauf G., 1995 Determination of the principal pathways of polychlorinated dibenzo-p-dioxins and dibenzofurans to Lolium multiflorum Welsh Rye. Gress. Environ. Sci. Technol. 29:1090-1098.
    Wiklund K., Dich J., Holme L.E., 1988 Soft tissue sarcoma risk in Swedish licensed pesticide applicators. J Occup Med 30: 801-804.
    Woods J.S., Polissar L., Severson R.K., Heuser L.S., Kulander B.G., 1987 Soft tissue sarcoma and non-Hodgkin's lymphoma in relation to phenoxyherbicide and chlorinated phenol exposure in western Washington. J Natl Cancer Inst 78: 899-910.
    W. Rotard, W. Christman, W. Knoth. 1994 Background levels of PCDD/F in soils of Germany. Chemosphere 29:2193-2200.
    江旭程等,1989,”ISC空氣品質模式使用手冊”。
    行政院衛生署藥物食品檢驗局,2003,食品中PCDD/Fs背景值調查。
    行政院衛生署藥物食品檢驗局,2004,食品中PCDD/Fs背景值調查。
    行政院衛生署藥物食品檢驗局,2005,食品中PCDD/Fs背景值調查。
    邱奕誠,1997,有害空氣污染物濃度解析方法在風險評估程序中之不確定性研究,國立雲林科技大學環境與安全技術研究所,碩士論文。
    周天穎、周學政,2000,ArcView 透視3.X,松崗電腦圖書股份有限公司,pp.3-1~4-14。
    林育安、林榮信、陳光堯、張伸彰,2003,台灣地區牧草種類與應用,行政院農業委員會農業推廣手冊,pp.1-15。
    施保旭,2001,地理資訊系統,儒林圖書有限公司,pp.63~140。
    陳建民、米孝萱,1999,”七座焚化爐戴奧辛風險評估”,環境品質文教基金會。

    下載圖示 校內:2009-08-03公開
    校外:2010-08-03公開
    QR CODE