| 研究生: |
陳永慶 Chen, Yong-Ching |
|---|---|
| 論文名稱: |
噴墨製程用低加工溫度銅銀墨水的製備與性質 Synthesis and Properties of Low Temperature Cured Copper-Silver Inks for ink-jet printing |
| 指導教授: |
許聯崇
Hsu, Lien-Chung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 材料科學及工程學系 Department of Materials Science and Engineering |
| 論文出版年: | 2013 |
| 畢業學年度: | 101 |
| 語文別: | 中文 |
| 論文頁數: | 71 |
| 中文關鍵詞: | 低加工溫度銅銀墨水 、噴墨印刷 |
| 外文關鍵詞: | low temperature cured copper-silver inks, ink-jet printing |
| 相關次數: | 點閱:69 下載:0 |
| 分享至: |
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本研究利用熱還原法製備低溫噴墨製程用的銅銀二元墨水,藉由銅的前驅鹽Copper(Ⅱ) formate tetrahydrate和錯合劑 n-octylamine去製備出銅墨水,以及利用銀的前驅鹽Silver nitrate和DP (1-dimethylamino-2-propanol)在最佳化的混合溶劑中(乙醇和乙二醇)去製備出銀墨水,接著再將兩種墨水混合在一起去製備出不同比例的銅銀墨水,並以XRD確認在不同熱處理溫度下的轉換效果,以及以SEM去確認薄膜表面燒結的情況。將製備好的銅銀墨水滴在玻璃基板上,在氮氣保護下以160℃進行熱處理1小時,所得最適合的銅銀比例之銅銀薄膜電阻率為3.4×10-4 Ω cm。
Low-temperature cured Copper-Silver binary Inks were prepared from thermal reduction reaction for ink-jet printing. Copper inks were synthesized by thermal decomposition of a copper precursor (Copper(Ⅱ) formate tetrahydrate) and a complexing agent (n-octylamine). Silver inks were synthesized by a silver precursor (silver nitrate) and DP(1-dimethylamino-2-propanol) in an optimal ratio of a mixed solvent(ethanol and ethylene glycol). The two kinds of inks were mixed in different ratio to prepare a binary inks. The conversions of the precursors to the copper and silver were confirmed by XRD. The situation of sintering was observed by SEM. A copper–silver film(copper precursor : silver precursor =1:0.1) was fabricated onto a glass substrate by calcination in nitrogen atmosphere at 160℃ for one hour. The resistivity of the film was 3.4×10-4 Ω cm.
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