本研究之主要目標在於以高溫熱熔法處理廢鹼性電池，回收其中可利用之重金屬包括鐵、錳和鋅，並達到廢鹼性電池固化／安定化的效果。為了提升熱熔融效果，本研究混合白雲石、石灰石及碎玻璃作為電池熱熔處理之添加物，將鹽基度（其定義為熱熔融前CaO與SiO2 之質量比，CaO/SiO2）調整在0.610以幫助熱熔融進行。處理過後產物包含金屬錠、熔渣及排放管道廢氣（分為氣相及固相飛灰），其中金屬錠之主要成分為鐵、錳，總共約佔80～90％，因此金屬錠可用作為煉鐵過程中一項進料來源。而熔渣主要成分為鈣、鎂、錳及矽，其中鈣、鎂及矽主要來自於進料之添加物。經由毒性特性溶出試驗（TCLP）之結果顯示熔渣之金屬溶出值均遠低於相關法規標準值。至於排放管道廢氣中固相飛灰之主要成分以鋅及鉀佔多數。O/I值（output-mass / input-mass ratio）顯示鐵、錳大部分進入金屬錠，鋅主要揮發進入排放管道廢氣中，而鈣、鎂及矽則保留在熔渣中。簡而言之，研究結果顯示高溫熱熔法對於廢鹼性電池之固化／安定化處理並同時回收利用鐵、錳、鋅乃一項預期可行之技術。

The object of this study is to recovery useful metals including Fe, Mn and Zn from waste alkaline batteries and to stabilize those batteries by vitrification. We use the blend of dolomite, limestone and cullet as the additive to enhance the vitrification. The basicity (mass ratio of CaO to SiO2 before vitrification) was adjusted to 0.610 which was favorable for vitrification. The output materials included ingot, slag, and flue gas (gas phase and particulate phase metals). The major composition of ingot was Fe and Mn of which the sum was 80~90% and this product was a good additive for iron making process. In slag, the major constituents were Ca, Mg, Mn, and Si contributed by the additives and toxicity characteristics leaching procedure also reveals its non-toxicity. As for flue gas, the major species were Zn and K which were predominately in particulate phase. The output/input ratio indicated that Fe and Mn mostly moved to ingot, Zn predominately vaporized to flue gas, and Ca, Mg and Si were still retained in slags. Overall speaking, the results shows that the vitrification is a prospective technology to stabilize the waste alkaline batteries and to recovery Fe, Mn and Zn simultaneously.

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