| 研究生: |
蘇郁婷 Su, Yu-Ting |
|---|---|
| 論文名稱: |
微囊藻毒素在淨水處理程序流佈之研究 Occurrence of Microcystins in Water Treatment Processes |
| 指導教授: |
林財富
Lin, Tsair-Fuh |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 環境工程學系 Department of Environmental Engineering |
| 論文出版年: | 2006 |
| 畢業學年度: | 94 |
| 語文別: | 中文 |
| 論文頁數: | 131 |
| 中文關鍵詞: | 微囊藻 、藍綠細菌 、澄清湖 、石門淨水場 、牡丹水庫 、太湖 、微囊藻毒素 |
| 外文關鍵詞: | Cyanobacteria, Chen-Chin Lake, Shi-Men water treatment plant, Tai Lake, Mu-Dan reservoir, microcysis spp., microcystin |
| 相關次數: | 點閱:308 下載:8 |
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本研究以台灣地區三個代表性處理程序之淨水場為對象,包括含傳統淨水程序(石門淨水場)、傳統淨水程序含浮除與慢濾(太湖淨水場)、及高級淨水處理(澄清湖淨水場),進行水源及處理流程監測與分析。探討其微囊藻及毒素流佈狀況、環境因子影響情形、以及藻類毒素去除效能比較。研究中並對金門太湖水庫進行密集採樣,以了解其微囊藻及毒素分佈情況,以供自來水處理技術及管制應用之參考。
研究中對於五種微囊藻毒素進行HPLC及LC/MS定性與定量,並製備檢量線。研究結果發現,藻類計數結果部份水庫表水樣品微囊藻數及葉綠素-a超過世界衛生組織警戒建議值,但是毒素濃度並未超過世界衛生組織之指引值。由於淨水場取水口一般較深,淨水場原水中微囊藻數及毒素濃度通常比同一水庫表水略低。牡丹長期監測結果顯示,主要藻類代謝物如microcystins毒素及2-MIB臭味物質濃度等,隨著季節有變化之趨勢,在較溫暖之季節,其濃度值也相對較高。2-MIB、microcystins毒素及十餘種水質參數迴歸分析結果顯示,微囊藻毒素濃度與水溫具有明顯的相關性。澄清湖因為豪雨、清除底泥影響,濁度值非常高,微囊藻毒素約在110 ng/L之下。
太湖水源短期密集採樣分析結果,太湖取水口代表性藻臭物質2-MIB濃度日變化僅約20%以內;相對而言,微囊藻毒素則明顯隨著時間變化有高達數倍的差距。金門太湖藻華地區發生地點與風向有密切關係。部分藻華MC-LR濃度高於世界衛生組織飲用水建議值1 μg/L。進行胞外分析,發現胞外藻毒濃度,約11%-35 %之間,顯示出大部分的微囊藻毒素是存在於細胞體內,微囊藻毒素與微囊藻數目和葉綠素-a成顯著性正相關。
淨水程序調查結果顯示。石門淨水場毒素平均去除效果均約在66%左右,太湖淨水場去除效率範圍約在54%到84%間,澄清湖淨水場由於2005年毒素濃度相當低,因此約較2004年90%以上之去除果而言偏低,僅在85 %左右。石門淨水場各淨水流程對於微囊藻毒素均有去除效果,但是仍以加氯後到混凝沉澱前去除效果最為明顯,應該是混凝的過程中去除顆粒狀之藻體及其藻體內所含之毒素,以及氯與溶解性毒素反應而降低。太湖淨水場同時含有浮除及慢濾的處理單元,浮除處理程序先將微囊藻藻體去除,溶解性的藻類毒素在慢砂濾處理程序獲得到較大的去除效果。澄清湖淨水場,2005年去除率雖較低,但清水濃度為全部淨水場濃度值最低的,大部分於20 ng/L之下,6月份及9月份甚至為低於偵測極限。
Microcystins, their associated toxin producers, and a few algal metabolites in three typical drinking water systems were monitored and interpreted for their relationships in this study. Two conventional and one advanced water treatment plants (WTPs) were examined, in which Shi-Men WTP represents typical conventional processes, Tai-Lake WTP represents conventional processes with flotation and slow sand filtration, and Chen-Chin Lake (CCL) WTP represents advanced treatment processes. A liquid chromatography with both photo diode array (PDA) detector and mass spectrometer (MS) was employed for the analysis of five typical microcystins in both source water and process water in the three WTPs.
Long-term monitoring data for the source water of Shi-Men WTP, Mu-Dan reservoir, indicated that the concentrations of microcystins and another algal metabolites, 2-MIB, followed the trend that higher concentrations were present in warmer seasons. Strong correlations among 2-MIB concentration, microcystin concentration, and ambient temperature were found in the water samples collected from the reservoir.
Four intensive water sampling were conduced in Tai-Lake for detecting cyanobacteria, microcysis spp., chlorophyll-a, microcystins and 2-MIB concentrations. Most of the parameters measured varied significantly at different depths and different time, and only 2-MIB concentration remained almost constant. This may imply that 2-MIB was likely to uniformly distribute in the reservoir water. In addition, a good correlation between microcystis spp. and microcystins concentrations was found, indicating that the probable relationship between the toxins and their producers. In a few algal blooms observed in Tai-Lake, the microcystins concentration was as high as near 10 μg/L. The extracellular concentrations of total microcystins were between 11%-35%, suggesting that most of the toxins were cell-bound.
For the removal efficiency of microcystins in the three WTPs, about 66% in average were observed for Shi-Men WTP, 54-84 % were for Tai-Lake WTP, and around 85 to >90 % were for CCLWTP. The processes for particulate removal, including floatation and coagulation-sedimentation, can effectively remove cell-bound microcystins. The slow filtration unit and residual chlorine were the two important processes to remove dissolved microcystins.
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