本論文主要使用reverse mode的Polymer-Stabilized Liquid Crystal (PSLC) cell串聯搭配光敏裝置，讓具電壓調控功能的PSLC cell，藉由與光敏裝置之間在照光前後的阻抗變化關係，產生光調控的功能，製作出可主動式電壓調控以及被動式光調控的智慧窗戶。在固定外加電壓的情況下，基於歐姆定律 V=IR 和電壓分配定則Vinput=VPSLC+VLDR，光導裝置在暗環境中處於高電阻的狀態，樣品呈現穩定的透明態，之後隨著環境光增強，光導裝置的電阻大幅下降導致PSLC cell的電壓上升轉變為散射態，其散射程度與環境光強度成正比，展現出多灰階調控效果。
本文實驗分為兩個部分，第一部分將PSLC cell外接光敏電阻(Light-Dependent Resistor, LDR)製作LDR-PSLC smart window；第二部分則採用有機光導體材料TiOPc，嘗試調配出最佳比例的TiOPc溶液，利用特殊的薄膜電極設計，以全溶液製程的方式製作TiOPc-PSLC smart window。光電量測結果顯示出兩者皆有顯著的電及光雙調控效果，並擁有快速的響應時間以及長久的穩定性。最後，我們利用戶外陽光進行驅動，成功以陽光驅動樣品。由實驗結果可知，本文的液晶樣品非常適合應用於智慧窗戶上。

In this study, we develop two types of electro-optically controllable smart window based on a reverse mode Polymer-Stabilized Liquid Crystal (PSLC). The first one is LDR (Light-Dependent Resistor)-PSLC smart window, and the other is TiOPc-PSLC smart window. The experimental results show that they present a stable highly transparent state at low ambient light, and can be fast switched to multi-gray transmission states under a biased applied voltage (~20 V) controlled by the ambient light intensity.

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