國內校園實驗室廢棄物年產生量約為兩、三百噸以上，為了協助成功大學環境資源研究管理中心處理其所收集之全國綜合實驗室廢液，本研究以不同物化技術進行處理，其處理效果為：電-Fenton法 (EF-Fere法)＞Fenton法＞混凝沈澱法，表示電-Fenton法為現階段最適用於去除廢液中高濃度有機物。為使電-Fenton法發揮作用達其較佳處理效果，本研究針對進料水樣（混凝前），改變不同（亞）鐵加藥量，結果發現最佳鐵加藥量為4g-Fe/L，COD去除率可達約九成。推測由於其水樣中Cl-含量太高，導致Cl-與廢水中有機物爭相與高氧化能力的‧OH反應，使得原先預期‧OH會攻擊有機物竟而轉與氯離子進行反應，使得COD仍有10％的殘留。
接著為進一步深入探討最適鐵加藥量，本研究設計了多套光、電系統，針對三價鐵鹽進行鐵還原實驗，找出不同的光源、電源系統中適用於將三價鐵還原成二價鐵的條件。實驗所得到的最適系統為四組直徑5cm不鏽鋼網陰極與直徑0.625cm DSA不溶性陽極的電極， 配合4支UV365nm光源的光電反應器，其最適鐵離子濃度為0.4g-Fe /L，其可在陰極電流密度為6.5A/m2、草酸存在下獲得最佳鐵還原效率。
最後，為了驗證上述最佳系統與及其最適操作條件，本研究以phenol為研究對象，探討不同系列Fenton系統對2000 mg/L phenol的處理效果，結果發現處理效果最差的是Fenton，當系統額外加入光源及電源都可以提高其礦化效果，但處理效果最好的並不是上述的光電-Fenton系統，反而是光-Fenton系統，其礦化效果可達九成。為了提升其他系統的礦化效果，在原來的四小時反應時間結束後，均啟動光源系統進行後續兩小時的反應，研究發現其他的系統均明顯提高礦化效率，且草酸濃度皆明顯下降。推測其原因是以不同Fenton系統處理phenol時，反應中、後半部分生成大量的中間產物草酸，草酸進一步與三價鐵反應形成草酸鐵錯合物(Fe3+-oxalato complexes)，此錯合物難以被‧OH分解，但因其具光反應性，故可加入UV光源進行光分解將其進一步礦化，而提升礦化效率。

Advanced oxidation processes (AOPs) are based on radical reactions and offer the potential of a complete oxidation of water pollutants to water, carbon dioxide and mineral salts. This study applied AOPs to treat high organic concentration wastewater from Sustainable Environment Research Center, NCKU. The result indicated that almost 90% of COD could be removed by using Electro-Fenton process at 4g-Fe/L.
In order to find the optimum Fe(III) dosage UV light was applied into Electro-Fenton system. The result shows that the suitable equipment for reducing Fe(III) is a system with four pairs of electrodes(φ=0.625 cm cylindrical Ti-DSA rod for anode ; φ=5 cm cylindrical SUS304 stainless steel grid for cathode), UV lights. It could obtain maximum ferrous production rate at 0. 4 g-Fe/L, 6.5A/m2 cathode current density and exist of oxalic acid.
The experimental apparatus and working procedures are examined for wastewater treatment and phenol is used to be target compound. Treatment of high concentration phenol shows that almost 100% removal of phenol and about 91% removal of total organic carbon (TOC) are obtained for Photo-Fenton process. The presence of persistent oxalic acid in Fenton and Electro-Fenton react with Fe3+ to form Fe3+-oxalato complexes, which are slowly destroyed by ‧OH. These complexes are photo-active to be efficiently photodecomposed by photo-Fenton and photoelectro-Fenton processes and also found to be successful mineralization.

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