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研究生: 鄭哲硯
Cheng, Che-Yen
論文名稱: CdZnSeS/ZnS量子點保護層對鈣鈦礦太陽能電池之應用
CdZnSeS/ZnS Quantum Dots Protective Layer for Perovskite Solar Cells Application
指導教授: 涂維珍
Tu, Wei-Chen
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 微電子工程研究所
Institute of Microelectronics Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 77
中文關鍵詞: 量子點保護層 、發光降檔 、穩定性 、鈣鈦礦 、太陽能電池
外文關鍵詞: Quantum dots protective layer, Luminous downshift, Stability, Perovskite, Solar cell
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  • 鈣鈦礦太陽能電池具有成本便宜、製程簡單及高度發展性等等的優點受到科學家高度關注,而鈣鈦礦做為電池主動層材料具有一個很大的致命傷,就是很容易因為外在因素而產生降解,像是水氧或是高能紫外光等等的都會使鈣鈦礦降解,因此如何提升鈣鈦礦太陽能電池的光伏特性及穩定性就成為了目前的研究趨勢。
    本篇論文選擇在整體元件的玻璃照光面塗佈具有發光降擋特性及強疏水性的CdZnSeS/ZnS 量子點來做為元件的保護層,並透過各種分析來證明其符合上述所提到的優勢,讓整體元件的光伏特性及穩定性得到顯著的提升。
    實驗成功製作出具有濃度為5 mg/ml量子點保護層的鈣鈦礦太陽能電池,並具有了最佳的表現,功率轉換效率為17.71 %,短路電流密度為21.19 A/cm2,並且在穩定性方面具有了非常顯著的提升,其照光穩定性在持續照光一小時仍保持為初始效率的90 %,以及在大氣穩定性經過十天的存放後能保持為初始效率的70 %,代表CdZnSeS/ZnS 量子點對鈣鈦礦太陽能電池的穩定性具有優異的保護力,未來可以將其應用在對元件的封裝,使得鈣鈦礦太陽能電池能具有更長的壽命。

    In the past decade, solar cells have received significant attention. Currently, most commercially available solar cells are silicon-based. However, due to their high cost and complex manufacturing process, research has shifted towards the development of other types of solar cells. Perovskite solar cells have become a major focus of development. However, perovskite materials are prone to degradation from ultraviolet (UV) light and moisture, presenting challenges that need to be addressed for the commercialization of perovskite solar cells.
    In this study, CdZnSeS/ZnS quantum dots (QDs) were selected as a protective layer to absorb UV light incident on perovskite solar cells and emit visible light for absorption by the perovskite layer. This approach aims to address the rapid degradation caused by ultraviolet (UV) light in perovskite solar cells. Additionally, the hydrophobic properties of CdZnSeS/ZnS QDs help prevent water vapor attachment, greatly enhancing the stability of perovskite solar cells.

    中文摘要 I 致謝 VIII 表目錄 XIII 圖目錄 XIV 第一章 緒論 1 1-1 前言 1 1-2 研究動機 3 第二章 太陽能電池原理 5 2-1 太陽能電池發展 5 2-2 太陽能電池工作原理 6 2-3 鈣鈦礦太陽能電池結構 7 2-3-1 氧化銦錫基坂 (Indium Tin Oxide, ITO) 8 2-3-2 鈣鈦礦(Perovskite)吸收層 9 2-3-3 電子傳輸層(Electron Transport Layer) 10 2-3-4 電洞傳輸層(Hole Transport Layer) 12 2-4 太陽能電池等效電路 13 2-5 太陽能電池常用參數 15 2-5-1 短路電流 16 2-5-2 開路電壓 17 2-5-3 填充因子 17 2-5-4 功率轉換效率 18 2-6 量子點簡介 18 2-4-1 量子侷限效應 19 2-4-2 表面效應 (Surface Effect) 21 2-4-3 製備方法 21 2-7 CdZnSeS/ZnS 量子點 22 第三章 實驗材料及儀器 24 3-1 製程儀器 24 3-1-1 微量吸管 24 3-1-2 旋轉塗佈儀 25 3-1-3 電磁加熱攪拌器 26 3-1-4 超音波洗淨機 27 3-1-5 惰性氣體手套箱 28 3-1-6 熱蒸鍍機 30 3-1-7 電子天秤 31 3-1-8 電漿清潔儀 32 3-2 量測儀器 33 3-2-1 太陽光源模擬器 33 3-2-2 光電轉換效率 35 3-2-3 接觸角量測儀 36 3-2-4 光致發光光譜儀 37 3-2-5 紫外光-可見光-近紅外光分光光譜儀 38 3-2-6 X光繞射儀 40 第四章 實驗步驟 41 4-1 鈣鈦礦太陽能電池製程與結構 41 4-2 ITO基板蝕刻 43 4-3 NiOx電洞傳輸層製備 44 4-4 CH3NH3PbI3吸收層製備 45 4-5 PC61BM電子傳輸層製備 46 4-6 BCP緩衝層製備 47 4-7 銀電極蒸鍍 48 4-8 CdZnSeS/ZnS量子點保護層製備 48 第五章 結果與討論 50 5-1 CdZnSeS/ZnS量子點 50 5-1-1 CdZnSeS/ZnS量子點之穿透與吸收特性分析 50 5-1-2 CdZnSeS/ZnS量子點之光致發光光譜分析 53 5-1-3 CdZnSeS/ZnS量子點之水滴接觸角分析 55 5-1-4 材料之XRD分析 56 5-2 PSC之量測分析 58 5-2-1 PSC之吸收光譜分析 58 5-2-2 PSC之光電轉換效率分析 60 5-2-3 PSC之電流及電壓量測分析 63 5-2-4 PSC之照光穩定性分析 67 5-2-5 PSC之大氣穩定性分析 69 第六章 結論及未來展望 70 參考文獻 71

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