| 研究生: |
郭凡稜 Kuo, Fan-Leng |
|---|---|
| 論文名稱: |
大氣中戴奧辛/呋喃之氣固相及粒徑分佈 Gas/Particle Phase Partitions and Size Distributions of PCDD/Fs in Atmosphere |
| 指導教授: |
李文智
Lee, Wen-Jhy |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 環境工程學系 Department of Environmental Engineering |
| 論文出版年: | 2007 |
| 畢業學年度: | 95 |
| 語文別: | 中文 |
| 論文頁數: | 203 |
| 中文關鍵詞: | 戴奧辛 、粒徑分佈 、氣固相分佈 |
| 外文關鍵詞: | Gas/Particle partition, PCDD/Fs, Size Distribution |
| 相關次數: | 點閱:81 下載:1 |
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爲了調查台灣南部K與R垃圾焚化廠所排放之PCDD/Fs對周遭環境之影響,本研究針對這二座垃圾焚化廠周界之大氣濃度、氣固相分佈及粒徑分佈分別進行PCDD/Fs含量採樣分析,研究結果如下:
K垃圾焚化廠周界大氣PCDD/Fs平均濃度為0.0749 pg I-TEQ/Nm3;R垃圾焚化廠為0.0727 pg I-TEQ/Nm3。
K垃圾焚化廠周界大氣總氣相及總固相PCDD/Fs平均濃度分別為0.0358及0.0283 pg I-TEQ/Nm3;R垃圾焚化廠為0.0315及0.0195 pg I-TEQ/Nm3。利用氣固相分佈之模式模擬K垃圾焚化廠周界大氣總氣相及總固相PCDD/Fs平均濃度分別為0.0405及0.0345 pg I-TEQ/Nm3;R垃圾焚化廠為0.042 及0.0305 pg I-TEQ/Nm3,將氣固相分佈之實測值與模式模擬值相互比較,可了解採樣分析時之人為誤差(Artifact)。
垃圾焚化廠周界大氣中懸浮微粒分佈均呈現雙峰分佈,其粒徑分別為3.2~36.5 μm及0.52~1.8 μm;總PCDD/Fs主要呈現為單峰分佈,其粒徑分別為0.31~1.0 μm;總I-TEQ PCDD/Fs主要仍呈現為單峰分佈,其粒徑分別為0.31~1.0 μm。
垃圾焚化廠周界大氣中懸浮微粒、總PCDD/Fs及總I-TEQ PCDD/Fs之濃度累積粒徑分佈,其平均MMD值分別為5.77、0.77及0.78 μm。垃圾焚化廠周界大氣中懸浮微粒、總PCDD/Fs及總I-TEQ PCDD/Fs之平均MMDo及δg,o值分別為(5.77、0.77、0.71)及(5.17、2.68、2.32) μm;平均MMDf及δg,f值分別為(0.98、0.62、0.59)及(1.91、2.04、1.98) μm;平均MMDc及δg,c值分別為(12.78、7.44、8.74)及(2.72、2.75、2.63) μm,可知大氣中懸浮微粒在不同粒徑範圍之分佈甚廣。
各採樣點粒狀物相PCDD/Fs含量之粒徑分佈皆隨粒徑增加而遞減之趨勢,且較小粒徑之懸浮微粒有較大之PCDD/Fs含量,其原因可歸為較小之懸浮微粒具有較大之比表面積,故經由大氣冷凝等作用後,可吸附較多氣相中之PCDD/Fs;在較大粒徑之懸浮微粒有較少之PCDD/Fs含量,此因PCDD/Fs主要吸附於粒徑較小之懸浮微粒,而大粒徑範圍之PCDD/Fs在主要是來自土壤風化、路塵及交通工具之再捲揚作用至大氣所造成。
In order to investigate K and R municipal solid waste incinerators (MSWIs) PCDD/Fs of flue gas effect on the surrounding environment. This research focus on K and R MSWIs`s ambient air, Gas/Particle Partitions and Size Distributions of PCDD/Fs. The results are as follows:
K MSWI average concentration in ambient air of PCDD/Fs is 0.0749 pg I-TEQ/Nm3; and R MSWI is 0.0727 pg I-TEQ/Nm3.
K MSWI Gas/Particle Partitions of PCDD/Fs average concentration is 0.0358 and 0.0283 pg I-TEQ/Nm3; R MSWI is 0.0315 and 0.0195 pg I-TEQ/Nm3. K MSWI Gas/Particle Partitions simulation model of PCDD/Fs average concentration is 0.0405 and 0.034 pg I-TEQ/Nm3; R MSWI is 0.042 and 0.0305 pg I-TEQ/Nm3. To compare surveying and simulation value, that can get the sampling and analysis of Artifact.
In MSWI, the size distributions of total particle mass is showed of two peaks, the total particle mass range 3.2~36.5 and 0.52~1.8 μm; the total PCDD/Fs and total I-TQE PCDD/Fs are showed of one peak, the total PCDD/Fs and total I-TQE PCDD/Fs range 0.31~1.0 μm.
In MSWI, the cumulative percentage of the total particle mass, total PCDD/Fs and total I-TQE PCDD/Fs, the average MMD are 5.77, 0.77 and 0.78 μm. In MSWI, the average MMDo andδg,o of the total particle mass, total PCDD/Fs and total I-TQE PCDD/Fs, the value are (5.77, 0.77 and 0.71) and (5.17, 2.68 and 2.32) μm;the average MMDf and δg,f are (0.98, 0.62 and 0.59) and (1.91, 2.04 and 1.98) μm;the average MMDc and δg,c are (12.78, 7.44 and 8.74) and (2.72, 2.75 and 2.63) μm.
In all of sampling site, the total PCDD/Fs of MMDo value are less than total particle mass of MMDo value. According to the total particle mass and the total PCDD/Fs of theδg,o, it indicates that the distribution range of small particles is larger than the coarse particles. And the range of particle distribution is quite large in atmosphere. Small particle has higher PCDD/Fs concentration than that of larger particle. It could be due to the small particle has larger surface and adsorb more PCDD/Fs on it.
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