本研究整理與再分析氫化鈉D1Σ+能態以及氘化鈉C1Σ+能態。氫化鈉D1Σ+方面，整理了本實驗室楊承翰、江仁楙、以及蕭翊翔學長的實驗數據，藉由最新發表的氫化鈉A1Σ+的振轉能態的能量作為中間態的能量，加上重新校正過的probing雷射能量值計算出D1Σ+各個振轉能級的絕對能量值，此方法消弭了不同實驗數據的誤差值。利用校正過的實驗數據，搭配理論計算的D1Σ+位能曲線[ Can. J. Phys. 87, 543 (2009)]，分析出D state兩個位能井的振轉量子數及能量。經由些微改變理論計算位能曲線以及實驗數據的登亥姆係數運算結果，獲得更為吻合實驗數據的位能曲線。
氘化鈉C1Σ+方面，整理了本實驗室林明弘及鄭守恩學長的實驗數據，藉由重新校正過實驗所使用中間態氘化鈉A1Σ+振轉能態的能量，對比了經過同位素轉移的氫化鈉C1+能態[ J. Chem. Phys. 148, 114301 (2018) ]，與同位素轉移後的數值較為接近，故以校正後的數據導出NaDＣ1Σ+雙位能井之下的RKR位能曲線。於雙位能井部分，利用NaH C1Σ+雙位能井位能曲線加以變形，擬合出符合NaD C1Σ+實驗數據值的位能曲線。

In this work, the experimental data of the NaH D1Σ+ state and the NaD C1Σ+ are reanalyzed. For the D1Σ+ state, the experimental works done by Yang, Chiang, and Hsiao are recalibrated by replacing the original intermediate A1Σ+ state with the latest published values and recalibrating the probing laser to calculate the absolute energy; this method diminishes the deviation among the different experimental works. By exploiting the recalibrated experimental signals and the potential energy curve of the theoretical ab initio calculation [ Can. J. Phys. 87, 543 (2009)], the vibrational quantum numbers and the corresponding rovibrational energies are indicated. Moreover, through the slight deformation of the theoretical potential curve, the new potential energy curve that accords better with the experimental data is presented.
For the NaD C1Σ+ state, experimental works performed by Lin and Cheng are reanalyzed. By recalibrating the NaD A1Σ+ intermediate state, the recalibrated experimental signals of the C1Σ+ state fits well with the isotopically shifted potential curve of the NaH C1Σ+ state [ J. Chem. Phys. 148, 114301 (2018) ], so these signals are applied to derive the RKR potential energy curve below the double-well region. Besides, by slightly deforming the potential energy curve of the double-well NaH C1Σ+ state, the potential energy curve that accords well with the experimental data of the C1Σ+ state is proposed.

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