利用水熱/溶劑熱法，我們成功的合成出一系列鑭金屬有機配位聚合物。我們實驗得到五個新穎的鑭系金屬化合物。化合物先經由X-光單晶繞射儀鑑定出它們的結構，接著由元素分析儀與X-光粉末繞射儀確定化合物純度，再以紅外線光譜儀分析特定官能基，最後利用超導磁性量子干涉儀探討其磁性行為。

Five new lanthanide coordination polymers have been prepared under the mild solvothermal conditions.The five compounds belong to two new three-dimensional (3D) structural groups.The assembly of heterometallic 3d-4f ions and organic ligands, have successfully constructed two series of metal-organic frameworks. Single-crystal structures, elemental analyses, Infrared records, and magnetic behavior were characterized for these compounds.

1.(a) Reinhard, C. a. G., H. U. , Inorg. Chem. 2002, 41, 1048-1055 ; (b) Sharma, C. V. K. R., R. D. , Chem. Commun. 1999, 83-84
2.Bangln Chen, S. X., and Guodong Qian, Accounits of Chemical Research 2010, 43, 1115-1124.
3.M. D. Allendorf, C. A. B., R. K. Bhakta, and R. J. T. Houk, Chem. Soc. Rev. 2009, 38, 1330-1352.
4.Ruiyao Wang, H. L., Michael D. Carducci, Tianzhu Jin, Chong Zheng, and Zhiping Zheng, Inorg. Chem. 2001, 40, 2743-2750.
5.(a) Yajie Gao, L. Z., Xuebin Xu, Gong-Feng Xu, Yun-Nan Guo, Jinkui Tang, and Zhiliang Liu, Inorg. Chem. 2011, 50, 1304-1308;
(b) Simon M. Humphrey, A. A., Carlos J. Go'mez Garcia, and Paul T. Wood, Chem. Commun. 2006, 1607-1609.
6.Kai Liu, H. Y., Yuhua Zheng, Guang Jia, Yanhua Song, Yeju Huang, Mei Yang, Junjiao Jia, Ning Guoa and Hongjie Zhang, J. Mater. Chem. 2010, 20, 3272-3279.
7.Marco Evangelisti, O. R., Elias Palacios, Agustin Camo'n, Thomas N. Hooper, Euan K. Brechin, and Juan J. Alonso, Angew. Chem. Int. Ed. 2011, 50, 6606-6609.
8.Pei-Xin Li, a. J.-G. M., Crystal Growth & Design 2008, 8, 3385-3389.
9.Zhaob., B.-D. R. a. Y.-J., Acta Cryst. 2006, E62, m170-m171.
10.Chiara Dinoi, P. P., Funda Demirhan, Jenny Gun, Ovadia Lev., Journal of Organometallic Chemistry 2007, 692, 2599-2605.
11.Jean-Pierre Costes, J. M. C.-J., FranÁoise Dahan, Franck Nicode ¡me, and Marc Verelst, Angew. Chem. Int. Ed. 2002, 41, 323-325.
12.Marı´a Herna ´ndez-Molina, C. R.-P. r., Trinidad Lo ´pez, Francesc Lloret, and Miguel Julve, Inorg. Chem. 2003, 42, 5456-5458.
13.Athanassios Panagiotopoulos;Theodoros F. Zafiropoulos: Spyros P. Perlepes, y. E. B., Isabelle Masson-Ramade,Olivier Kahn, Aris Terzis, and Catherine P. Raptopoulou, Inorg. Chem. 1995, 34, 4918-4920
14.Laura Ca˜ nadillas-Delgado, O. F., Jorge Pas´ an, Fernando S. Delgado, Francesc Lloret, Miguel Julveb and Catalina Ruiz-P´ erez, Dalton Trans. 2010, 39, 7286-7293.
15.Laura Can ˜ adillas-Delgado, J. P. n., Oscar Fabelo, Marı ´a Herna ´ndez-Molina, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pe ´rez, Inorg. Chem. 2006, 45, 10585-10594.
16.Subal Chandra Manna, E. Z., Alessandro Bencini,Cristiano Benelli, and Nirmalendu Ray Chaudhuri,, Inorg. Chem. 2006, 45, 9114-9122.
17.Gatteschi, C. B. a. D., Chem. Rev. 2002, 102, 2369-2388.
18.Hsiao.Chan Liu, I. H. C., Anny Huang, Sin.Chiang Huang and Kuei-Fang Hsu, Dalton Trans. 2009, 3447-3456.
19.Ricardo Baggio, R. C., Marı ´a Teresa Garland, Octavio Pen ˜a,Mireille Perec, and Alberto Rizzi, Inorg. Chem. 2005, 44, 8979-8987.
20.Urland, D. J. a. W., Z. anorg. allg. Chem. 2005, 631, 2635-2637.
21.Urland, D. J. a. W., Eur. J. Inorg. Chem. 2006, 3503-3509.
22.S. C. Manna, E. Z., J. Ribas and N. R. Chaudhuri, Polyhedron 2006, 25, 1779-1786.
23.Laura Ca˜ nadillas-Delgado, O. F., Jorge Pas´ an, Fernando S. Delgado, Francesc Lloret, Miguel Julveb and Catalina Ruiz-P´ erez, Cryst Eng Comm 2009, 11, 2131-2142
24.Urland, A. R. a. W., Z. anorg. allg. Chem. 2005, 631, 417-420.
25.Urland, S. T. H. a. W., Angew. Chem. Int. Ed. 2003, 42, 2862-2864.
26.Boca, R., Coord. Chem. Rev. 2004, 248, 757-815
27.(a) Sheldrick, G. M., Program for the Solution of Crystal Structure. Germany, 1997;
(b) Sheldrick, G. M., Program for the Refinement of Crystal Structure. Germany, 1997.
28.Robin G. Prichard, R. V. P. a. Z. S., Dalton Trans. 1999, 243-250.
29.Dan Li, T. W., Xiao-Ping Zhou, Rui Zhou, and Xiao-Chun Huang, Angew. Chem. Int. Ed. 2005, 44, 4175-4178.
30.Biplab K. Maiti, K. P., and Sabyasachi Sarkar, Eur. J. Inorg. Chem. 2007, 5548-5555.
31.Richard V. Parish, Z. S., and Robin G. Pritchard, Angew. Chem. Int. Ed. 1997, 36, 251-253.
32.Zahra Salehi, R. V. P. a. R. G. P., Dalton Trans. 1997, 4241-4246.
33.方俊鑫、陸棟, 中華民國79年;固態物理學 [下冊]. 亞東書局: p 257-319.
34.杜怡君、張毓娟、翁乙壬、蘇怡帆、陳世毓、梁哲銘、葉巧雯、吳信璋、卓育泯 磁性基本特性及磁性材料應用; 國立台灣大學化學系.
35.(a) Duan, L. M.; Ye, L.; Liu, Y. B.; Xie, F. T.; Yu, J. H.; Xu, J. Q., Synthesis, structure and magnetic property of a new neodymium-adipate coordination polymer with large guest molecules. Pol. J. Chem. 2005, 79 (12), 1835-1842;
(b) Li-Qiong Yu, R.-D. H., Yan-Qing Xu, Tian-Fu Liu, Wei Chu, Chang-Wen Hu, Inorganica Chimica Acta 2008, 361, 2115-2122;
(c) Jean-Claude Bernier, A.-M. L., Roger Tueta,Robert Collongues, Materials Research Bulletin 1973, 8 (3), 261-270.
36.Jing-Ping Wang, J.-W. Z., Xian-Ying Duan, and Jing-Yang Niu, Cryst. Growth Des. 2006, 6, 507-513.
37.Ruiting Liu , X. L., Houcai Zhang , Linhong Weng and Xigeng Zhou Dalton Trans. 2010, 39, 11053-11059.
38.Xiaoping Yang, R. A. J. a. M. J. W., Dalton Trans. 2004, 1787-1788.