| 研究生: |
俞睿堯 Yu, Jui-Yao |
|---|---|
| 論文名稱: |
創新固體推進奈米鋁粉閃光點火藥之研究 A Novel Nano-Aluminum Flash Igniter for Solid Rockets |
| 指導教授: |
趙怡欽
Chao, Yei-Chin |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 航空太空工程學系 Department of Aeronautics & Astronautics |
| 論文出版年: | 2017 |
| 畢業學年度: | 105 |
| 語文別: | 中文 |
| 論文頁數: | 35 |
| 中文關鍵詞: | 奈米鋁粉 、閃光點燃 、火箭點火系統 |
| 外文關鍵詞: | Aluminum Nanoparticle, Flash-ignition mechanism, Rocket Ignition System |
| 相關次數: | 點閱:87 下載:13 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
傳統且成熟的固推點火方式多以電控系統觸發,而點火系統可能會受到發動機空間配線的限制,或者點火器構造成火箭發動機重量增加,隨著奈米金屬材料獨特光熱轉換的興新研究,也許能以非介入式遠端閃光點燃啟動固態火箭,若是能藉由閃光點燃不但能減輕發動機重量、還能簡化整個系統。
本研究欲藉由奈米鋁粉閃光點燃的特性,混合硝化纖維與高氯酸銨(Ammonium perchlorate, AP)製作出一個高能的閃光點燃點火藥,本研究涵蓋從製程調配到點燃機制探討再到實際工程應用,其中以不同設備進行點火藥的特性分析再搭配不同的實驗的觀察,找出閃光點燃機制的反應過程。
最後以一具小型發動機驗證閃光點火系統,證實了此創新點火藥應用於非介入式遠端點燃固體火箭概念的可行性。
SUMMARY
In this study, we develop a novel and high energetic flash igniter which combines of nano-aluminum (nAl) powder and Nitrocellulose (NC) and Ammonium perchlorate (AP). The ignition mechanism of the flash igniter is deduced through the comparison between the Thermogravimetric Analysis(TGA) characteristic analysis and the experiments, and we also validate the feasibility of the flash ignition system with a small motor. We prove the feasibility of this novel nano Aluminum flash igniter can be applied to the concept of non-intervening ignited of solid rocket by this motor.
[1] Anil K. Kulkarni, Mridul Kumar, and Kenneth K. Kuo, 1982, “Review of Solid-Propellant Ignition Studies” AIAA 80-1210R VOL. 20, NO. 2.
[2] “中山科學研究院第二研究所 固體推進劑火箭發動機,” 1987.
[3] D. O. Glushkov , G. V. Kuznetsov, and P. A. Strizhak, 2016, “Ignition of a Metallized Composite Solid Propellant by a Group of Hot Particles,” Combustion, Explosion, and Shock Waves, 2016, Vol. 52, No. 6, pp. 694–702.
[4] David A. Reese,Darren M. Wright,Steven F. Son, 2013, “CuO∕Al Thermites for Solid Rocket Motor Ignition,” JOURNAL OF PROPULSION AND POWER Vol. 29, No. 5.
[5] A. A. Zenina, C. Zanottib , P. Jiuliani, 2014, “Characteristics of Composite Propellant Ignition by a CO2Laser,” Russian Journal of Physical Chemistry B, Vol. 8, No. 4, pp. 475–484.
[6] A. A. Zenin and S. V. Finyakov, 1993, “STUDY OF SOLID PROPELLANT IGNITION BY A HOT GAS STREAM,” Vol. 29, No. 3, pp. 20-26.
[7] U. I. Gol'dshleger, V. V. Barzykin, T. P. Ivleva, 1973, “Ignition of Condensed Explosives by a Hot Spherical Particle” Vol. 9, No. 5, pp. 733-740.
[8] H. L. Girdhar, A. J. Arora, 1978, “Ignition of Composite Solid Propellants by the Hot Plate Technique,” COMBUSTION AND FLAME 31,245-250.
[9] P. Ajayan, M. Terrones, A. De la Guardia, V. Huc, N. Grobert, B. Wei, H. Lezec, G. Ramanath, T. Ebbesen, , 2002, “Nanotubes in a flash--ignition and reconstruction, ” Science, 296, 705.
[10] J. Smits, B. Wincheski, M. Namkung, R. Crooks, R. Louie, , 2003 “Response of Fe powder, purified and as-produced HiPco single-walled carbon nanotubes to flash exposure, ” Materials Science and Engineering: A, 358, 384-389.
[11] Z. Nan, B.M. Anthony,2009, “Heat generation by optically and thermally interacting aggregates of gold nanoparticles under illumination, ” Nanotechnology, 20, 375702.
[12] M. Rashidi-Huyeh, B. Palpant, 2004, “Thermal response of nanocomposite materials under pulsed laser excitation, Journal of Applied Physics, ” 96, 4475-4482.
[13] L. Castronuovo, D. Dunn-Rankin, J. Garman, “Photoignited aluminum nanopowder combustion in air. ”
[14] A.O. Govorov, H.H. Richardson, 2007, “Generating heat with metal nanoparticles,” Nano Today, 2, 30-38.
[15] Yuma Ohkura, Pratap M. Rao, Xiaolin Zheng, 2011, “Flash ignition of Al nanoparticles: Mechanism and applications,” Combustion and Flame 158 (2011) 2544–2548.
[16] Kim Aarseth Larsson, Bert van Bavel, 2015, “Chemical Characterisation of Nitrocellulose,”
[17] L. DAUERMAN, Y. A. TAJIMA, 2014, “Thermal Decomposition and Combustion of Nitrocellulose,” AIAA JOURNAL VOL. 6, NO. 8.
[18] S.M. Pourmortazavi , S.G. Hosseini, M. Rahimi-Nasrabadi, S.S. Hajimirsadeghi, H. Momenian, 2009, “Effect of nitrate content on thermal decomposition of nitrocellulose,” Journal of Hazardous Materials 162 , 1141–1144.
[19] LIU HUWEI , FU RUONONG, 1988, “Studies on thermal decomposition of nitrocellulose by pyrolysis-gas chromatography” Journal of Analytical and AppIied Pyrolysis, 14 163-169.
[20] 詹于霈, 2016, “奈米鋁粉高能點火器最低閃光點燃能量之分析:二維粒子間距的效應,” in: 航空太空工程學系,國立成功大學.
[21] Leili Liu, Fengsheng Li, Linghua Tan, Li Ming, Yang Yi, 2004, “Effects of Nanometer Ni, Cu, Al and NiCu Powders on the Thermal Decomposition of Ammonium Perchlorate,” Propellants, Explosives, Pyrotechnics 29, No. 1.
[22] S. Ramamurthy , P. G. Shrotri, 2014, “Catalytic decomposition of ammonium perchlorate a survey,” Journal of Energetic Materials.
[23] 陳明德, 過氧化氫鋁冰火箭藥柱性能分析:過氧化氫/水比例與奈米/微米鋁粉比 例對退縮率之影響, in: 航空太空工程學系, 國立成功大學, 2015.