| 研究生: |
林佩蓉 Lin, Pei-Jung |
|---|---|
| 論文名稱: |
利用溶膠凝膠法製備二氧化鈦-活性碳複合粉末及光催化效果之研究 Synthesis of TiO2-Activated carbon powders by sol-gel method and study of the photocatalytic activity |
| 指導教授: |
黃紀嚴
Huang, Chi-Yen |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 資源工程學系 Department of Resources Engineering |
| 論文出版年: | 2007 |
| 畢業學年度: | 95 |
| 語文別: | 中文 |
| 論文頁數: | 77 |
| 中文關鍵詞: | 溶膠凝膠法 、二氧化鈦 、活性碳 |
| 外文關鍵詞: | TiO2/AC, photocatalysis |
| 相關次數: | 點閱:109 下載:5 |
| 分享至: |
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二氧化鈦具有能隙大且無自溶性而廣為業界所使用,不論對水和空氣中有毒物質去除污水之純化、環境臭氧、CO2之固定氟氯碳化物之分解等都佔有極大之重要性,而隨著環保意識高漲,越來越多之研究也指向二氧化鈦,但是二氧化鈦卻有著低比表面積及熱穩定不佳之缺點,使得其在發展上大大打了折扣,如何改善其缺點則為現今專家學者研究的重點之ㄧ。
本研究利用溶膠凝膠法製備二氧化鈦-活性碳之複合粉末,由於活性碳具有高比表面積及多孔性質之優點,藉由異質成核機制,不僅可以降低二氧化鈦晶粒大小並提高其活性,且利用複合粉末也可達到改善二氧化鈦低比表面積及熱穩定性不佳之缺點。
將所得之複合粉末利用XRD、SEM等儀器推測其核為活性碳,微小之二氧化鈦粒子披覆其上,並且利用TEM等照片驗證確定二氧化鈦-活性碳複合粉末,藉由FTIR確認二氧化鈦與活性碳接合之情形,在光催化測試方面,複合粉末具有超越純二氧化鈦之光催化效果,原因為複合粉末確實可壓抑二氧化鈦粒子之成長並提高周圍污染物濃度,因而提高二氧化鈦光催化之效能。
TiO2 photocatalysts has attracted a great deal of attention with the increasing number of recent environmental problems in the world, especially for the detoxification of water and air. TiO2 must overcome the faults related to the low surface area of TiO2, it could be solven by modifying TiO2 on activated carbon surface.
In this study, activated carbon is regarded as substrate, and TiO2 sols was loaded on it, which was prepared by sol-gel method using tetraisopropyl titanate as precursor to mount thin TiO2 film on activated carbon by heterogeneous growth.
The TiO2-mounted activated carbon powder is characterizes by XRD、SEM for assuming that activated carbon is regarded as substrate and TiO2 is dispersed on it, and prove that have Ti-O-C chemical bonding by TEM、FTIR. The powder was employed as catalysts for photocatalytic test that was conducted on methylene blue,CO2 and bacteria reduction. The composite powder is observed by TEM that the crystallite size of TiO2 is smaller than bare TiO2(15nm and 24nm in 600℃) and this result is also proved by XRD calculation. Furthermore, The composite powder was shown higher photoactivity for the three photocatalytic test under UV irradiation. Compared to bare TiO2 prepared in parallel,it is attributed to the activated carbon large surface area and TiO2 dispersed on it as well as diminish anatase crystallite size.
1.葉國樑、吳瑞賢、許峰明、林勝雄,“以粒狀活性碳及活性碳纖
維處理氣相有機物之研究比較”,石油季刊,第32 卷,第一期,
pp43-52,1996。
2.邱正宏,“吸附於活性碳表面揮發性有機物之熱脫附動力學研
究”,國立中山大學環境工程研究所碩士論文,1993。
3.蔣本基,“活性碳物理化學特性對VOCs 吸附之影響”,工業污
染 防治,第58 期,1996。
4. 楊英傑,“以球狀活性碳吸附水溶液中甲苯及其脫附方法之研
究”,國立成功大學化學工程研究所碩士論文,1992。
5. I. Bedjat, P. V. Kamat, “Capped semiconductor
colloids. synthesis and photoelectrochemical behavior
of TiO2 -capped SnO2 nanocrystallites”, J. Phys.Chem.,
99, pp9182-9188, 2005.
6. A. Giraudeau, F. –R. F. Fan, and A. J. Bard,
“Semiconductor electrodes. 30. spectral sensitization
of the semiconductors n-TiO2 and n-WO3 with metal
Phthalocyanines”, J. Amer. Ceram. Soe., 16, pp102,1980.
7. R. W. Fessenden, P. V. Kamat, “Rate constants for
charge Injection from excited sensitizer into SnO2,
ZnO, and TiO2 semiconductor nanocrystallites”,
J.Phys.Chem., 99, pp12902-12906, 1995.
8. P. D. Cozzoli, R. Comparelli, E. Fanizza, M. L. Curri,
A. Agostiano, and D. Laub, “Photocatalytic synthesis
of silver nanoparticles stabilized byTiO2 nanorods: A
semiconductor/metal nanocomposite in homogeneou
nonpolar solution”, J. Amer. Ceram. Soe., 126,
pp3868-3879, 2004.
9. J.Yu, X. Zhao, “Effect of surface treatment on the
photocatalytic activity and hydrophilic property of the
sol-gel derived TiO2 thinfilms”,Mater.Res,Bull.36,pp97-
107,2001.
10.C. Trapails, A.D. Modestov, O. Lev, “Sol-gel
processing of titanium-containing thin coatings”, J.
Mater. Sci. 28,pp1276-1282,1993.
11.楊子寬,“利用溶膠凝膠法製備TiO2-Al2O3粉末及對TiO2光催化
效果影響之研究”,國立成功大學資源工程研究所碩士論
文,2004.
12.Linsebigier, A. L.; Lu, G. and Yates, J.T.,
“Photocatalysis on TiO2 surface: principles, mechanism,
and selected results”, Chemistry Reviews, Vol.95,
pp735-758, 1995.
13. M.Gratzel, N. Serpone, and E. Ed. Pelizzetti
“Colloidal semiconductor-in photocatalysis”, John
Wiley & Sons. New York,1989.
14. A. Mill, S. L. Hunte, “An overview of semiconductor
photocatalysis”, J.Photochem. and Photobio. A, 108,
pp1-35,1997.
15.中山千秋, “光觸媒の評價法と標準化”, 工業材料2002年7
月號,vol.50,No.7,2002。
16. M.R. Hoffmann, S.T. Martin, W. Choi, and D.W.
Bahnemann,“Environmental applications of
semiconductor photocatalysis,” Chem. Rev., 95, pp69-
96, 1995.
17. I. Willner, “ Photoswitchable biomaterials- En route
to optobioelectronic systems”, Acc. Chem. Res., 30,
pp347-356, 1997.
18. Y. Xu, W. Zheng, W. Liu, “Enhanced photocatalytic
activity of supported TiO2:dispersing effect of
SiO2”, J.Photochem. and Photobio. A., 122, pp57-60,
1999.
19. Amy L. Linsebigler, G. Lu, J. T. Yates, and Jr.,
“Photocatalysis on TiO2 surface:principles,
mechanisms, and selected results”, Chem. Rev., 95,
pp735-758, 1995.
20. K. M. Reddy, S. V. Manorama, A. R. Reddy, “Band gap
studies on anatase titanium dioxide nanoparticles”,
Mater. Chem. and Phys., 78, pp239-245, 2002.
21. K. Nagaveni, M. S. Hegde, N. Ravishankar, G. N.
Subbanna, G. Madras, “Synthesis and structure of
nanocrystalline TiO2 with lower band gap showing high
photocatalytic activity”, Langmuir , 20, pp2900-2907,
2004.
22. C. H. Hung, , and B. J. Marinas, , “Role of chlorine
and oxygen in the photocatalytic degradation of
trichloroethylene vapor on TiO2 films”,
Environ.Sci.Technol., 31:2, pp562-568, 1997.
23. E. Hosono, S. Fujihara, K. Kakiuchi, H. Imai, “Growth
of submicrometer-scale rectangular parallelepiped
rutile TiO2 films in aqueous TiCl3 solutions under
hydrothermal conditions”, J. Amer. Ceram. Soe., 126,
pp7790-7791, 2004.
24.K. J. Kim, K. D. Benkstein, Jao van de Lagemaat, A.
J.Frank, “Characteristics of low-temperature annealed
TiO2 films deposited by precipitation from hydrolyzed
TiCl4 solutions”, Chem. Mater., 14, pp1042-1047, 2002.
25.曹茂盛、關長斌、徐甲強編著,“奈米材料導論”,學富文化,
pp54,2002.
26. R.S. Sonawane, S.G. Hegde, M.K. Dongare, “Preparation
of titanium(IV) oxide thin film photocatalyst by sol–
gel dip coating”, Mater. Chem. and Phys., 77, pp744–
750, 2002.
27. N. Kaliwoh, J.Y. Zhang, I. W. Boyd, “Titanium dioxide
films prepared by photo-induced sol-gel processing
using 172 nm excimer lamps”, Surface Coatings
Technolog , 125, pp424-427, 2000.
28. Y. Xu, W. Zheng, W. Liu, “Enhanced photocatalytic
activity of supported TiO2:dispersing effect of
SiO2”, J.Photochem. and Photobio. A., 122, pp57-60,
1999.
29. R. Aelion, A. Loebel, F. Eirich, “Hydrolysis of ethyl
silicate”, J. Am. Chem. Sci., 72, pp5705, 1950.
30. C. Morterra, “An infrared spectroscopic study of
anatase properties”, J. Chem. soc. Faraday Trans.I, 84
(5),pp1617-1637, 1988.
31. H. Y. Ha, and M. A. Anderson., “Photocatalytic
degration of formic acidvia metal-supported
titania”,J. Environ. Engin., 122, pp217-221, 1996.
32. J. Araña , J.M. Doña-Rodr´ıguez , E. Tello Rendóna,
“TiO2 activation by using activated carbon as a
support Part I. Surface characterisation and
decantability study”,Applied Catalysis B:
Environmental,44,pp161-172,2003.
33. H. Yoneyama,, “Titanium Dioxide/Adsorbent Hybrid
Photocatalysts for Photodestruction of Organic
Substances of Dilute concentrations”, Catalysis
Today, 58, pp.133-140,2000.
34. B. Tryba,A. W. Mooraski, M. Inagaki, “A new route for
preparation of TiO2-mouted activated carbon”,
Environmetal.,46,pp203-208,2003.
35. Y. Li, X. Li, J. Li, J. Yin, “Photocatalytic
degradation of methyl orange in a sqarged tube reactor
withTiO2-coated carbon composites”,Catslysis
Communications.,6,pp650-655,2005.
36. A. Houas, H. Lachheb, M. Ksibi, E. Elaloui,C.
Guillard, J.M.Herrmann, “ Photocatalytic degradation
pathway of methylene blue in water,” Applied
Catalysis B: Environmental,31,pp145-147,2001.
37. S. S. Tan, L. Zou, E. Hu , “Photocatalytic reduction o
f carbon dioxide into gaseous hydrocarbon using TiO2
pellets”, Catalysis Today,115,pp269-273,2006
38. 鄭美玲,“氧化壓力對細胞生理之影響:以腐植酸及葡萄六磷酸
去氫酵素缺乏細胞為模式探討”,國立台灣大學醫學院生化學
研究所博士論文,2000.
39. J.Aikens, J.A. Dix,“perhydroxyl Radical(Hoo˙)
initiated Lipid peroxidation”, J. Biol,Chem,266 ,pp91-
98,1991.
40.許樹恩,吳泰伯,“X光繞射原理與材料結構分析”,中國材料
科學學會,pp422,1996.
41.G. Colón, M.C. Hidalgo, J.A. Nav´ıo, “A novel
preparation of high surface area TiO2 nanoparticles
from alkoxide precursor and using active carbon as
additive”, Catalysis today,76,pp91-101,2002.
42.S.X. Liu , X.Y. Chen, X. Chen, “A TiO2/AC composite
photocatalyst with high activity and easy separation
prepared by a hydrothermal .
method”,J.Haza.Mate.,43,pp257–263,2007.