疏水修飾（hydrophobically modification）是一種提高分子應用性的技術。討論HMPNVF與各類型界面活性劑的交互作用，利用黏度、螢光光譜比較差異。PNVF僅與陰離子型界面活性劑（SDS）有交互作用的存在，探討HMPNVF主鏈與界面活性劑間交互作用對本文系統的影響。
由黏度與螢光光譜可知，相較於PNVF/SDS系統，HMPNVF/SDS有更強的作用發生。藉由疏水修飾，HMPNVF與CTAB、C12E7間有交互作用的存在。界面活性劑對疏水修飾高分子溶液黏度影響極大，藉由界面活性劑濃度以調控黏度高低。HMPNVF/SDS系統中，藉由黏度與[I1/I3]py值變化可知，黏度提升原因來自HMPNVF/SDS系統獨特的network-like association結構。比較不同類型界面活性劑系統，HMPNVF/CTAB系統的黏度提升效果最差。C12E7不具電荷的特性，令HMPNVF/C12E7系統在高界面活性劑濃度區內有大範圍的黏度提升現象。
本文中，藉由黏度、微極性（[I1/I3]py值）、Pyrene局部濃度（[IE/IM]py值）和微黏度（[IE/IM]DP值），研究界面活性劑於不同濃度疏水修飾高分子溶液的吸附機制。

Hydrophobically modification is a useful technology to raise polymer’s properties. In the research, the interaction of hydrophobically Poly(N-vinylformamide) (HMPNVF) with surfactants is studied by viscosity measurement and fluorescence techonology. The interaction between PNVF and Surfactants just happens in the PNVF/SDS system, so the effect of backbone of HMPNVF in the aggragative structure of HMPNVF/Surfactant solution is interesting.
By viscosity and fluorescence techonology, we find the HMPNVF/SDS system has the stronger interaction than PNVF/SDS system. The interaction of plymer with surfactant appears in HMPNVF/CTAB and HMPNVF/C12E7 systemms.
The viscosity of HMPNVF solution is affected and controlled by surfactants. In the low surfactant concentration region, ionic surfactants provide the remarkable viscosity enchancement which be caused by the unusual “netwok-like association” structure in HMPMVF/SDS system. The anionic surfactants’ (SDS) ability is greater than cationic surfactants’ (CTAB) in raising viscosity. Because nonionic surfactants don’t have electrostatic repulsive force, the tendency of viscosity enhancement continues for long range in the high C12E7 concentration region.
In the research, the binding mechisms of HMPNVF/surfactant systems is studied by viscosity, micropolarity ([I1/I3]py value), microviscosity (IM/IE]DP value), and pyrene local concentration ([IE/IM]py value).

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