| 研究生: |
林育昇 Lin, Yu-Sheng |
|---|---|
| 論文名稱: |
界面壓力對質子交換膜燃料電池堆之性能影響 Influence of Clamping Force on the Performance of PEMFC Stack |
| 指導教授: |
溫志湧
Wen, Chih-Yung |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 航空太空工程學系 Department of Aeronautics & Astronautics |
| 論文出版年: | 2008 |
| 畢業學年度: | 96 |
| 語文別: | 中文 |
| 論文頁數: | 66 |
| 中文關鍵詞: | 螺栓鎖附 、質子交換膜燃料電池堆 、界面壓力 |
| 外文關鍵詞: | PEMFC Stack, Clamping Pressure, Bolt-Clamping |
| 相關次數: | 點閱:88 下載:1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
現今燃料電池設計均著重於大面積與大電流的特點,當數個單電池組合而成燃料電池堆(Fuel Cell Stack)之後,組裝所帶來的影響性就比單電池更為複雜且重要。由於組裝的過程中有接觸阻抗,在燃料電池的效率上影響非常大,組裝壓力不夠會造成燃料漏氣、過高的接觸阻抗甚至電池損壞;但是,組裝壓力過大的話又會造成膜電極組的損傷。本研究中利用感壓軟片的可視化技術,來探討燃料電池堆的組裝過程中,膜電極組反應面積上與雙極板間接觸的界面壓力狀況,進而討論以傳統螺栓鎖附方式組裝,不同的螺栓組態和鎖附扭力,對於性能的影響。由實驗的結果中發現螺栓的組態與鎖附扭力所造成的均勻度會對性能有著很顯著的影響。這些實驗結論將提供未來設計燃料電池的依循。
Recently, there is a tendency toward larger reactive area and higher current in PEMFC stack design. The design of assembly of a PEMFC stack becomes much more complex and important than just a single cell. The assembly mechanism will affect the contact behavior between bipolar plates and membrane electrode assemblies (MEAs)and hence the performance of PEMFC stack. Inadequate clamping pressure may lead to leakage of fuels, high electric impedance and malfunction of the cells. On the other hand, excessive clamping pressure may destroy the MEA. This study is to study the PEMFC stack design and its clamping pressure distribution, using the pressure sensitive film (FUJI-FILM I&I) to measure the clamping pressure between the reactive area and the bipolar plates under different bolt-clamping configurations and different clamping forces. According to the experimental results, the stack performance and the pressure’s distribution is greatly influenced by the clamping force and the bolt configuration. The experimental results further our understanding of the effects of clamping conditions on the performance of a PEMFC.
[1]Von Spakovsky,M.R.,Nelson,D.J.,Ellis,M.W., Olsommer,B. and Ogburn,M.J.,“A Multi-/Inetr-Disciplinary Approach to Fuel Cell System Development: The U.S. DoEGATE Center for Automotive Fuel Cell Systems at Virginia Tech”,Society of Automotive Engineers,Vol. 1,1555,2000
[2]黃鎮江,“燃料電池”,第二版,全華科技圖書股份有限公司,pp 1-3-1-8
[3]http://www.plugpower.com/products/premium.cfm,2008
[4]http://pc.watch.impress.co.jp/docs/2003/0226/nanotech.htm,2003
[5]http://big5.nikkeibp.co.jp/china/news/news/200704/auto200704260126.html,2007
[6]http://www.apfct.com/3-Electric%20Scooter.htm,2002
[7]Z. Qi and A. Kaufman,“Activation of low temperature PEM fuel cells” ,Journal of Power Sources,Vol. 111,pp. 181-184,2002
[8]F. Barbir,H. Gorgun,X. Wang,“Relationship between pressure drop and cell resistance as a diagnostic tool for PEM fuel cells”,Journal of Power Sources,Vol. 141,pp. 96-101,2005
[9]D. Chu and R. Jiang,“Comparative studies of polymer electrolyte membrane fuel cell stack and single cell”, Journal of Power Sources,Vol. 80,pp.226-234,1999
[10]S. Shimpalee,S. Greenway,J. W. Van Zee,“The impact of channel path length on PEMFC flow-field design”,Journal of Power Sources,Vol. 160,pp. 398-406,2006
[11]S. Y. Kim,W. N. Kim,“Effect of cathode inlet manifold configuration on performance of 10-cell proton-exchange membrane fuel cell”,Journal of Power Sources,Vol. 166,pp. 430-434,2007
[12]US Fuel Cell Council,www.usfcc.com,2008
[13]V. Mishra,F. Yang,R. Pitchumani,“Measurement and prediction of electrical contact resistance between gas diffusion layers and bipolar plate for applications to PEM fuel cells”,Mem. ASME,Vol. 1,2004.
[14]W. K. Lee,C. H. Ho,J. W. Van Zee,M. Murthy,“The effects of compression and gas diffusion layers on the performance of a PEM fuel cell” ,Journal of Power Sources,Vol. 84,pp. 45-51,1999
[15]P. Zhou,C. W. Wu,G. J. Ma,“Influence of clamping force on the performance of PEMFCs”,Journal of Power Sources,Vol. 163,pp. 874-881,2007
[16]X. Wang,Y. Song,B. Zhang,“Experimental study on clamping pressure distribution in PEM fuel cell”,Journal of Power Sources,Vol. 179,pp. 305-309,2008
[17]C. H. Chien,C. W. Lin,S. C. Li,“Experimental study of assembly contact pressure of micro-fuel cell stack”,the XIth International Congress and Exposition,Society for Experimental Mechanics,2008
[18]W. R. Chang,J. J. Hwang,F. B. Weng,S. H. Chan,“Effect of clamping pressure on the performance of a PEM fuel cell”,Journal of Power Sources,Vol. 166,pp. 149-154,2007
[19] H. S. Chu,C. Yeh,F. Chen,“Effects of porosity change of gas diffuser on performance of proton exchange membrane fuel cell”,Journal of Power Sources,Vol. 123,pp. 1-9,2003
[20]S. J. Lee,C. D. Hsu,C. H. Huang,“Analyses of the fuel cell stack assembly pressure”,Journal of Power Sources,Vol. 145,pp. 353-361,2003
[21]P. Zhou,C. W. Wu,G. J. Ma,“Contact resistance prediction and structure optimization of bipolar plates”,Journal of Power Sources,Vol. 159,pp. 1115-1122,2006
[22]L. Zhang,Y. Liu,H. Song,S. Wang,Y. Zhou,S. J. Hu,“Estimation of contact resistance in proton exchange membrane fuel cells”,Journal of Power Sources,Vol. 162,pp. 1165-1171,2006
[23]Y. Yan,W. D. Wen,F. K. Chang,P. Shyprykevich,“Experimental study on clamping effects on the tensile strength of composite plates with a bolt-filled hole”,Composites,Part A,Vol. 30,pp. 1215-1229,1999
[24]I. Nitta,T. Hottinen,O. Himanen,M. Mikkola,“Inhomogeneous compression of PEMFC gas diffusion layer part I. experimental”,Journal of Power Sources,Vol. 171,pp. 26-36,2007
[25]I. Nitta,T. Hottinen,O. Himanen,M. Mikkola,“Inhomogeneous compression of PEMFC gas diffusion layer part II. modeling the effect”,Journal of Power Sources,Vol. 171,pp. 113-121,2007
[26]J. Ge,A. Higier,H. Liu,“Effects of gas diffusion layer compression on PEM fuel cell performance”,Journal of Power Sources,Vol. 171,pp. 113-121,2006
[27]鄭錕燦,邱耀輝,“質子交換膜燃料電池氣體擴散層及流道板電阻之探討”,中國機械工程學會第十八屆全國學術研討會論文集,第一冊 熱流與能源,pp. 529-534.,2001
[28]溫志湧、蔡秉蒼,黃國瑋,“質子交換膜燃料電池水氣生成觀測暨組裝界面壓力對性能之影響,中國機械工程學會第二十二屆全國學術研討會論文集,熱傳與能源工程,A8-020,2005
[29]蔡秉蒼,“質子交換膜燃料電池水氣生成觀測暨組裝界面壓力對性能之影響”,大葉大學機械與自動化工程學系碩士論文,2005
[30]http://www.fujifilm.co.jp/prescale/,2008