本論文應用雷射激發螢光技術於氫/空氣混合氣流經鉑觸媒平板，觸媒反應釋出OH自由基之量測，藉由OH-LIPF與溫度量測結果，配合二維觸媒平板流模擬，以分析鉑觸媒兩相反應機構。
本研究避免引發氣態燃燒，設定在三個不同流速（10、20與30cm/sec），當量比分別為0.32、0.28與0.26作為實驗條件；實驗溫度是以K-type熱電偶量測，並對熱輻射作修正。其結果顯示最高溫出現在平板前緣，平板表面溫度約1120K。經OH-LIPF量測半定量分析後，結果顯示OH濃度在近平板處最高，約5×1014 molecules/cc.，且遠離平板表面逐漸遞減。平板流模擬結果顯示，若不考慮兩相反應機構，OH濃度僅1012molecules/cc.，遠低於實驗量測結果，證實了非勻相反應機構兩相反應存在的可能性。
靈敏度分析的結果顯示，HO2*與HO2對於OH生成是一關鍵物種，降低OH+ Pt* → OH* 與OH+O*→HO2* 的反應速率常數可增加近表面OH濃度；增加HO2+H＝OH+OH的速率常數或降低HO2+OH＝H2O+O2的速率常數可延緩氣態OH粒子被消耗。由於觸媒反應屬於低溫反應，目前低溫下化學反應資料仍有不足，因此對於氣態OH濃度模擬仍有改進空間。

The existence of two-phase reactions on catalytic surface was investigated in this study. A laminar H2/air mixture flow parallel to a platinum flat plate system was designed to investigate the temperatures and OH distributions near the plate surface. Laser-Induced Predissociation Fluorescence (LIPF) technique was adopted to quantitatively analyze OH radical distributions. Gas-phase temperature profiles were measured by a K-type thermocouple with radiation correction. In conjunction with the experimental observations, a model to simulate the reacting flow over a thin flat plate was used to analyze the mechanism of the 2-D catalytic reactions.
In this study, in order to focus on catalytic reactions and to avoid the occurrence of ignition in gas-phase combustion, the equivalence ratios at mixture flow velocities of 10cm/sec, 20cm/sec, and 30cm/sec were set to be 0.32, 0.28, and 0.26, respectively. The experimental observations showed that the maximum surface temperatures at different experimental conditions occurred at the leading edge of the plate. A universal calibration constant, CF = (1.076±0.174)×1016molecules/cc showed in the literature, was used to quantify the OH concentrations. The measured OH concentrations near the plate surface were about 5×1014molecules/cc and decreased as the distance away from the plate surface. However, the calculated near-surface OH concentrations with the Deutschmann mechanism which included the catalytic surface reactions only were approximated to 1012molecules/cc. The analysis showed that the two-phase reactions should be included in the catalytic reaction mechanism.
Based on the “brute force” sensitivity analysis, HO2* and HO2 were the key species for OH production in the low-temperature catalytic reaction environment. By adjusting the sticking coefficients of the reactions OH+Pt*→OH* and OH+O*→HO2* in reacting flow simulations, near-surface OH could be significantly increased, and gas-phase OH depleted slower by increasing the rate constant of the reaction HO2+H→OH+OH or decreasing the rate constant of the reactionHO2+OH→H2O+O2. However, since the low-temperature kinetic data for those reactions are still unjustified, the validation of the results of this thesis research required further fundamental studies on chemical kinetics.

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