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研究生: 陳芷儀
Chen, Chih-I
論文名稱: 丙酮與水混合液的冷卻特性
Cooling Characteristics of Acetone and Water Mixtures
指導教授: 周榮華
Chou, Jung-Hua
學位類別: 碩士
Master
系所名稱: 工學院 - 工程科學系
Department of Engineering Science
論文出版年: 2026
畢業學年度: 114
語文別: 中文
論文頁數: 64
中文關鍵詞: CDS相變潛熱丙酮丙酮-水混合液
外文關鍵詞: CDS, phase transition, latent heat, acetone, acetone-water mixture
相關次數: 點閱:17下載:3
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  • 物理機制裡有一種「相變冷卻技術」,利用物質狀態改變時吸收潛熱的散熱方式,這種不需要能源驅動的被動冷卻方式,具備環保、高效率的優點,應可適用於高性能資料處理中心的機櫃伺服器的冷卻上。如何將冷卻分配系統 (Cooling Distribution System, CDS) 發揮節能效益,乃為研究的課題。
    本研究以機櫃伺服器發熱須冷卻的環境發想,選用丙酮與水混合液作為熱傳媒介。熱源是使用加熱平板,其實驗溫度設定為50 ℃、60 ℃、70 ℃及80 ℃,每個溫度階段的加熱時間為4分鐘。實驗混合液的體積合計為100ml或200ml。以100ml為例,若丙酮5ml則水溶液95ml,以不同濃度相同體積與不同溫度作為實驗參數。冷卻則使用TEC1-12710致冷晶片作降溫元件。觀察燒杯內丙酮與水混合液混合後,同時加熱冷卻的相變化 (Phase transition) 的熱傳現象。
    在實驗比例裡,以丙酮30ml+水溶液70ml為最佳曲線比例。以氣相溫度來看,加熱到達沸點溫度56 ℃前,溫度曲線平穩,在加熱60 ℃~70 ℃區間進入氣體轉變成液體的凝結放熱過程,開始升溫。以液體的相變溫度來看,在加熱50 ℃~60 ℃區間是氣化潛熱冷卻相變平台較為平穩,在加熱60 ℃~70 ℃區間進入相變潛熱現象溫度則緩慢爬升,以上是本次研究的最佳比例。

    The cooling technique by phase change utilizes the absorption of latent heat during the change in the state of matter. This passive cooling method is environmentally friendly and highly efficient, making it suitable for cooling servers in high-performance data centers. Therefore, maximizing the energy efficiency of the Cooling Distribution System (CDS) is essential for further development of AI related data centers.
    This study focuses on using an acetone-water mixture for liquid cooling applications. A heated plate was adopted as the heat source with the heating conditions set to constant temperatures of 50 °C, 60 °C, 70 °C, and 80 °C, respectively. The total volume of the experimental mixture was either 100ml or 200ml. For example, 100ml would consist of 5ml of acetone and 95ml of aqueous solution. Different concentrations at the same volume and different temperatures were used as experimental parameters. A TEC1-12710 cooling chip was used as the cooling element. The heat transfer phenomena were observed for their cooling analysis.
    Among the experimental ratios tested, the combination of 30 ml of acetone and 70 ml of water tends to give a better cooling performance. Regarding the gas-phase temperature above the liquid mixture, the temperatures remain stable until the boiling point of 56 °C of acetone is reached; as heating progressed to the 60°C–70°C range, the system enters into the exothermic condensation process of acetone, thus accompanying a rise in temperature. Regarding the liquid-phase transition temperature, a relatively stable plateau associated with the latent heat of vaporization cooling is observed between 50°C and 60°C, followed by a gradual temperature rise in the 60°C–70°C range as the sensible heat comes into play.

    摘要 I EXTENDED ABSTRACT II 目錄 VII 表目錄 IX 圖目錄 X 符號說明 XI 第一章 緒論 1 1.1前言 1 1.2研究動機與目的 2 1.3論文架構 3 第二章 文獻回顧 5 2.1相變化 (Phase change) 5 2.2氣液平衡 (Vapor–Liquid Equilibrium, VLE) 6 2.3混合液加熱 6 2.3.1理想氣體定律(Ideal Gas Law) 7 2.3.2比熱容公式(Specific Heat Capacity) 7 2.3.3潛熱公式(Latent Heat) 7 第三章 實驗方法 10 3.1 實驗材料 10 3.1.1丙酮 (Acetone) 10 3.1.2致冷晶片 11 3.1.3導熱、導冷裝置 11 3.1.4傳冷鐵片 12 3.1.5玻璃燒杯 13 3.1.6鋁箔隔熱棉 13 3.2儀器設備 14 3.2.1加熱平台 14 3.2.2溫度量測 15 3.2.3電源供應 17 3.3實驗流程 17 3.4實驗步驟 18 3.4.1實驗設計 19 3.4.3實驗安全注意事項 22 3.5實驗量測的重複性與CV值穩定度判定 23 第四章 結果與討論 24 4.1實驗數據-體積100ml (燒杯無隔熱) 24 4.2實驗數據-體積100ml (燒杯有隔熱) 30 4.3實驗數據之CV值解讀 34 4.4溫度變化曲線分析 34 4.4.1優化-體積增量200ml實驗數據 37 4.5 優化-增加比例之溫度變化曲線分析 39 4.6 相變化現象與熱力學關係 40 4.6.1體積100ml只加熱不致冷,實驗數據 40 4.7 實驗總結 44 第五章 結論與建議 47 5.1結論 47 5.2未來展望 47 參考文獻 48

    [1] Chen, Z., Yao, Y., Yuan, S., and Yin, H. Measurement of Critical Temperatures, Critical Pressures and Densities of Acetone–Water Solutions for Simulation. Journal of Solution Chemistry, 52, 1331-1351. 2023.
    [2] Shin, S., Kang, H., Kim, J. S., and Kang, H. Phase transitions of amorphous solid acetone in confined geometry investigated by reflection absorption infrared spectroscopy. The Journal of Physical Chemistry B, 118(47), 13349-13356. 2014.
    [3] Venables, D. S., and Schmuttenmaer, C. A. Spectroscopy and dynamics of mixtures of water with acetone, acetonitrile, and methanol. Journal of Chemical Physics, 113(24), 11222-11230. 2000.
    [4] Pereyra, R. G., Asar, M. L., and Carignano, M. A. The role of acetone dipole moment in acetone-water mixture. Chemical Physics Letters, 507(4-6), 240-243. 2011.
    [5] Thomsen, K., Olsen, M. D., and Correa, L. F. F. Modeling vapor-liquid-solid equilibrium for acetone-water-salt systems. Pure and Applied Chemistry, 92(10), 1663-1672. 2020.
    [6] Selvam, D. C., Devarajan, Y., Beemkumar, N., Bhanot, D., Acharya, S. K., Sukhdev, A., and Agrawal, T. Advances in nano-enhanced phase change materials and hybrid thermal energy storage systems: Paving the way for sustainable energy solutions. Results in Engineering, 105729. 2025.
    [7] Fredenslund, A., Jones, R. L., and Prausnitz, J. M. Group-contribution estimation of activity coefficients in nonideal liquid mixtures: UNIQUAC model. AIChE Journal, 21, 1086-1098. 1975.
    [8] Polednová, J., and Wichterle, I. Vapour–liquid equilibrium in the acetone–water system at 101.325 kPa. Fluid Phase Equilibria, 17(1), 115–121. 1984.
    [9] Sachin, I., Manojkumar, M. S., and Sivaprakash, B. Vapour liquid equilibrium model testing based on activity coefficient models applied to binary azeotropic systems. International Journal of ChemTech Research, 11(1), 362–376. 2018.
    [10] Meriluoto, A., Kulmala, H., and Kontogeorgis, G. M. Vapor–liquid azeotropic systems and liquid–liquid equilibrium calculations using UNIFAC and NRTL-SAC activity coefficient models. Fluid Phase Equilibria, 494, 33-44. 2019.
    [11] Joshi, A. B., and Patil, D. J. Prediction of VLE for binary azeotropes using activity coefficient models. International Journal of Innovative Technology and Exploring Engineering, 8(12S2), 340–345. 2019.
    [12] Makwana, R., and Solanki, D. VLE prediction of azeotropic systems using UNIQUAC and UNIFAC. Makhil Research Journal of Applied Science, 1(3), 216–224. 2018.
    [13] Camacho, A., and Sandler, S. I. Thermodynamic modeling of vapor–liquid equilibria using the NRTL equation. Industrial and Engineering Chemistry Research, 33(10), 2373–2383. 1994.
    [14] Brouwer, T., and Prausnitz, J. M. Activity coefficients in nonideal mixtures. Chemical Engineering Science, 39(4), 571–580. 1984.
    [15] Nicholson, D. E. Integral heats of mixing of water and acetone at 90 °C. Journal of Chemical and Engineering Data, 5(3), 309–312. 1960.
    [16] Malhotra, R., and Woolf, L. A. Thermodynamic properties of propanone (acetone) at 278–323 K and up to 400 MPa. Journal of Chemical Thermodynamics, 23(9), 873–879. 1991.
    [17] Saluja, P. P. S., Peacock, T. D., and Fuchs, R. Enthalpies of interaction of aliphatic ketones with polar and nonpolar solvents. Journal of the American Chemical Society, 101(15), 4350–4354. 1979.
    [18] Yang, T., Sandler, S. I., and Reid, R. C. Thermodynamic excess functions from experimental data. AIChE Journal, 32(9), 1464–1472. 1986.
    [19] Kato, Y., and Mori, Y. H. Molar enthalpy increments for (water + acetone) mixtures at elevated temperatures. The Journal of Physical Chemistry B, 104(2), 324–329. 2000.
    [20] Kelley, G. S., and Patterson, D. Heat capacities of water + organic-solvent mixtures. Journal of the Chemical Society, Faraday Transactions 1, 81(3), 635–641. 1985.
    [21] Coomber, B. A., and Wormald, C. J. A stirred flow calorimeter for the excess enthalpies of acetone + water and of acetone + some normal alcohols from methanol to hexan-1-ol. The Journal of Chemical Thermodynamics, 8(6), 537–544. 1976.
    [22] Egorov, G. I., Voloshin, D. G., and Prikhod’ko, T. M., Volume expansion coefficients of the water-acetone system at temperatures of 278-323K and pressures up to 1000 bar. Russian Journal of Physical Chemistry A, 81(10), 1690-1694. 2007.
    [23] Montgomery, D. C. John Wiley and Sons. Design and analysis of experiments (9th ed.). 2017.
    [24] 林郁智,產品與量測人員有交互作用存在下之量測重複性與再現性分析,碩士論文,台南,2005.
    [25] Bell, S. (1999). A beginner’s guide to uncertainty of measurement (Measurement Good Practice Guide No. 11, Issue 2). National Physical Laboratory.
    [26] ISO (2025). Accuracy (trueness and precision) of measurement methods and results-Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method (ISO Standard No. 5725-2:2025). International Organization for Standardization.
    [27] Oh, H., Jin, W., Peng, P., Winick, J., Sickinger, D., Sartor, D., Zhang, Y., Beckers, K., Kitz, K., Acero-Allard, D., Atkinson, T., and Dobson, P. Techno-economic performance of reservoir themal energy storage for data center cooling system. Applied Energy, 391, Article 125858. 2025.
    [28] Cai, S., and Gou, Z. Towards energy-efficient data centers: A comprehensive review of passive and active cooling strategies. Energy and Built Environment, 7(2). 2024
    [29] Liu, L., X., Li, Y., and Zhang, S. Multi-time scale optimization scheduling of data center considering workload shift and refrigeration regulation. Energy Engineering, 123(2), 65668. 2026.
    [30] Zhang, C., Li, M., Chen, X., Dang, C., Li, X., and Han, Z. Dual evaporating temperature steam generation heat pump system for waste heat recovery of air-liquid hybrid cooling data center. Energy Conversion and Management, 353, Article 121199. 2026.
    [31] Safari, A., and Blaabjerg, F. A research-industry perspective of battery systems technology for next-generation data centers. Journal of Energy Storage, 152, 1220386. 2026.
    [32] 致冷晶片。https://tw.shp.ee/ryXA4edB。
    [33] 導熱、導冷裝置。https://tw.shp.ee/Sh1yzh7d。
    [34] 玻璃燒杯。https://tw.shp.ee/SQsfoWEm。
    [35] 鋁箔隔熱棉。https://tw.shp.ee/C1jGkQdz。
    [36] 加熱台。https://tw.shp.ee/XYaFGkTw。
    [37] 防水感應溫度計。https://tw.shp.ee/jSUnuHKa。
    [38] 針式溫度計。https://tw.shp.ee/M2Ym1f9L。
    [39] 紅外線溫度槍。https://tw.shp.ee/6jPjoQbQ。
    [40] 電源供應器。https://tw.shp.ee/MErNWM8K。
    [41] 散熱膏。https://tw.shp.ee/cbmfymye。

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