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研究生: 李育荏
Li, Yu-Ren
論文名稱: 高溫超導線材金屬保護層蝕刻與檢測技術研究
Study of Etching of Metallical Stabilizer Layer and Characterization of High Temperature Superconducting Tapes
指導教授: 陳引幹
Chen, In-Gann
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學及工程學系
Department of Materials Science and Engineering
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 72
中文關鍵詞: 超導線材蝕刻超導線材接合臨界電流量測機械接合法
外文關鍵詞: superconductor tape etching, superconductor joining, critical current measurement, mechanical joining
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  • 高溫超導線材(HTS)具有應用於MRI、NMR或磁浮列車等高磁場線圈的潛力,而目前所能製備的線材長度不足以直接使用,因此需要先發展線材接合技術,方能得到足夠的使用長度。發展零電阻超導線材接合技術可以降低接合後電流的損耗,為了達到接合後的電阻為零,需要先將線材表層的銅保護層及銀保護層去除,使線材超導層露出,以便後續的接合製程。
    為了使線材超導層順利露出,需要透過蝕刻法移除線材保護層,且在蝕刻過程中需要避免影響到線材的超導性質。為了蝕刻線材銅保護層,使用30wt%氯化鐵溶液作為蝕刻劑,為了避免氯化鐵溶液影響到線材邊緣而影響到線材性質,因此在實驗中以Kapton膠帶將線材不欲蝕刻區保護,將蝕刻區域限制在需要的範圍,最終在將銅保護層蝕刻後,線材仍可保留原本60%的臨界電流。除了銅保護層外,在超導層上還殘留銀保護層,銀蝕刻液以NH4OH及H2O2以1:1比例混合,可以順利將銀層去除,且對線材臨界電流影響小。
    為了確認線材在經過蝕刻及接合後的臨界電流變化,以四點量測方法測量線材V-I曲線,由於四點量測是輸出電流到線材並量測線材上特定距離(實驗中以5公分)的電壓,直到臨界電壓標準1μV/cm,而該臨界電壓所對應到的電流即臨界電流。
    當線材超導層順利露出後,我們藉由機械接合法,直接以機械應力將線材超導層相互接觸在一起,使得線材接點位置僅超導層存在,不含其他材料,預期當溫度低於超導線材臨界溫度(約90K)時,接點附近電阻為零。然而實際上在接合後電阻並非為零,目前的推測是在77K時,壓力並不足以大到使線材能夠完全接觸在一起,而是會有大於超導層相干長度(0.1奈米)空隙存在,因此接合電阻不為零。

    The superconductor tape length that can be prepared at present is not enough for direct application, so it is necessary to develop joining technology to obtain a sufficient length for use. The development of zero-resistance superconducting tape joining technology can reduce the current loss after joining. In order to achieve zero resistance after joining, it is necessary to remove the copper stabilizer and silver stabilizer on the surface of the tape to expose the tape superconducting layer.
    In order to etch the copper stabilization layer of the strip, 30wt% ferric chloride solution was used as the copper etchant. In order to prevent the ferric chloride solution from affecting the side of the tape and affecting the properties of the tape, in the experiment, Kapton tape was used to protect the side of the tape. In addition to the copper stabilizer, there is a silver stabilizer remaining on the superconducting layer. The silver etching solution is mixed with NH4OH and H2O2 in a ratio of 1:1.In order to confirm the critical current change of the tape after etching and joining, the V-I curve of the tape was measured by the four-point measurement method.
    When the superconducting layer was exposed, we used mechanical joining to directly contact the superconducting layer with mechanical stress, so that only the superconducting layer exists at the contact point of the strip without other materials.

    摘要 I 致謝 V 目錄 VII 表目錄 IX 圖目錄 IX 第一章 緒論 1 1-1 前言 1 1-2 銅氧系超導體之應用 2 1-3 研究目的 2 第二章 理論基礎與文獻回顧 4 2-1 超導體發展歷程及相關理論 4 2-1.1 超導體的發現及發展歷史 4 2-1.2 超導體的基本性質[12] 5 2-1.3 超導體的基礎及相關理論[12] 8 2-2 Y-Ba-Cu-O超導線材 10 2-2.1 Y-Ba-Cu-O晶體結構與性質 10 2-2.2 Y-Ba-Cu-O超導線材(2G HTS)組成與製備 12 2-2.3 Y-Ba-Cu-O超導線材應用 15 2-3 超導線材接合 18 2-3.1 Solder joint【37】 18 2-3.2 Diffusion joint【38】 20 2-3.3 Superconductor joint 21 第三章 實驗方法及步驟 28 3-1 實驗流程 28 3-1.1 線材邊緣保護步驟 29 3-1.2 蝕刻線材 31 3-1.3 超導臨界電流量測(四點量測步驟) 32 3-1.4 模具修改 37 3-1.5 線材機械接合 42 第四章 實驗結果與討論 45 4-1 超導臨界電流量測結果 45 4-1.1 臨界電流量測方式 45 4-1.2 臨界電流量測結果 47 4-2超導線材處理 48 4-2.1超導線材蝕刻後臨界電流量測 49 4-2.2 線材剪除前後臨界電流變化 54 4-3機械接合結果 58 4-3.1 彈簧彈性係數量測 58 4-3.2 接合結果 59 第五章 結論 67 參考資料 68

    [1] J. G. Bednorz and K. A. Müller, "Possible highTc superconductivity in the
    Ba−La−Cu−O system," Zeitschrift für Physik B Condensed Matter, journal
    article vol. 64, no. 2(1986),189-193.
    [2] M. K. Wu et al., "Superconductivity at 93 K in a new mixed-phase
    Y-Ba-Cu-O compound system at ambient pressure," Physical Review Letters,
    vol. 58, no. 9(1987), 908-910
    [3] Y.Arai et al "Development of superconducting magnetic bearing with superconducting coil and bulk superconductor for flywheel energy storage system" Physica C: Superconductivity Volume 494, 15 November 2013, Pages 250-254
    [4] O.Tønnesen et al " Power applications for superconducting cables " Supercond. Sci. Technol. 13 (2000) 506–509
    [5] Y. Hatsukade et al. "Application of Ultra-Low Field HTS-SQUID NMR/MRI to Conation Detection in Food"IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, VOL.23(2013), NO.3 1602204
    [6] HTS Development and Industrialization at SuNAM
    [7] Yanagisawa Y et al" Operation of a 400 MHz NMR magnet using a
    (RE:Rare Earth)Ba2Cu3O7-x hightemperature superconducting coil: Towards
    an ultra-compact super-high field NMR spectrometer operated beyond 1 GHz"
    J. Mag. Reson. 249(2014) 38–48
    [8] Liu J, Cheng J and Wang Q" Evaluation of NbTi superconducting joints
    for 400 MHz NMR magnet" IEEE Trans. Appl. Supercond. 23(2013) 34–9
    [9] Daniela P Boso1,3 and Marek Lefik" A thermo-mechanical model for Nb3Sn
    filaments and wires: strain field for different strand layouts" Supercond. Sci.
    Technol. 22 (2009) 125016
    [10] Dirk van Delft and Peter Kes "The discovery of superconductivity"
    September 2010 Physics Today, p38~p43
    [11] M. . Cyrot. and D. Pavuna, "Introduction to Superconductivity and High-Tc
    Materials," World Scientific 1992,1-21
    [12] Yeekin Tsui, Elizabeth Surrey and Damian Hampshire "Soldered joints—an
    essential component of demountable high temperature superconducting fusion
    magnets"Supercond. Sci. Technol. 29 (2016) 075005
    [13] A. E. Yuh Shiohara, "Crystal growth of bulk high-Tc superconducting oxide
    materials," Materials Science and Engineering, vol. 19(1997), no. 1-2,1-86
    [14] Y. Zhao, et al "Flux pinning by NiO-induced nano-pinning centres in melt-textured YBCO superconductor," (in English), Superconductor Science & Technology, Article; Proceedings Paper vol. 18(2005), no. 2,S43-S46.
    [15] Q. Li et al., "INTERLAYER COUPLING EFFECT IN HIGH-TC
    SUPERCONDUCTORS PROBED BY YBa2Cu3O7-X/PRBA2CU3O7-X
    SUPERLATTICES," Physical Review Letters, Article vol. 64
    (1990), no. 25,3086-3089
    [16] 《科學發展》2013 年 6 月,486 期,40 ~ 46 頁
    [17] Juan Bascunan et al., "On the 600 MHz HTS Insert for a 1.3 GHz NMR
    Magnet" IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY,
    VOL. 22(2012), NO. 3, 4302104
    [18] T Nakane et al, "Fabrication of Cu-sheathed MgB2 wire with high Jc–B performance using a mixture of in situ and ex situ PIT techniques". Physica C:Superconductivity. 469(2009), vol.15–20: 1531–1535
    [19] V.Selvamanickam et al., " Progress in second-generation HTS wire
    development and manufacturing" Physica C 468 (2008) 1504–1509
    [20] H Kutami et al,"Progress in research and development on long length coated conductors in Fujikura" Physica C, Volume 469(2009),
    Issues 15–20, 15,1290-1293
    [21] Selvamanickam V et al, "High Performance 2G Wires: From R&D to
    Pilot-Scale Manufacturing " IEEE Trans. Appl. Supercond. 19(2009) 3225–30
    [22] Rupich M W et al "Advances in second generation high temperature
    superconducting wire manufacturing and R&D at American Superconductor
    Corporation" Supercond. Sci. Technol. 23(2010) 014015
    [23] J H Lee et al "RCE-DR, a novel process for coated conductor fabrication with
    high performance" Supercond. Sci. Technol. 27 (2014) 044018
    [24] W.T. Wang et al “High performance fluorine-free MOD YBa2Cu3O7-z film preparation by partial melting process” Journal of Alloys and Compounds 513 (2012) 610–614
    [25] http://www.amsc.com/solutions-products/hts_wire.html(AMSC公司官網)
    [26] http://www.superpower-inc.com/content/2g-hts-wire(Superpower公司官網)
    [27] Y. Hyuck Choi et al "Quench and Recovery Characteristics of
    the Zr-Doped (Gd,Y) BCO Coated Conductor Pancake Coils Insulated With
    Copper and Kapton Tapes "IEEE Trans. Appl. Supercond.. 21(2011), NO. 3,, 2415– 2419
    [28] 《Chemistry World》2008 年 2 月,46~47 頁
    [29] http://www.mat-test.com/Post/Details/PT151124000046A7D0G
    [30] S Iguchi et al. "Advanced field shimming technology to reduce the influence
    101 of a screening current in a REBCO coil for a high-resolution NMR magnet" Supercond. Sci. Technol. 29 (2016) 045013

    [31] Yuri Lvovsky et al "Novel technologies and configurations of superconducting magnets for MRI" Supercond. Sci. Technol. 26 (2013) 093001
    [32] Philip C. Michael et al "A REBCO Persistent-Current Switch (PCS): Test
    Results and Switch Heater Performance " IEEE Trans. Appl. Supercond. 27(2017) 0500705
    [33] Yanagisawa Y et al" Operation of a 400 MHz NMR magnet using a (RE:Rare Earth)Ba2Cu3O7-x hightemperature superconducting coil: Towards an ultra-compact super-high field NMR spectrometer operated beyond 1 GHz"
    J. Mag. Reson. 249(2014) 38–48
    [34] Yeekin Tsui, Elizabeth Surrey and Damian Hampshire "Soldered joints-an essential component of demountable high temperature superconducting fusion
    [35] J.Y.Kato "Diffusion joint of YBCO coated conductors using stabilizing silver layers" Physica C 445–448 (2006) 686–688
    [36] Yeonjoo Park et al "A superconducting joint for GdBa2Cu3O7 d-coated conductors" NPG Asia Mater. 6 e98
    [37] Xinzhe Jin et al"Development of a superconducting joint between a GdBa2Cu3O7-δ-coated conductor and YBa2Cu3O7−δ bulk: towards a superconducting joint between RE (Rare Earth) Ba2Cu3O7−δ-coated conductors"Supercond. Sci. Technol. 28 (2015) 075010
    [38] Yutaro Seinoet et al"Joint Resistance Characteristics of Mechanical LapJoint of a GdBCO Tape With a Change in Temperature and Magnetic Field"IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, VOL. 24, NO. 3, JUNE 2014
    [39] J.W Lee et al"Stability phase diagram of GdBa2Cu3O7-x in low oxygen pressures" Journal of Alloys and Compounds 602 (2014) 78–86
    [40] 歐陽天” 新穎二代高溫超導線材接合技術研究與性質量測”(Study of Novel 2G High Temperature Superconducting Tape Joint Method and Joint Property Analysis) 2018

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