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研究生: 馬哈
Maharjan, Sumit
論文名稱: 優化生質燃油以改善生命週期碳排放與節能評估之分析
Oil Upgrading for Improving Life Cycle Emission and Energy Assessment of Biomass Derived Fuel
指導教授: 王偉成
Wang, Wei-Cheng
學位類別: 碩士
Master
系所名稱: 工學院 - 航空太空工程學系
Department of Aeronautics & Astronautics
論文出版年: 2015
畢業學年度: 103
語文別: 英文
論文頁數: 57
中文關鍵詞: Life-Cycle AssessmentPalm biodieselGlobal warming potentialCumulative energy demandLand-use changePayback timeGreen DieselHydrotreatingHydrodeoxygenation
外文關鍵詞: Life-Cycle Assessment, Palm biodiesel, Global warming potential, Cumulative energy demand, Land-use change, Payback time, Green Diesel, Hydrotreating, Hydrodeoxygenation
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  • Palm biodiesel is widely considered as an environmental-friendly alternative to conventional diesel due to its capacity of carbon capture in plantation life-cycle phase. In Taiwan, due to the limited capacity of waste cooking oil, palm oil has been viewed as the potential low cost imported feedstock for producing biodiesel, which is obtains the oil feedstock in Malaysia and produces biodiesel in Taiwan. However, the impact of land-use change impact such as deforestation, and the characteristic of relatively lower-energy in combustion phase, are often neglected. This study aims to evaluate the cradle-to-grave life-cycle environmental performance of palm biodiesel. Phases in the life-cycle such as land- use change, plantation and milling for the Malaysia case and refining and fuel producing as well as engine combustion for the Taiwan case are investigated. The greenhouse gas (GHG) emission and energy consumption for the whole life-cycle are calculated as -28.29 kg CO2-equiv. and -23.71 MJ per kg of palm derived biodiesel. The payback time for using biodiesel is 14 and 95 years for rainforest and peat-forest cases, respectively. The GHG emission and payback time can further be reduced by adapting advanced oil-upgrading technologies like hydrotreating. Green diesel produced via hydrotreating has higher calorific value of 44 MJ/kg, higher cetane number 70-90 and lower CO2 emission compared to biodiesel produced via transesterification which has lower calorific value of 39.36 MJ/kg, lower cetane number of 65 and has higher carbon emission. For this reason, hydrotreating as an oil upgrading process has been adapted in this study to produce the green diesel.

    ABSTRACT i ACKNOWLEDGEMENT iii CONTENTS iv LIST OF TABLES vi LIST OF FIGURES vii ABBREVIATIONS viii CHAPTER I INTRODUCTION 1 1.1 Life Cycle Assessment of Palm Biodiesel 1 1.2 Upgrading Crude Palm Oil to Produce Green Diesel via Hydrotreating 4 CHAPTER II METHODOLOY 7 2.1 Life Cycle Analysis 7 2.2 Goal and Scope Definition 8 2.3 System Boundary 9 2.4 Inventory Analysis 9 2.4.1 Land-use change 10 2.4.2 Plantation 10 2.4.3 Milling 12 2.4.4 Refining and Transesterification 12 2.4.5 Combustion 13 CHAPTER III EXPERIMENTAL 14 3.1 Experimental setup 14 3.2 Experimental Procedure 16 CHAPTER IV RESULT AND DISCUSSION 18 4.1 Life Cycle Assessment of Palm Biodiesel 18 4.1.1 Life cycle phase’s contribution 18 4.1.2 Hotspots of GWP 24 4.1.3 GHG Payback time 26 4.2 Upgrading Crude Palm Oil to Produce Green Diesel via Hydrotreating 30 4.2.1 Sample products with different operating conditions 30 4.2.2 Number of carbons analyzed via GC-MS 32 CHAPTER VI CONCLUSION AND FUTURE TASKS 34 REFERENCES 37 APPENDIX 41

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