簡易檢索 / 詳目顯示

研究生: 萬乃容
Wan, Nai-Jung
論文名稱: 雙殼貝殼體化學元素及穩定碳氧同位素訊號所示之環境變遷意義
Geochemical and Isotopic Study of Bivalve Shells
指導教授: 游鎮烽
You, Chen-Feng
學位類別: 碩士
Master
系所名稱: 理學院 - 地球科學系
Department of Earth Sciences
論文出版年: 2004
畢業學年度: 92
語文別: 中文
論文頁數: 58
中文關鍵詞: 同位素貝殼地球化學
外文關鍵詞: Geochemistrt, Shell, Isotope
相關次數: 點閱:117下載:5
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 摘要
    利用碳氧同位素、元素比值以及鍶同位素分析採自華北平原3000年前的淡水雙殼貝Arconaia lanceolata,我們獲得殼體年際尺度以下高解析度地球化學訊號。殼體元素比值有強烈周期變化,配合δ13C資料能對貝殼的年際做明確的標定。Mg/Ca、Al/Ca、Sr/Ca、Ba/Ca比值紀錄了乾、濕季節河水化學對於諸如降雨、洪汛及沙塵暴等天氣現象的反應訊號。87/86Sr變化顯示河水的沉積物來源除了因季節性的變動外(0.7120 ~ 0.7115),尚有另一來自系統外因洪水氾濫或者水道改變帶來的沉積物來源( ~ 0.7095)。A. lanceolat殼體生長紋紀錄每年有兩次碳酸鈣停止分泌現象分別由於夏季河水濁度提高及冬季河溫過低產生的。

    Abstract
    Biogenic carbonates provide important information for a better understanding of environmental changes in the past. A large fossil aragonitic fresh-water bivalve, Arconaia lanceolata, collected from Lao Heto, Hebei, PRC, has been used widely as a climatic recorder in lake basin. The dating result is 3028 years ( U-Th dating, TIMS). We analyze the shell skeleton with δ13C&δ18O, elements/calcium ratios and 87Sr/86Sr ratios individually by IRMS, LA-ICPMS and TIMS.
    There is a strong correlation between elements/calcium ratios and growth band series. It suggests that some environmental factors influences between the shell annual physiological rotations and elements concentration variations in the river in similar trends. Observing the last several years elements/calcium ratio records, the mean are increased and the oscillation transition becomes rapid and huge, because of the ripe process of the shell metabolic variations.
    In annual scale, the importance of δ18O variations in the river is more controlled by precipitation effect than temperature effect in monsoon climate. And there is a same δ18O variable margin trend between in river and in rainfall when the wet-dry seasons change. So the situation is controlled by summer and winter monsoon changes. Still some δ18O records distribute near 0 ‰, and it suggests there would be a sea-source to influent the variations.
    Most 87Sr/86Sr ratio records indicate that the heavier 87Sr/86Sr ratio sediments in the shell are from terrigenous source. The 87Sr/86Sr ratio variations in the shell are controlled by flux and sediment transition in the river and rainfall. Beside this mix effects in the river, like the sea-source δ18O oscillation, some 87Sr/86Sr ratio records in the shell present a near sea-source average ratios. It proves that the shell growth water mass results from sea water mass or mass of sea water mixing with river water.
    We communicate with isotope and elements/calcium ratio records and growth band series on the growth time axis. Shell skeleton has several information; 1.wet and dry seasons exchange in annual like present; 2.great quantity and rapid rainfall on wet season results in bringing terrigenous source sediments to the river; 3.there are two growth bands on annual develop, light and grey bands individually represent of growth stop by temperature and turbidity; 4.water mass between sea-source and none-sea-source on annual scale; 5.Sr/Ca ratio records could be use to define the annual band on shell skeleton; 6.prat of factors of trace elements distribution on shell skeleton controlled by metabolic effects.

    目錄 第一章、緒論 1 1.1 前言 1 1.2 雙殼貝( Bivalve )及其研究 5 1.3 研究目的 9 第二章、研究背景 10 2.1 Arconaia lanceolata概述 10 2.2全新世華北平原 13 第三章、分析原理及方法 14 3.1 X光粉末繞射分析法 14 3.2 感應耦合電漿質譜分析法 16 3.3熱離子源質譜分析法 20 3.4 鈾系(Uranium Series)定年法 21 3.5 樣品前處理 23 3.5.1 前處理及採樣 23 3.5.2 U-Th定年前處理 25 3.5.3 鍶同位素分析前處理 26 3.6 X光粉末繞射分析 28 3.7感應耦合電漿質譜儀(ICP-MS)分析 29 3.7.1 Element / Calcium Ratios 29 3.7.2 U - Th定年分析 31 3.8 鍶同位素分析 32 3.9 氣體比值型質譜儀(IRMS)分析 33 第四章、結果 34 4.1 X光粉末繞射分析 34 4.2穩定碳氧同位素 35 4.3 Element/Calcium Ratios 37 4.4 鍶同位素 40 4.5定年 41 第五章、討論 42 5.1 年際界定 42 5.2 地球化學紀錄與季節性或者氣候訊號間的關連性 46 5.3 殼體生長紋與貝殼生命週期效應(Vital Effects) 49 第六章、結論 53 參考文獻 54

    參考文獻
    中文書籍
    于津生,中國同位素地球化學研究,科學出版社,北京,共621頁,1997。
    任淑仙,無脊椎動物學(上冊),淑馨出版社,台北,共383頁,1995。
    江旭楨、楊惠珍,質譜分析術專輯,行政院國家科學委員會精密儀器發展中心,台北,共390頁,1992。
    李孟達,高解析度雷射剝蝕電漿質譜儀在精確測量自然標本微量元素/鈣比值上的應用,中國地質學會九十一年年會暨學術研討會論文集,台北, 318-319頁,2002。
    巫文隆,CITES珍稀貝類研究參考圖冊,行政院農業委員會,台北,共133頁,1997。
    何心一、徐桂榮等,古生物學教程,地質出版社,北京,共255頁,1993。
    杜桓儉、陳華慧、曹伯勛,地貌學及第四紀地質學,地質出版社,北京,共374頁,1981。
    沈川洲,高精度之鍶鈣比值分析及其在環境上的應用。國立清華大學化學研究所博士論文,新竹,共187頁,1996。
    陳佩娟、楊錫賢、紀子文,沙塵暴懸浮微粒與硝酸鹽關係研究,沙塵暴學術研討會論文集,台北,130-151頁,2002。
    陳鎮東,南海海洋學,渤海堂文化公司,台北,2001。
    曹家欣,第四紀地質,商務印書館,北京,1983。
    黃怡禎 譯,礦物學,地球科學文教基金會,台北,共689頁,2000。
    鄭妙靜,台南、台中及彭家嶼雨水的化學成分探討,中國地質學會九十二年年會暨學術研討會論文集,台北,165頁,2003。
    魏國彥、許晃雄,全球環境變遷導論,教育部環境保護小組,台北,共378頁,1997。
    鍾小良,二仁溪河水地球化學和同位素初探,國立成功大學地球科學所碩士論文,台南,共85頁,2002。

    中文期刊
    何勇、楊杰東,現代硨磲殼體鍶同位素與其生活環境的關係,海洋地質與第四紀地質,第20卷,第1期,2000。
    莊啟謙,西沙群島的硨磲科軟體動物,海洋科學集刊,第12期,1978。
    扈治安,鈾系(Uranium Series)定年法,地質,第16卷,第1-2期,113~114頁,1997。
    楊守業,長江與黃河沉積物元素組成及地質背景,海洋地質與第四紀地質,第19卷,第2期,1999。

    英文書籍
    Fadini, A and Schnepal, F. M. , Vibrational Spectroscopy-Methods and Applications, Ellis Horwood Limited, England, pp. 205, 1989.
    Goodess, C. M. and Palutikof, J. P. and Davies, T. D., The Nature and Causes of Climate Change, Belhaven Press , Londin , 1992.
    Ruddiman, William F. , Earth’s Climate Past and Future , W. H. Freeman and Company, New York , 2001.
    Taylor, H. E. , Inductively Coupled Plasma-Mass Spectrometry Practices and Techniques, Academic Press, Florida, 2001.

    英文期刊文獻
    Cole, J. J. and Caraco, N.F. and Kling, G..W. and Katz, T.K., Carbon dioxide supersaturation in the surface waters of lakes, Science, Vol. 265, pp. 1568-1570, 1994.
    Dettman, D. L. and Reische, A. K. and Lohmann, K. C., Control on the stable isotope composition of seasonal growth bands in aragonitic fresh-water bivalves (unionidae), Geochimica et Cosmochimica Acta, Vol. 63, No. 7/8, pp. 1049-1057, 1999.
    Epstein, S. and Buchsbaum, R. and Lowenstam, H. A. and Urey, H. C., Carbonate-water isotopic temperature scale, Geological Society of America Bulletin, Vol. 62, pp. 417-425, 1951.
    Hong Wang and Keppens, E. and Nielsen, P. and Riet, A. , Oxygen and carbon isotope study of the Holocene oyster reefs and paleoenvironmental reconstruction on the northwest coast of Bohai Bay, China, Marine Geology, Vol.124, pp. 289-302, 1995.
    Hendry, J. P. and Perkins, W. T. and Bane T., Short-term environmental change in a Jurassic lagoon deduced from geochemical trends in aragonite bivalve shells, Geological Society of America Bulletin, Vol. 113, No. 6, pp. 790-798, 2001.
    Kaandorp R. J. G. and Vonhof, H. B. and Busto, C. D. and Wesselingh, F. P. and Ganssen, G. M. and Marmól, A. E. and Pittman, L. R. and Hinte, J. E., Seasonal stable isotope variations of the modern Amazonian freshwater bivalve Anodontites trapesialis, Palaeogeography Palaeoclimatology Palaeoecology, Vol. 194, pp. 339-354, 2003.
    Klein, R. T. and Lohmann, K. C. and Thayer, C. W., Bivalve skeletons record sea-surface temperature and δ18O via Mg/Ca and 18O/16O ratios, Geology, Vol. 24, No. 5, pp. 415-418, 1996.
    Krantz, D. E. and Williams, D. F. and Jones, D. S., Ecological and Paleoenvironmenyal Information Using Stable Isotope Profiles from Living and Fossil Molluscs, Palaeogeography Palaeoclimatology Palaeoecology, Vol. 58, pp. 249-266, 1987.
    McMillian, P.F., Vibrational Spectroscopy in the mineral sciences, Mineral. Soc. of Am., Vol. 14, pp. 9-63, 1985.
    Peng Zicheng and Chen Tegu and Nie Baofu and Head, M. J. and He Xuexian and Zhou Weijian, Coral δ18O records as an indicator of winter monsoon intensity in the South China Sea, Quaternary Research, Vol. 59, pp. 285-292. 2003.
    Purton, L. M. A. and Shields, G. A. and Brasier, M. D. and Grime, G. W., Metabolism controls Sr/Ca ratios in fossil aragonitic mollusks, Geology, Vol. 27, No. 12, pp. 1083-1086, 1999.
    Savazzi, E. and Yao, P. , Some morphological adaptations in freshwater bivalves, Lethaia, Vol. 25, pp. 195-209, 1992.
    Stecher, H. A. and Krantz, D. E. and Lord, C.J. and Luther, G. W. and Bock, K. W., Profiles of strontium and barium in Mercenaria mercenaria and Spisula solidissima shells, Geochimica et Cosmochimica Acta, Vol. 60, pp. 3445-3456, 1996.
    Wang Hongya and Liu Hongyan and Cui Haiting and Abrahamsen, N. , Terminal Pleistocene-Holocene palaeoenvironmental changes revealed by mineral-magnetism measurements of lake sediments for Dali Nor area, southeastern Inner Mongolia Plateau, China, Palaeogeography Palaeoclimatology Palaeoecology, Vol. 170, pp. 115-132, 2001.
    Wu Chen and Xu Qinghai and Ma Yonghong and Zhang Xiuqing, Palaochannels on the North China Plain : palaeoriver geomorphology, Geomorphology, Vol. 18, pp. 37-45, 1996.

    網頁資料
    北京市氣象局[簡體]
    http://www.bjmb.gov.cn/index.asp

    下載圖示 校內:立即公開
    校外:2004-05-14公開
    QR CODE