簡易檢索 / 詳目顯示

研究生: 陳冠良
Chen, Guan-Liang
論文名稱: 重質油氣化合成氣觸媒氣渦輪引擎之研發
Development of a Gasified Heavy-oil Syn-gas Catalytic Gas Turbine
指導教授: 趙怡欽
Chao, Yei-Cheng
學位類別: 碩士
Master
系所名稱: 工學院 - 航空太空工程學系
Department of Aeronautics & Astronautics
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 102
中文關鍵詞: 氣化觸媒重質油氣渦輪引擎合成氣
外文關鍵詞: Heavy-oil, Gas Turbine, Catalytic, Gasification, Syn-gas
相關次數: 點閱:62下載:5
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  •   石化碳氫燃料之貧油預混燃燒技術,以及廢棄物與生質能之氣化低熱值燃燒是目前因應世紀二氧化碳減量與石油匱乏問題而普遍受到重視的兩項新型態燃燒技術,但是這兩項技術均受到火焰穩定性的問題的嚴重挑戰。觸媒燃燒被建議為一種可用來改善貧油預混與低熱值燃燒穩定性,並且降低污染排放與提高燃燒效率的有效方法。本文研發以觸媒燃燒(catalytic combustion)技術搭配貧油預混(lean pre-mixing),使用再生低熱值氣化石化燃料或生質燃料為設計觀念的低污染能源潔淨使用技術。
      本研究目的在於發展以重質油氣化合成氣為燃料的觸媒氣渦輪引擎,主要探討的問題有發展該引擎的可行性評估、燃燒室設計、零組件測試以及引擎運轉。起初藉由循環分析運算與觸媒燃燒測試結果,初步評估發展該引擎的可行性,並經由實驗證實,且經循環分析得知其輸出功率及熱效率約為37kW/12%。
      在燃燒室設計方面,將燃燒室設定運作在較低流速下,預計可降低觸媒燃燒室壓力損失,以及增加燃料與觸媒床的反應時間,並以自行製作的燃氣混合裝置(靜態混合器和圓弧狀多孔口板),將燃氣均勻擴散至觸媒面上,達到更高反應溫度,提高整體燃燒效率。
      研究則以重質油氣化產氣中的氫氣和一氧化碳作為主要燃料,並以鉑觸媒作為觸媒燃燒室用。完成整體引擎設計與製造,並對各組件進行相關測試,逐步組裝建立完整觸媒氣渦輪引擎,啟動並運轉驗證其可行性,並提出一套適合重質油氣化合觸媒氣渦輪引擎的操作程序與規範,未來可整合發電系統,使能源作更有效的利用。

     In facing the more and more stringent shortage of fossil fuels and environmental regulations for carbon dioxide reduction in the new century, lean premixed combustion of hydrocarbon fuels and low-BTU (low calorific) combustion of gasified renewable biomass and waste are the two new combustion techniques that receiving intensive attention recently. However, both techniques are seriously challenged by the major problems of combustion instability. Catalytic combustion is suggested to improve the combustion instability of above-mentioned techniques with high combustion efficiency and low pollutant emissions. In this study, we investigate the feasibility of using catalytic combustion of lean premixed low-BTU syn-gas from gasified fossil fuel or biomass in a catalytic gas turbine for clean utilization of recycled and renewable energy resources.
     The objective of study is to develop a catalytic gas turbine engine using syn-gas from recycled heavy oil. There are several issues in this study needed to be investigated, including feasibility assessment of the catalytic engine, new design of the combustion chamber, tests of components and parametric studies of engine operation. The feasibility of a low-BTU syn-gas catalytic gas turbine can be assessed by preliminary cycle analysis and catalytic combustion tests. From the cycle analysis, the engine work output and thermal efficiency are estimated to be 37kW/12%.
     In order to reduce the pressure loss and to enhance catalytic reaction by in the catalytic combustion chamber, low flow velocities in the chamber are assigned to increase residence time in the combustion chamber design. The lab-build static mixer and perforated plate are used to enhance uniform fuel air mixing for enhanced combustion efficiency and output temperature.
     Syn-gas from gasified heavy oil is mainly composed of hydrogen and carbon monoxide as the major fuels in this study. Platinum catalyst is used for catalytic combustion for the syn-gas. After the procedure of engine design, fabrication and component tests, the start-up and operation tests of the developed catalytic gas turbine engine system are then performed for parametric analysis to establish the start-up and operation procedure. The above-mentioned design procedure can be used as a model in the future design of syn-gas catalytic gas turbine engine for power generation.

    摘要…I Abstract…III 致謝…V 目錄…VI 表目錄…VIII 圖目錄…IX 第一章 緒論…1 1.1 前言…1 1.2 文獻回顧…2  1.2.1 生質能於觸媒燃燒測試…2  1.2.2 觸媒氣渦輪引擎之應用…5 1.3 研究動機與目的…7 第二章 基礎原理與分析…9 2.1 基礎簡介…9  2.1.1 重質油…9  2.1.2 氣化合成氣…10  2.1.3 觸媒燃燒…14  2.1.4 觸媒氣渦輪引擎…15 2.2 引擎循環分析…16 2.3 產氣觸媒燃燒測試…18  2.3.1 實驗方法…18  2.3.2 燃燒測試結果…19 2.4 觸媒燃燒室規劃…21 第三章 實驗設備…23 3.1 蜂巢式觸媒…23 3.2 渦輪增壓機…23 3.3 燃料空氣混合段…24 3.4 空氣與燃料供應設備…25 3.5 測量系統…26  3.5.1 溫度測量…26  3.5.2 轉速測量…26  3.5.3 壓力測量…27  3.5.4 數據擷取系統…27 第四章 實驗方法…28 4.1 引擎零組件測試…28  4.1.1 渦輪增壓機測試…28  4.1.2 觸媒燃燒室壓力損失測試…28  4.1.3 燃氣混合均勻度測試…30 4.2 整體引擎運轉測試…31 第五章 結果與討論…34 5.1 引擎零組件測試結果…34  5.1.1 渦輪增壓機測試結果…34  5.1.2 觸媒燃燒室壓力損失測試結果…35  5.1.3 燃氣混合均勻度測試結果…36 5.2 整體引擎運轉測試結果…38 5.3 討論…39  5.3.1 循環分析與燃燒測試…39  5.3.2 引擎燃燒室…40  5.3.3 引擎零組件…42  5.3.4 引擎運轉…43 第六章 結論與未來工作…46 6.1 結論…46 6.2 未來工作…47 參考文獻…49 附錄說明…83 自述…90

    Ayhan, D., 2004, Progress in Energy and Combustion Science 30, pp.219-230.
    Bartok, W., Engleman, V.S., Goldstein, R. and Del Valle, E.G., 1972, "Basic Kinetic Studies and Modeling of Nitrogen Oxide Formation in Combustion Progresses," AICHE Symp., Ser. 126, Vol. 68, pp. 30-38.
    Bond, T.C., Noguchi, R.A., Chou, C.P., Mongia, P. K., Chen, J.Y., and Dibble, R.W., 1996, "Catalytic Oxidation of Natural Gas over Supported Platinum: Flow Reactor Experiments and Detailed Numerical Modeling," Twenty-sixth Symposium (International) on combustion, The Combustion Institute, pp.1771-1778.
    Carroni, R., Schmidt, V., and Griffin, T., 2002, "Catalytic combustion for power generation," Catalysis Today, vol.75, pp.287–295.
    Chang, H.N., and Hyun, D.S., 2003, "Inhibition effect of carbon dioxide on the oxidation of hydrogen over a platinum foil catalyst," Catalysis Today, vol.83, pp.257-264.
    Chao, Y.C., Chen, G.B., and Hsu, J.R., 2004, "Catalytic combustion of gasified biomass in a platinum monolith honeycomb reactor," Applied Catalysis A : General, vol.261, pp.99-107.
    David, S., Brian, K., Julian R.H., 2001, "Review of literature on catalysts for biomass gasification," Fuel Processing Technology, vol.73, pp.155–173.
    Etemad, S., Karim, H., Smith, L.L., and Pfefferle, W.C., 1999, "Advanced technology catalytic combustor for high temperature ground power gas turbine applications," Catalysis Today, vol.47, pp.305-313.
    Gimino, S., Di Benedetto, A., Pirone, R., and Russo, G., 2003, "CO, H2 or C3H8 assisted catalytic combustion of methane over supported LaMnO3 monoliths," Catalysis Today, vol.83, pp.33–43.
    Groppi, G., Lietti, L., Tronconi, E., and Forzatti, P., 1998, "Catalytic combustion of gasified biomass over Mn-substituted hexaaluminates for gas turbine applications," Catalysis Today, vol.45, pp.159-165.
    Hanzade, H.A., 2003, Energy Conversion and Management, vol.44, pp.155–162.
    Helena, L.C., and Ralph, P.O., 2001, "Biomass and renewable fuels," Fuel Processing Technology, vol.71, pp.187–195.
    Johansson, E.M., Magnus. B., Johan, K., and Sven, G.J., 1999, "Catalytic combustion of gasified biomass : poisoning by sulphur in the feed," Applied Catalysis B: Environmental, vol.20, pp.319-332.
    Johansson, E.M., Danielsson, K.M.J., Pocoroba, E., Haralson, E.D., and Järås, S.G., 1999, "Catalytic combustion of gasified biomass over hexaaluminate catalysts : Influence of palladium loading and ageing," Applied Catalysis A : General, vol.182, pp.199-208.
    Küçük, M.M., and Demirbas, A., 1997, Energy Convers. Mgmt, vol.38, No.2, pp.151-165.
    Kuper, W.J., Blaauw, M., van der Berg, F., Graaf, G.H., 1999, "Catalytic combustion concept for gas turbines," Catalysis Today, vol.47, pp.377-389.
    Marcus, F.M.Z., Heginuz, G.M.E., Gregertsen, B.H., Sjöstrom, K., and Järås, S.G., 1997, "Catalytic combustion of gasified biomass over Pt/Al2O3," Applied Catalysis A: General, vol.148, pp.325-341.
    Miller, J.A. and Bowman, C.T., 1989, "Mechanism and Modeling of Nitrogen Chemistry in Combustion," Prog. Energy Combust. Sci. Vol. 15, pp. 287-338.
    Omar, O.B., 1999, "Gas-turbine performance improvements," Applied Energy, vol.64, pp.263-273.
    Pfefferle, W.C., Heck, R.M., Carrubba, R.M., and Roberts, G.W., 1975, "Catathermal Combustion: A New Process for Low-emission Fuel Conversion," ASME Paper 75-WA/Fu-1.
    Pilavachi, P.A., 2000, "Power generation with gas turbine systems and combined heat and power," Applied Thermal Engineering, vol.20, pp.1421-1429.
    Quick, L.M., Kamitomai, S., 1995, "Catalytic combustion reactor design and test results," Catalysis Today, vol.26, pp.303-308.
    Saito, K., Saito, T., Yoda, Y., Sasaki M., and Kubota, T., 1997, "Fundamental Operating Characteristics of a Catalytic Combustor as a Residential Kerosene Heater," Proceeding of The First Asia-Pacific Conference on Combustion, Osaka, pp.551-554.
    Schlegel, A., Benz, P., Griffin, T., Weisenstein W., and Bockhorn, H., 1996, "Catalytic Stabilization of Lean Premixed Combustion : Method for Improving NOX Emissions," Combustion and Flame Vol. 105, pp.332-340.
    Schlegel, A., Buser, S., Benz, P., Bockhorn, H., and Mauss, F., 1994, Twenty-fifth Symposium (International) on combustion, The Combustion Institute, Pittsburgh, pp. 1019-1026.
    Williams, R.H., Larson, E.D., 1996, "Biomass gasifier gas turbine power generation technology," Biomass and Bioenergy, vol.10, No.2-3, pp.149-166.
    Witton, J.J., Noordally, E., and Przybylski, J.M., 2003, "Clean catalytic combustion of low heat value fuels from gasification processes," Chemical engineering Joournal, vol.91, pp.115-121.
    Yasushi, O., Tomoharu, F., Mikio, S., Takaaki, K., and Hitoshi, I., 1999, "Development of a catalytically assisted combustor for a gas turbine," Catalysis Today, vol.47, pp.399-405.
    許紘瑋,1998,"觸媒穩駐燃燒之初步研究",國立成功大學航空太空工程研究所碩士論文。
    蔡銘晃,2000,"小型氣渦輪引擎觸媒燃燒室之設計",國立成功大學航空太空工程研究所碩士論文。
    謝維昇,2002,"觸媒氣渦輪引擎原型之發展",國立成功大學航空太空工程研究所碩士論文。

    下載圖示 校內:2006-08-04公開
    校外:2006-08-04公開
    QR CODE