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研究生: 王子仁
Wang, Zih-ren
論文名稱: 表面粗糙度對硬質陶瓷鍍膜與類鑽碳鍍膜耐磨性之影響
Influence of substrate surface roughness on the wear of hard ceramic and DLC coatings
指導教授: 蘇演良
Su, Yan-liang
學位類別: 碩士
Master
系所名稱: 工學院 - 機械工程學系
Department of Mechanical Engineering
論文出版年: 2008
畢業學年度: 96
語文別: 中文
論文頁數: 43
中文關鍵詞: 表面粗糙度類鑽碳
外文關鍵詞: DLC, surface roughness
相關次數: 點閱:98下載:4
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  • 本研究利用封閉式磁控濺鍍法,在不同表面粗糙度之底材,被覆類鑽碳薄膜(DLC)與Zr-Ti-N陶瓷鍍膜,探討不同表面粗糙度之底材與厚度鍍膜,對於DLC鍍膜與Zr-Ti-N鍍膜耐磨性和附著性之影響。首先以XRD分析鍍膜在不同厚度下的結構改變,再以SEM觀察被覆鍍膜在不同厚度與底材粗糙度下,表面成長之微結構與形貌,以及利用刮痕試驗機與洛氏壓痕試驗其附著性,並運用Pin-On-Disk磨耗試驗機研究其磨耗性質影響,最後整理分析以得到,底材粗糙度與鍍膜厚度之最佳關係比例。
    實驗結果顯示,ZT系列之三組試件濺鍍時間不相同,具有相同之鍍層安排,但鍍層晶粒尺寸,卻因濺鍍時間設定減少而隨之變小,其繞射峰之半高寬,也變寬變矮。ZT、DLC系列都可觀察到在粗糙表面的波峰處有較大的晶粒,且與沈積理論相符。薄膜厚度(H)與底材粗糙度(R)成一相依關係,且在H/R比值在30以上,底材粗糙度將不會影響薄膜磨耗性質,而在1.5μm厚度以下的薄膜依底材原本表面形貌成長。其膜厚對粗糙度的比值與磨耗深度關係成一線性,不論在較軟DLC系列鍍層或較硬脆Zr-Ti-N系列鍍層,鍍膜厚度之值為粗糙度的30倍以上則具有較佳的耐磨性質。

    The purpose of this research is study the Influence of substrate surface roughness and varied coating thickness on the wear and adhesion properties of hard ceramic and DLC coatings deposited on HSS tool steel substrate by close-field unbalanced magnetron sputtering system. The effect of coating thickness on surface microstructure and morphology analysis was analyzed by FE-SEM and SEM. Adhesion of the coating to the substrate was assessed by using a Rockwell C hardness tester and a scratch test machine. The tribological performance of the coatings was tested by a Pin-on-disk wear test machine against AISI 52100 balls. Finally, the best ratio of surface roughness and coating thickness for apply in roughness and coating thickness mechanism relation was obtained. The experiment results show as following: three of the hard ceramic coatings have the same deposition designs, but the grains size become smaller with decreasing sputtering duration. The bigger grains obtained on the peak of the rough surface due to the geometrical effect. The optimal roughness (R) depends on the coating thickness (H). The optimal H/R value which more then 30 has the best wear resistance.

    總目錄 合格證明書 I 摘要 II Abstract III 誌 謝 IV 總目錄 V 表目錄 VI 圖目錄 VII 第一章 緒論 1 第二章 文獻回顧 3 2-1奈米薄膜表面型態 3 2-2氮化鋯與類鑽碳鍍膜 4 2-2-1 氮化鋯(ZrN)鍍膜性質 4 2-2-2 類鑽碳(DLC)鍍膜性質 4 2-3 磁控濺鍍理論 5 2-3-1 濺鍍技術 5 2-3-2 平衡與非平衡磁控濺鍍 6 第三章 實驗方法與步驟 8 3-1實驗目的 8 3-2 實驗流程 8 3-3 實驗方法與規劃 9 3-3-1 濺鍍參數與鍍膜安排 9 3-3-2 結構分析 10 3-3-3 附著性測試 10 3-3-4 迴轉式磨耗試驗 11 3-4 實驗設備 11 第四章 實驗結果與討論 13 4-1 基本性質分析 13 4-1-1 結構分析 13 4-1-2 附著性分析 14 4-2 Pin-on-disk 磨耗試驗 15 第五章 結論 17 第六章 參考文獻 19

    1. D. J. Cheng, W. P. Sun, M. H. Hon, Thin Solid Films, 146 (1) (1987) 45-53
    2. B. E. Jacobson, C. V. Deshandey, H. J. Doerr, A. A. Karim, R. F. Bunshah, Thin Solid Films, 118 (3) (1984) 285-292
    3. W.J. Chou, G.P. Yu, J.H. Huang, Surface & Coating Technology, 167 (2003) 59-67
    4. K.A. Gruss, T. Zheleva, R.F. Davis, T.R. Watkins, Surface & Coating Technology, 107 (1998) 115-124
    5. L.Pichon, T. Girardeau, A. Straboni, F. Lignou, P. Guerin, J.Perriere, Applied Surface Science, 150 (1999) 115-124
    6. D.M. Mattox, Surface and Coatings Technology 81 (1996) 8-16
    7. F. Vaz, L. Rebouta, M. Andritschky, M.F. da Silva, J.C. Soares, Journal of Materials Processing Technology, 92-93 (1999) 169-176
    8. C. Mitterer, P. H. Mayrhofer, M. Beschliesser, P. Losbichler, P. Warbichler, F. Hofer, P. N. Gibson, W. Gissler, H. Hruby, J. Musil, J. Vlček, Surface & Coatings Technology, 120-121 (1999) 405-411
    9. J. Musil, F. Regent, Journal of Vacuum Science and Technology A, 16(6) (1998) 3301-3304
    10. L.C. Stearns, J. Zhao, M.P. Harmer, J. Euro. Cera. Soc., 10 (1992) 473-477
    11. Lili Hu, Dejie Li, Guojia Fang, Applied Surface Science, 220 (2003) 367-371
    12. Henry J. Ramos, Nicomedes B. Valmoria, Vacuum, 73 (2004) 549-554
    13. L.-J. Meng, M.P. Dos Santos, Surface & Coating Technology, 90 (1997) 64-70
    14. T. Yotsuya, M. Yoshitake, T. Kodama, Cryogenics, 37 (1997) 817-822
    15. B. Mayumi, T. Itoi, Eiji Aoyagi, Atsushi Noya, Applied Surface Science, 190 (2002) 450-454
    16. M. Takeyma, S. Kagomi, A. Noya, K. Sakanishi, J. Appl. Phys., 80 (1996) 569-573
    17. M.Schlatter, Diamond Relat.Mater. 11 (2002) 1781-1787.
    18. M. Neuhaeuser, H. Hilgers, P. Joeris, R. White, J. Windeln, Diamond Relat. Mater.9 (2000) 1500-1505.
    19. R. Hauert, Diamond Relat. Mater. 12 (2003) 583-589.
    20. M.-S. Hwang, E.-T. Kim, C. Lee, Diamond Relat. Mater. 10 (2001) 2063-2068.
    21. C. Prado, S.J. Wilkins, F. Marken, R.G.. Compton, Electroanalysis 14 (2002) 262.
    22. A. Matthews, S.S. Eskildsen, Diamond Relat. Mater. 3 (1994) 902-908.
    23. J. Robertson, Mater. Sci. Eng. R, 37 (2002) 129-281.
    24. L.G. Jacobsohn, R. Prioli, F.L. Freirejr, G. Mariotto, M.M.Lacerda, Y.W. Chung,Diamond Relat. Mater. 9 (2000) 680.
    25. R.F. Huang, C.Y. Chan, C.H. Lee, J. Gong, K.H. Lai, C.S. Lee, K.Y. Li, L.S. Wen, C. Sun, Diamond Relat. Mater. 10 (2001) 1850.
    26. M. Maharizi, N. Croitoru, A. Seidman, J. Non-Cryst. Solids. 289 (2001) 221.

    27. P. Merel, M. Tabbal, M.Chaker, S. Moisa, J. Margot, Appl. Surf. Sci. 136 (1998) 105.
    28.柯賢文,“表面與薄膜技術”,課程講義
    29. P.J. Kelly, R.D. Amell, Vacuum, 56 (2000) 159-172
    30. T.Arai,H.Fujita,M.Watanable, Thin Solid Films,Vol.154,1987,pp.391.
    31. P. J. Burnett, D. S. Rickerby, Thin Solid Films, 154 (1987) 403-416
    32. M.C. Salvadori, D.R. Martins, M. Cattani, Surface & Coatings Technology 200 (2006) 5119 – 5122
    33. Z.-J. Liu, P.W. Shum, Y.G. Shen, Thin Solid Films, 496 (2006) 326- 332
    34. D. Sheeja, B.K. Tay, K.W. Leong, C.H. Lee, Diamond and Related Materials, 11 (2002) 1643–1647
    35. Y. Al-Olayyan, G.E. Fuchs, R. Baney, J. Tulenko, Journal of Nuclear Materials, 346 (2005) 109–119
    36. T. Ohana, M. Suzuki, T. Nakamura, A. Tanaka, Y. Koga, Diamond & Related Materials, 13 (2004) 2211– 2215
    37. J. Jiang, R.D. Arnell, Wear, 239 2000 1–9
    38. B. Podgornik, S. Hogmark , O. Sandberg, Surface and Coatings Technology, 184 (2004) 338–348
    39. F. Svahn, Å. Kassman-Rudolphi, E. Wallén, Wear, 254 (2003) 1092–1098
    40. J. H.W. Siu, Lawrence K.Y. Li, Wear, 237 2000 283–287
    41. A.B. Vladimirov, I.Sh. Trakhtenberg, A.P. Rubshtein , S.A. Plotnikov, O.M. Bakunin,L.G. Korshunov, E.V. Kuzmina, Diamond and Related Materials 9 (2000) 838–842

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